Stefanie Dehnen

Reactivity of chalcogenostannate salts: unusual synthesis and structure of a compound containing ternary cluster anions [Co4(micro4-Se)(SnSe4)4]10-.

Reactivity of chalcogenostannate compounds: syntheses, crystal structures, and electronic properties of novel compounds containing discrete ternary anions [MII4(mu4-Se)(SnSe4)4]10- (MII = Zn, Mn).

Syntheses and crystal structures of the Ag[bond]S cluster compounds [Ag70S20(SPh)28(dppm)10] (CF3CO2)2 and [Ag262S100(StBu)62(dppb)6].

Syntheses of the 47 electron clusters [(Cp*Fe)3(mu3-X)2] (X = S, Se) and the First Fe/Sn/Se Heterocubane Cluster [(CpFe)3(SnCl3)(mu3-Se)4] x DME by the use of chalcogenostannate salts.

Ortho-chalcogenostannates as ligands: syntheses, crystal structures, electronic properties, and magnetism of novel compounds containing ternary anionic substructures [M4(mu4-Se)(SnSe4)4]10- (M=Mn, Zn, Cd, Hg), 3(infinity)[[Hg4(mu4-Se)(SnSe4)3]6-], or 1(infinity)[[HgSnSe4]2-].

Unusual syntheses, structures, and electronic properties of compounds containing ternary, T3-type supertetrahedral M/Sn/S anions [M5Sn(mu3-S)4(SnS4)4](10- (M = Zn, Co).

Ternary Mn/Ge/Se anions from reactions of [Ba2(H2O)9][GeSe4]: synthesis and characterization of compounds containing discrete or polymeric [Mn6Ge4Se17]6- units.

Fine-tuning of optical properties with salts of discrete or polymeric, heterobimetallic telluride anions [M4micro4-Te)(SnTe4)4](10-) (M = Mn, Zn, Cd, Hg) and 3{[Hg4(micro4-Te)(SnTe4)3](6-)}.

One-size adjustable-gap cluster anions: systematic approach to multinary, water-soluble chalcogenidometalate compounds.

A heterometallic, heterovalent Cu(I)/Sn(II/IV)/S cluster with an unprecedented Cu4Sn core and stannacyclopentane units.

Inorganic frameworks from selenidotetrelate anions [T2Se6]4- (T = Ge, Sn): synthesis, structures, and ionic conductivity of [K2(H2O)3][MnGe4Se10] and (NMe4)2[MSn4Se10] (M = Mn, Fe).

Thiostannate tin-tin bond formation in solution: in situ generation of the mixed-valent, functionalized complex [{(RSn(IV))2(mu-S)2}3Sn(III)2S6].

Transformation of a layered zinc phosphite to a three-dimensional open-framework structure with intersecting 16- and 12-ring channels.

Stabilization of gold(I) and gold(III) complexes by pyridil bis{3-hexamethylene-iminylthiosemicarbazone}: spectroscopic, structural and computational study.

Syntheses, structures, and comprehensive NMR spectroscopic investigations of hetero-chalcogenidometallates: the right mix toward multinary complexes.

Synthesis and properties of the tetranuclear palladium chalcogenolato-acetato complex [Pd(SePh)(OOCCH3)]4 with Pd-Pd bonding: an experimental and theoretical study.

Synthesis and reactivity of functionalized binary and ternary thiometallate complexes [(RT)4S6], [(RSn)3S4]2-, [(RT)2(CuPPh3)6S6], and [(RSn)6(OMe)6Cu2S6]4- (R=C2H4COOH, CMe2CH2COMe; T=Ge, Sn).

Facile access to the hydrazone functionalized PdGeS cluster [{R(N)Ge(mu-S)3}4Pd6] from the thiogermanate anion [{R(N)Ge}2(mu-S)2S2]2-.

[Zn6Sn3Bi8]4-: expanding the intermetalloid zintl anion concept to ternary systems.

A cubic coordination framework constructed from benzobistriazolate ligands and zinc ions having selective gas sorption properties.

Intermediate spin ground state of an isosceles triangular [Mn(II)(3)] complex.

The subtle influence of binary versus homoatomic zintl ions: the phenyl-ligated trimetallic cage [Sn(2)Sb(5)(ZnPh)(2)](3-).

Presence or absence of a central Se atom in silver selenide/selenolate clusters with halite topology: syntheses and properties of [(Ph(3)PAg)(8)Ag(6)(mu(6)-Se)(1-x/2)(SePh)(12)](x+) (x = 0, 1).

From an organic-functionalized Ge4S6 cage to a chalcogenidometallate organic coordination framework with antiferromagnetic chain behavior.

Directed formation of an organotin sulfide cavitand and its transformation into a rugby-ball-like capsule.

Synthesis and reactivity of ferrocenyl functionalized Sn/S cages.

Directed derivatization of organotin sulfide compounds: synthesis and self-assembly of an SnS backpack-like cage and a CuSnS ternary cluster.

Organotin chalcogenide salts: synthesis, characterization, and extended crystal structures.

Aqueous telluridoindate chemistry: water-soluble salts of monomeric, dimeric, and trimeric In/Te anions [InTe(4)](5-), [In(2)Te(6)](6-), and [In(3)Te(10)](11-).

In situ Ge-Ge bond formation under ambient conditions: synthesis, characterization and reactivity of organo-functionalized telluridogermanate complexes.

Neither electron-precise nor in accordance with Wade-Mingos rules: the ternary cluster anion [Ni2Sn7Bi5]3-.

[Eu@Sn6Bi8]4-: a mini-fullerane-type Zintl anion containing a lanthanide ion.

Trigonal propeller-shaped [Mn(III)3M(II)Na] complexes (M = Mn, Ca): structural and functional models for the dioxygen evolving centre of PSII.

Controlling the architecture of discrete organotin sulfide molecules by optimization of the intramolecular spacer length.

New three-dimensional metal-organic framework with heterometallic [Fe-Ag] building units: synthesis, crystal structure, and functional studies.

Formation of a strandlike polycatenane of icosahedral cages for reversible one-dimensional encapsulation of guests.

[MnIII6O3Ln2] single-molecule magnets: increasing the energy barrier above 100 K.

[BMIm]4[Sn9Se20]: ionothermal synthesis of a selenidostannate with a 3D open-framework structure.

[Pd3Sn8Bi6]4-: a 14-vertex Sn/Bi cluster embedding a Pd3 triangle.

Doped semimetal clusters: ternary, intermetalloid anions [Ln@Sn7Bi7]4- and [Ln@Sn4Bi9]4- (Ln = La, Ce) with adjustable magnetic properties.

"Zeoball" [Sn36Ge24Se132]24-: a molecular anion with zeolite-related composition and spherical shape.

Heterobimetallic chalcogenidometallate strands: synthesis, structure, magnetism, and conductivity.

Structure and properties of new mixed-valent [Mn(III)2Mn(IV)3Ln(III)5O5] complexes (Ln(III) = Tm(III), Lu(III), and Yb(III)).

Borophosphonate cages: easily accessible and constitutionally dynamic heterocubane scaffolds.

Chalcogenide clusters of copper and silver from silylated chalcogenide sources.

Controlling the assembly of chalcogenide anions in ionic liquids: from binary Ge/Se through ternary Ge/Sn/Se to binary Sn/Se frameworks.

Making practical use of the pseudo-element concept: an efficient way to ternary intermetalloid clusters by an isoelectronic Pb(-)-Bi combination.

Subtle impact of atomic ratio, charge and lewis basicity on structure selection and stability: the Zintl anion [(La@In2Bi11)(μ-Bi)2(La@In2Bi11)]6-.

Trinuclear nickel-lanthanide compounds.

Modification of Sn/S cages with bis-functionalized ferrocenyl units.

Synthesis of complex polymeric telluridoindates from KInTe2.

Changes in the structural dimensionality of selenidostannates in ionic liquids: formation, structures, stability, and photoconductivity.

A defect supertetrahedron naphthoxime-based [Mn(III)9] Single-Molecule Magnet.

Towards the installation of transition metal ions on donor ligand decorated tin sulfide clusters.

Functionalized organotin-chalcogenide complexes that exhibit defect heterocubane scaffolds: formation, synthesis, and characterization.

Li10SnP2S12: an affordable lithium superionic conductor.

Directed formation of a ferrocenyl-decorated organotin sulfide complex and its controlled degradation.

Unusual 14-electron fragments [Pd(η(3) -Bi3-x Pbx )]((x+1)-) as pseudo lead atoms in closo-[Pd@Pd2 Pb10 Bi6 ](4-).

Quantitative investigation of bonding characteristics in ternary Zintl anions: charge and energy analysis of [Sn2E(15)(2)(ZnPh)](-) (E(15) = Sb, Bi) and [Sn2Sb5(ZnPh)2](3-).

K(4)[PbSe(4)]⋅en⋅NH(3) : a non-oxide, non-halide inorganic lead(IV) compound.

Formation of [Bi(11)](3-) , a homoatomic, polycyclic bismuth polyanion, by pyridine-assisted decomposition of [GaBi(3)](2-).

Synthesis, crystal structure, and photoluminescence studies of a ruthenocenyl-decorated Sn/S cluster.

Bronze, silver and gold: functionalized group 11 organotin sulfide clusters.

Organotin-oxido cluster-based multiferrocenyl complexes obtained by hydrolysis of ferrocenyl-functionalized organotin chlorides.

Origin and location of electrons and protons during the formation of intermetalloid clusters [Sm@Ga(3-x)H(3-2x)Bi(10+x)](3-) (x = 0, 1).

Ferrocenyl-functionalized Sn/Se and Sn/Te complexes: synthesis, reactivity, optical, and electronic properties.

Ionic-radius-driven selection of the main-group-metal cage for intermetalloid clusters [Ln@Pbx Bi14-x](q-) and [Ln@Pby Bi13-y](q-) (x/q=7/4, 6/3; y/q=4/4, 3/3).

Revisiting [(RSn(IV))6Sn(III)2S12]: directed synthesis, crystal transformation, and luminescence properties.

[M4Sn4Se17](10-) cluster anions (M = Mn, Zn, Cd) in a Cs(+) environment and as ternary precursors for ionothermal treatment.

[V@Ge8As4]3- and [Nb@Ge8As6]3-: encapsulation of electron-poor transition metal atoms.

Molecular CHEVREL-like clusters [(RhPPh3)6(μ3-Se)8] and [Pd6(μ3-Te)8](4-).

Syntheses, structures and theoretical investigations of [Au10S2(PPh2)2(dppma2)4(dppma3)]·[Au6S2(dppma2)2(dppma3)].

Synthesis and Thorough Investigation of Discrete Organotin Telluride Clusters.

{μ-PbSe}: a heavy CO homologue as an unexpected ligand.

Synthesis of Crystalline Chalcogenides in Ionic Liquids.

Understanding of multimetallic cluster growth.

Formation and Reactivity of Organo-Functionalized Tin Selenide Clusters.

Etching of Crystalline ZnO Surfaces upon Phosphonic Acid Adsorption: Guidelines for the Realization of Well-Engineered Functional Self-Assembled Monolayers.

A highly efficient directional molecular white-light emitter driven by a continuous-wave laser diode.

Mercurates from a Revised Ionothermal Synthesis Route: The Pseudo-Flux Approach.

Main Group Metal-Actinide Magnetic Coupling and Structural Response Upon U(4+) Inclusion Into Bi, Tl/Bi, or Pb/Bi Cages.

{[CuSn5 Sb3 ](2-) }2 : A Dimer of Inhomogeneous Superatoms.

{[Ir3(cod)3(μ3-S)2](μ3-S)SnCl}2 - a ternary Ir-Sn-S cluster with the iridium atoms in three different chemical environments.

Organotetrel Chalcogenide Clusters: Between Strong Second-Harmonic and White-Light Continuum Generation.