Claudio Schrenk

The formation of a metalloid Sn(10)[Si(SiMe(3))(3)](6) cluster compound and its relation to the alpha<-->beta tin phase transition.

Sn[Si(SiMe3)3]3- and Sn3[Si(SiMe3)3]4: first insight into the mechanism of the disproportionation of a tin monohalide gives access to the shortest double bond of tin.

[Sn4Si{Si(SiMe3)3}4{SiMe3}2]: a model compound for the unexpected first-order transition from a singlet biradicaloid to a classical bonded molecule.

{Sn9[Si(SiMe3)3]3}− and {Sn8Si[Si(SiMe3)3]3}−: variations of the E9 cage of metalloid group 14 clusters.

{Sn9[Si(SiMe3)3]2}2-: a metalloid tin cluster compound with a Sn9 core of oxidation state zero.

{Sn10 [Si(SiMe3 )3 ]4 }(2-) : A highly reactive metalloid tin cluster with an open ligand shell.

Reactions with a Metalloid Tin Cluster {Sn10[Si(SiMe3)3]4}(2-): Ligand Elimination versus Coordination Chemistry.

Reactions with a Metalloid Tin Cluster {Sn10[Si(SiMe3)3]4}(2-): Ligand Elimination versus Coordination Chemistry.

{Ge9[Si(SiMe3)2(SiPh3)]3}(-): Ligand Modification in Metalloid Germanium Cluster Chemistry.

The Largest Metalloid Group 14 Cluster, Ge18[Si(SiMe3)3]6 : An Intermediate on the Way to Elemental Germanium.

Reactivity of [Ge9{Si(SiMe3)3}3]- towards transition metal M2+ cations : coordination and redox chemistry.