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Retropinacol/Cross-pinacol Coupling Reactions - A Catalytic Access to 1,2-Unsymmetrical Diols

DOI :

10.3791/51258-v

April 4th, 2014

April 4th, 2014

12,702 Views

1Department of Chemistry, Humboldt University of Berlin

A novel account for the synthesis of unsymmetrical 1,2-diols based on a retropinacol/cross-pinacol coupling mechanism is described. Due to the catalytic execution of this reaction a considerable improvement compared to conventional cross-pinacol couplings is achieved.

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Retropinacol Cross pinacol Coupling Reactions

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