Source: Laboratory of Dr. Neal Abrams - SUNY College of Environmental Science and Forestry
Determining the chemical formula of a compound is at the heart of what chemists do in the laboratory every day. Many tools are available to aid in this determination, but one of the simplest (and most accurate) is the determination of the empirical formula. Why is this useful? Because of the law of conservation of mass, any reaction can be followed gravimetrically, or by change in mass. The empirical formula provides the smallest whole-number ratio among elements (or compounds) within a molecular compound. In this experiment, gravimetric analysis will be used to determine the empirical formula of copper chloride hydrate, CuxCly·nH2O.
1. Dehydrating the Hydrate
In one example, suppose an unknown biomolecule containing only C, H, and O is found to act well as a new fuel. One way to determine the formula of the fuel would be to combust it in air and analyze the products:
CxHyOz + O2 → mCO2 + nH2O
While O2 is in excess, we would know all the carbon in CO2 originated from the biomolecule and all the hydrogen would be present in H
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