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DOI :
10.3791/58067-v
August 23rd, 2018
Chapters
0:04
Title
1:16
Synthesis of Ruthenium Olefin Metathesis Catalyst 1
3:30
Metathesis Reaction and Removal of Catalyst Residue in Aqueous Media
4:39
Ring-opening Metathesis Polymerization and Removal of Catalyst Residue in Aqueous Media
5:52
Metathesis Reaction and Removal of Catalyst Residue from CH2Cl2
7:20
Results: Removal of Water-Soluble Ruthenium Olefin Metathesis Catalyst via Host-Guest Interaction
9:02
Conclusion
开发了一种可移动的水溶性n-杂环卡宾 (NHC) 配体在水介质中的宿主-来宾相互作用。我们在水中和二氯甲烷中表现出了代表性的烯烃置换反应。通过主-客交互或萃取, 在反应后, 残余钌 (钌) 催化剂的低至 0.14 ppm。
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