Joseph T. Hupp

Primitive Molecular Recognition Effects in Electron Transfer Processes: Modulation of ((Trimethylammonio)methyl)ferrocenium/ferrocene Self-Exchange Kinetics via Hydrophobic Encapsulation.

Electron Self-Exchange Kinetics for a Water-Soluble Ferrocenium/Ferrocene Couple: Rate Modulation via Charge Dependent Calix[6]arene-p-sulfonate Encapsulation.

Self-Assembly of Luminescent Molecular Squares Featuring Octahedral Rhenium Corners.

Electroabsorption Studies of Metal-to-Ligand Charge Transfer in Ru(phenanthroline)(3)(2+): Evidence for Intrinsic Charge Localization in the Initially Formed Excited State.

Electroabsorption and Related Spectroscopic Studies of Bimetallic Tetraiminoethylenedimacrocyclic Complexes: Corroboration of Valence Electron Delocalization.

Synthesis and Characterization of Molecular Rectangles Based upon Rhenium Thiolate Dimers.

Synthesis, characterization, and preliminary intramolecular energy transfer studies of rigid, emissive, rhenium-linked porphyrin dimers.

Shape-selective transport through rectangle-based molecular materials: thin-film scanning electrochemical microscopy studies.

Experimental studies of light-induced charge transfer and charge redistribution in (X(2)-bipyridine)Re(I)(CO)(3)Cl complexes.

Large-scale resonance amplification of optical sensing of volatile compounds with chemoresponsive visible-region diffraction gratings.

Analysis of molecular square size and purity via pulsed-field gradient NMR spectroscopy.

Synthesis of silver nanodisks using polystyrene mesospheres as templates.

Microporous supramolecular coordination compounds as chemosensory photonic lattices.

Micropatterned polymeric gratings as chemoresponsive volatile organic compound sensors: implications for analyte detection and identification via diffraction-based sensor arrays.

Real-time multicolor DNA detection with chemoresponsive diffraction gratings and nanoparticle probes.

Nonadiabatic electron transfer at the nanoscale tin-oxide semiconductor/aqueous solution interface.

Characterization and purification of supramolecular metal complexes using gel-permeation chromatography.

Directed assembly of transition-metal-coordinated molecular loops and squares from salen-type components. Examples of metalation-controlled structural conversion.

X-ray nanoscale profiling of layer-by-layer assembled metal/organophosphonate films.

Rhenium-based molecular rectangles as frameworks for ligand-centered mixed valency and optical electron transfer.

Permeable nonaggregating porphyrin thin films that display enhanced photophysical properties.

Tetra-rhenium molecular rectangles as organizational motifs for the investigation of ligand-centered mixed valency: three examples of full delocalization.

Synthesis and optical properties of anisotropic metal nanoparticles.

Walljet electrochemistry: quantifying molecular transport through metallopolymeric and zirconium phosphonate assembled porphyrin square thin films.

Microporous pillared paddle-wheel frameworks based on mixed-ligand coordination of zinc ions.

Anthracene-induced turnover enhancement in the manganese porphyrin-catalyzed epoxidation of olefins.

Borderline class II/III ligand-centered mixed valency in a porphyrinic molecular rectangle.

Chemistry. Better living through nanopore chemistry.

Anodic aluminium oxide catalytic membranes for asymmetric epoxidation.

C- and Z-shaped coordination compounds. synthesis, structure, and spectroelectrochemistry of cis- and trans-[Re(CO)3(L)]2-2,2'-bisbenzimidizolate with L = 4-phenylpyridine, 2,4'-bipyridine, or pyridine.

Mucin-Pseudomonas aeruginosa interactions promote biofilm formation and antibiotic resistance.

Liquid/liquid interface polymerized porphyrin membranes displaying size-selective molecular and ionic permeability.

Underlying spin-orbit coupling structure of intervalence charge transfer bands in dinuclear polypyridyl complexes of ruthenium and osmium.

A metal-organic framework material that functions as an enantioselective catalyst for olefin epoxidation.

Comparative X-ray standing wave analysis of metal-phosphonate multilayer films of dodecane and porphyrin molecular square.

pH-dependent electron transfer from re-bipyridyl complexes to metal oxide nanocrystalline thin films.

A new class of mixed-valence systems with orbitally degenerate organic redox centers. Examples based on hexa-rhenium molecular prisms.

Dynamics of charge transport and recombination in ZnO nanorod array dye-sensitized solar cells.

Supramolecular porphyrinic prisms: coordinative assembly and solution phase X-ray structural characterization.

Solution-phase structural characterization of supramolecular assemblies by molecular diffraction.

Comparison of interfacial electron transfer through carboxylate and phosphonate anchoring groups.

ZnO nanotube based dye-sensitized solar cells.

Chemical reduction of metal-organic framework materials as a method to enhance gas uptake and binding.

Synthesis and hydrogen sorption properties of carborane based metal-organic framework materials.

Coordinative self-assembly and solution-phase X-ray structural characterization of cavity-tailored porphyrin boxes.

Intramolecular energy transfer within butadiyne-linked chlorophyll and porphyrin dimer-faced, self-assembled prisms.

New architectures for dye-sensitized solar cells.

Fast energy transfer within a self-assembled cyclic porphyrin tetramer.

Alkali metal cation effects on hydrogen uptake and binding in metal-organic frameworks.

Separating solids: purification of metal-organic framework materials.

Growth of narrowly dispersed porphyrin nanowires and their hierarchical assembly into macroscopic columns.

Separation of CO2 from CH4 using mixed-ligand metal-organic frameworks.

Hollow porphyrin prisms: modular formation of permanent, torsionally rigid nanostructures via templated olefin metathesis.

Ligand-elaboration as a strategy for engendering structural diversity in porous metal-organic framework compounds.

Radial electron collection in dye-sensitized solar cells.

Carborane-based metal-organic frameworks as highly selective sorbents for CO(2) over methane.

An example of node-based postassembly elaboration of a hydrogen-sorbing, metal-organic framework material.

Covalent surface modification of a metal-organic framework: selective surface engineering via Cu(I)-catalyzed Huisgen cycloaddition.

Cavity-tailored, self-sorting supramolecular catalytic boxes for selective oxidation.

Framework reduction and alkali-metal doping of a triply catenating metal-organic framework enhances and then diminishes H2 uptake.

Supercritical processing as a route to high internal surface areas and permanent microporosity in metal-organic framework materials.

A catalytically active, permanently microporous MOF with metalloporphyrin struts.

Post-synthesis alkoxide formation within metal-organic framework materials: a strategy for incorporating highly coordinatively unsaturated metal ions.

Gas-sorption properties of cobalt(II)--carborane-based coordination polymers as a function of morphology.

Electron transport in dye-sensitized solar cells based on ZnO nanotubes: evidence for highly efficient charge collection and exceptionally rapid dynamics.

Metal-organic framework materials as catalysts.

Toward plasmonic solar cells: protection of silver nanoparticles via atomic layer deposition of TiO2.

Electron transfer in platinum(II) diimine-centered triads: mechanistic insights from photoinduced transient displacement current measurements.

Distance dependence of plasmon-enhanced photocurrent in dye-sensitized solar cells.

A Zn-based, pillared paddlewheel MOF containing free carboxylic acids via covalent post-synthesis elaboration.

Probing exciton localization/delocalization: transient dc photoconductivity studies of excited states of symmetrical porphyrin monomers, oligomers, and supramolecular assemblies.

Selective bifunctional modification of a non-catenated metal-organic framework material via "click" chemistry.

Solvent-induced configuration mixing and triplet excited-state inversion: insights from transient absorption and transient dc photoconductivity measurements.

Synthesis and gas sorption properties of a metal-azolium framework (MAF) material.

Dye sensitized solar cells: TiO2 sensitization with a bodipy-porphyrin antenna system.

Dye-sensitized solar cells: sensitizer-dependent injection into ZnO nanotube electrodes.

An interpenetrated framework material with hysteretic CO(2) uptake.

Control over catenation in metal-organic frameworks via rational design of the organic building block.

Photoinduced electron transfer from rail to rung within a self-assembled oligomeric porphyrin ladder.

Chemical reduction of a diimide based porous polymer for selective uptake of carbon dioxide versus methane.

Dye-sensitized solar cells: driving-force effects on electron recombination dynamics with cobalt-based shuttles.

Excess polarizability reveals exciton localization/delocalization controlled by linking positions on porphyrin rings in butadiyne-bridged porphyrin dimers.

Ni(III)/(IV) bis(dicarbollide) as a fast, noncorrosive redox shuttle for dye-sensitized solar cells.

Separation of gas mixtures using Co(II) carborane-based porous coordination polymers.

Metal-organic frameworks as sensors: a ZIF-8 based Fabry-Pérot device as a selective sensor for chemical vapors and gases.

Crystal engineering: towards artificial enzymes.

Electronic tuning of nickel-based bis(dicarbollide) redox shuttles in dye-sensitized solar cells.

Rational design, synthesis, purification, and activation of metal-organic framework materials.

Porphyrin sensitized solar cells: TiO2 sensitization with a pi-extended porphyrin possessing two anchoring groups.

Metal-organic framework thin film for enhanced localized surface plasmon resonance gas sensing.

De novo synthesis of a metal-organic framework material featuring ultrahigh surface area and gas storage capacities.

Cubic and rhombohedral heterobimetallic networks constructed from uranium, transition metals, and phosphonoacetate: new methods for constructing porous materials.

A convenient route to high area, nanoparticulate TiO2 photoelectrodes suitable for high-efficiency energy conversion in dye-sensitized solar cells.

Selective surface and near-surface modification of a noncatenated, catalytically active metal-organic framework material based on Mn(salen) struts.

Kinetic separation of propene and propane in metal-organic frameworks: controlling diffusion rates in plate-shaped crystals via tuning of pore apertures and crystallite aspect ratios.

Active-site-accessible, porphyrinic metal-organic framework materials.

The role of electronic coupling in linear porphyrin arrays probed by single-molecule fluorescence spectroscopy.

Post-synthesis modification of a metal-organic framework to form metallosalen-containing MOF materials.

Luminescent infinite coordination polymer materials from metal-terpyridine ligation.

Fabrication of metal-organic framework-containing silica-colloidal crystals for vapor sensing.

Enhanced electrocatalytic reduction of CO2 with ternary Ni-Fe4S4 and Co-Fe4S4-based biomimetic chalcogels.

Light-harvesting metal-organic frameworks (MOFs): efficient strut-to-strut energy transfer in bodipy and porphyrin-based MOFs.

Photocurrent enhancement by surface plasmon resonance of silver nanoparticles in highly porous dye-sensitized solar cells.

Metal-organic framework materials as chemical sensors.

Coordination-chemistry control of proton conductivity in the iconic metal-organic framework material HKUST-1.

Metal-adeninate vertices for the construction of an exceptionally porous metal-organic framework.

High propene/propane selectivity in isostructural metal-organic frameworks with high densities of open metal sites.

Large-scale screening of hypothetical metal-organic frameworks.

Urea metal-organic frameworks as effective and size-selective hydrogen-bond catalysts.

Enhanced catalytic decomposition of a phosphate triester by modularly accessible bimetallic porphyrin dyads and dimers.

Imparting functionality to a metal-organic framework material by controlled nanoparticle encapsulation.

Glass-encapsulated light harvesters: more efficient dye-sensitized solar cells by deposition of self-aligned, conformal, and self-limited silica layers.

Designing higher surface area metal-organic frameworks: are triple bonds better than phenyls?

Engineering ZIF-8 thin films for hybrid MOF-based devices.

Fast transporting ZnO-TiO2 coaxial photoanodes for dye-sensitized solar cells based on ALD-modified SiO2 aerogel frameworks.

Metal-organic framework materials with ultrahigh surface areas: is the sky the limit?

Cyclic metalloporphyrin dimers and tetramers: tunable shape-selective hosts for fullerenes.

Understanding excess uptake maxima for hydrogen adsorption isotherms in frameworks with rht topology.

Incorporation of an A1/A2-difunctionalized pillar[5]arene into a metal-organic framework.

Opening ZIF-8: a catalytically active zeolitic imidazolate framework of sodalite topology with unsubstituted linkers.

Effective panchromatic sensitization of electrochemical solar cells: strategy and organizational rules for spatial separation of complementary light harvesters on high-area photoelectrodes.

Effects of adsorbed pyridine derivatives and ultrathin atomic-layer-deposited alumina coatings on the conduction band-edge energy of TiO2 and on redox-shuttle-derived dark currents.

Light-harvesting and ultrafast energy migration in porphyrin-based metal-organic frameworks.

Hematite-based photo-oxidation of water using transparent distributed current collectors.

Energy transfer from quantum dots to metal-organic frameworks for enhanced light harvesting.

γ-Cyclodextrin cuprate sandwich-type complexes.

Simultaneously high gravimetric and volumetric methane uptake characteristics of the metal-organic framework NU-111.

Removal of airborne toxic chemicals by porous organic polymers containing metal-catecholates.

Three-dimensional architectures incorporating stereoregular donor-acceptor stacks.

Selective isolation of gold facilitated by second-sphere coordination with α-cyclodextrin.

Vapor-phase metalation by atomic layer deposition in a metal-organic framework.

Methane storage in metal-organic frameworks: current records, surprise findings, and challenges.

An exceptionally high boron content supramolecular cuboctahedron.

Enhanced Catalytic Activity through the Tuning of Micropore Environment and Supercritical CO2 Processing: Al(Porphyrin)-Based Porous Organic Polymers for the Degradation of a Nerve Agent Simulant.

Dye Stabilization and Enhanced Photoelectrode Wettability in Water-Based Dye-Sensitized Solar Cells through Post-assembly Atomic Layer Deposition of TiO2.

A facile synthesis of UiO-66, UiO-67 and their derivatives.

Aromatizing olefin metathesis by ligand isolation inside a metal-organic framework.

Layer-by-layer fabrication of oriented porous thin films based on porphyrin-containing metal-organic frameworks.

A mixed dicarboxylate strut approach to enhancing catalytic activity of a de novo urea derivative of metal-organic framework UiO-67.

Systematic modulation of quantum (electron) tunneling behavior by atomic layer deposition on nanoparticulate SnO2 and TiO2 photoanodes.

Perfluoroalkane functionalization of NU-1000 via solvent-assisted ligand incorporation: synthesis and CO2 adsorption studies.

Simple and compelling biomimetic metal-organic framework catalyst for the degradation of nerve agent simulants.

Versatile functionalization of the NU-1000 platform by solvent-assisted ligand incorporation.

Solvent-assisted linker exchange: an alternative to the de novo synthesis of unattainable metal-organic frameworks.

Beyond post-synthesis modification: evolution of metal-organic frameworks via building block replacement.

A metal-organic framework-based material for electrochemical sensing of carbon dioxide.

High-surface-area architectures for improved charge transfer kinetics at the dark electrode in dye-sensitized solar cells.

Defect creation by linker fragmentation in metal-organic frameworks and its effects on gas uptake properties.

SERS of molecules that do not adsorb on Ag surfaces: a metal-organic framework-based functionalization strategy.

Are Zr₆-based MOFs water stable? Linker hydrolysis vs. capillary-force-driven channel collapse.

Fabrication of Transparent-Conducting-Oxide-Coated Inverse Opals as Mesostructured Architectures for Electrocatalysis Applications: A Case Study with NiO.

Real-time observation of atomic layer deposition inhibition: metal oxide growth on self-assembled alkanethiols.

Directed Growth of Electroactive Metal-Organic Framework Thin Films Using Electrophoretic Deposition.

Water-Stable Zirconium-Based Metal-Organic Framework Material with High-Surface Area and Gas-Storage Capacities.

Dynamics of Back Electron Transfer in Dye-Sensitized Solar Cells Featuring 4-tert-Butyl-Pyridine and Atomic-Layer-Deposited Alumina as Surface Modifiers.