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Chapter 7

Principles of Nuclear Magnetic Resonance

Nuclear Magnetic Resonance (NMR): Overview
Nuclear Magnetic Resonance (NMR): Overview
Nuclear magnetic resonance (NMR) is a phenomenon exhibited by certain nuclei that can absorb characteristic radio frequency radiation under certain ...
Atomic Nuclei: Nuclear Spin
Atomic Nuclei: Nuclear Spin
All atomic particles possess an intrinsic angular momentum, or 'spin'. Electrons, protons, and neutrons each have a spin value of ½, although ...
Atomic Nuclei: Nuclear Magnetic Moment
Atomic Nuclei: Nuclear Magnetic Moment
All atomic nuclei are positively charged. When they have a nonzero spin, they behave like rotating charges. As a consequence of their charge and spin, ...
Atomic Nuclei: Nuclear Spin State Overview
Atomic Nuclei: Nuclear Spin State Overview
NMR-active nuclei have energy levels called 'spin states' that are associated with the orientations of their nuclear magnetic moments. In the ...
Atomic Nuclei: Nuclear Spin State Population Distribution
Atomic Nuclei: Nuclear Spin State Population Distribution
Near absolute zero temperatures, in the presence of a magnetic field, the majority of nuclei prefer the lower energy spin-up state to the higher energy ...
Atomic Nuclei: Larmor Precession Frequency
Atomic Nuclei: Larmor Precession Frequency
The earth's gravitational field produces a 'twisting force' perpendicular to the angular momentum of a spinning mass (such as a spinning top) ...
Atomic Nuclei: Magnetic Resonance
Atomic Nuclei: Magnetic Resonance
The number of nuclear spins aligned in the lower energy state is slightly greater than those in the higher energy state. In the presence of an external ...
Atomic Nuclei: Nuclear Relaxation Processes
Atomic Nuclei: Nuclear Relaxation Processes
In the absence of an external magnetic field, nuclear spin states are degenerate and randomly oriented. When a magnetic field is applied, the spins begin ...
Atomic Nuclei: Types of Nuclear Relaxation
Atomic Nuclei: Types of Nuclear Relaxation
Relaxation in NMR systems is a first-order exponential decay and can occur by either spin–lattice or spin–spin mechanisms. Spin–lattice ...
NMR Spectrometers: Overview
NMR Spectrometers: Overview
NMR spectrometers consist of a strong magnet, a radiofrequency transmitter, and a detector attached to a computer console for recording spectra of samples ...
NMR Spectrometers: Radiofrequency Pulses and Pulse Sequences
NMR Spectrometers: Radiofrequency Pulses and Pulse Sequences
A pulse is a short burst of radio waves distributed over a range of frequencies that simultaneously excites all the nuclei in the sample. Upon passing a ...
NMR Spectrometers: Resolution and Error Correction
NMR Spectrometers: Resolution and Error Correction
When magnetic nuclei in a sample achieve resonance and undergo relaxation, the signal detected in NMR is an approximately exponential free induction ...
Diamagnetic Shielding of Nuclei: Local Diamagnetic Current
Diamagnetic Shielding of Nuclei: Local Diamagnetic Current
An applied magnetic field causes the electrons present in the molecule to circulate, setting up a local diamagnetic current within the molecule. The local ...
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