Stephen Chamberland

Using nucleophilic substitution reactions to understand how a remote alkyl or alkoxy substituent influences the conformation of eight-membered ring oxocarbenium ions.

Structural evidence that alkoxy substituents adopt electronically preferred pseudoaxial orientations in six-membered ring dioxocarbenium ions.

Synthetic and biosynthetic studies on FR900482 and mitomycin C: an efficient and stereoselective hydroxymethylation of an advanced benzazocane intermediate.

Synthesis of potential early-stage intermediates in the biosynthesis of FR900482 and mitomycin C.

Total synthesis of clavatadine A.

Correction to Total synthesis of clavatadine A.