Christian M. Frech

Redox-induced collapse and regeneration of a pincer-type complex framework: a nonplanar coordination mode of palladium(II).

Unprecedented ROMP activity of low-valent rhenium-nitrosyl complexes: Mechanistic evaluation of an electrophilic olefin metathesis system.

Metal-controlled reactivity of a pincer-type, sigma-coordinated naphthyl radical anion.

Direct observation of reductive elimination of methyl iodide from a rhodium(III) pincer complex: the importance of sterics.

Methylene transfer from SnMe groups mediated by a rhodium(I) pincer complex: Sn-C, C-C, and C-H bond activation.

Short, facile, and high-yielding synthesis of extremely efficient pincer-type suzuki catalysts bearing aminophosphine substituents.

Rationally designed pincer-type heck catalysts bearing aminophosphine substituents: Pd IV intermediates and palladium nanoparticles.

Highly selective dehydrogenative silylation of alkenes catalyzed by rhenium complexes.

Pincer-type Heck catalysts and mechanisms based on Pd(IV) intermediates: a computational study.

Facile synthetic access to rhenium(II) complexes: activation of carbon-bromine bonds by single-electron transfer.

Dichloro-bis(aminophosphine) complexes of palladium: highly convenient, reliable and extremely active suzuki-miyaura catalysts with excellent functional group tolerance.

P Csp(3) P and P Csp(2) P palladium(II) hydride pincer complexes: small structural difference-large effect on reactivity.

[Pd(Cl)2{P(NC5H10)(C6H11)2}2]--a highly effective and extremely versatile palladium-based Negishi catalyst that efficiently and reliably operates at low catalyst loadings.

Hydrolysis of ammonia borane catalyzed by aminophosphine-stabilized precursors of rhodium nanoparticles: ligand effects and solvent-controlled product formation.

Negishi cross-coupling reaction catalyzed by an aliphatic, phosphine based pincer complex of palladium. biaryl formation via cationic pincer-type Pd(IV) intermediates.

Negishi cross-coupling reactions catalyzed by an aminophosphine-based nickel system: a reliable and general applicable reaction protocol for the high-yielding synthesis of biaryls.

Cyanation of aryl bromides with K4[Fe(CN)6] catalyzed by dichloro[bis{1-(dicyclohexylphosphanyl)piperidine}]palladium, a molecular source of nanoparticles, and the reactions involved in the catalyst-deactivation processes.

Alkyne hydrothiolation catalyzed by a dichlorobis(aminophosphine) complex of palladium: selective formation of cis-configured vinyl thioethers.