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DOI :
10.3791/58067-v
August 23rd, 2018
Chapters
0:04
Title
1:16
Synthesis of Ruthenium Olefin Metathesis Catalyst 1
3:30
Metathesis Reaction and Removal of Catalyst Residue in Aqueous Media
4:39
Ring-opening Metathesis Polymerization and Removal of Catalyst Residue in Aqueous Media
5:52
Metathesis Reaction and Removal of Catalyst Residue from CH2Cl2
7:20
Results: Removal of Water-Soluble Ruthenium Olefin Metathesis Catalyst via Host-Guest Interaction
9:02
Conclusion
取り外し可能な水溶性N-ホスト-ゲスト相互作用による水溶液中における複素環カルベン (NHC) を配位子が開発されています。ジクロロ メタンと同様に水で代表的なオレフィンのメタセシス反応を示しました。ホスト-ゲスト相互作用または抽出のいずれかを介して残留ルテニウム (Ru) 触媒は反応後 0.14 ppm と低かった。
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