monitoring-effects-illumination-on-structure-conjugated-polymer-gels

Monitoring the Effects of Illumination on the Structure of Conjugated Polymer Gels Using Neutron Scattering

We demonstrate a protocol to effectively monitor the gelation process of a high concentration solution of conjugated polymer both in the presence and ...

University of Tennessee, Knoxville

Oak Ridge National Laboratory

Device efficiency in key organic electronic devices such as organic photovoltaics, field transistors, and light emitting diodes has long been known to be closely tied to the conformation of the conjugated polymer chains which make up the active layers. Our previous results show that light exposure can have a profound effect on the structure and assembly of these optoelectronic materials in solution. In order to advance our understanding of the role which solvent quality plays in this phenomenon, we have further studied the modulation of these illumination dependent structural changes on the key benchmark conjugated polymers P3HT and MEH-PPV as a function of solvent quality over a wide range of polymer solubilities. Analysis of this data indicates that use of poorer conjugated polymer solvents ultimately results in larger absolute alterations to polymer conformation, denoting the crucial role which solution thermodynamics plays in this generic effect. This discovery opens the door to controlling final device morphology through careful manipulation of solvent composition during solution based device casting techniques, moving our efforts closer to the development of a powerful, non-destructive, and tunable method for light-driven control of polymer conformation in novel light-responsive organic materials.

The importance of solvent quality on the modification of conjugated polymer conformation and thermodynamics with illumination.

With a growing variety of nanoparticles available, research probing the influence of particle deformability, morphology, and topology on the behavior of all polymer nanocomposites is also increasing. In particular, the behavior of soft polymeric nanoparticles in polymer nanocomposites has displayed unique behavior, but their precise performance depends intimately on the internal structure and morphology of the nanoparticle. With the goal of providing guidelines to control the structure and morphology of soft polymeric nanoparticles, we have examined monomer starved semi-batch nano-emulsion polymerizations that form organic, soft nanoparticles, to correlate the precise structure of the nanoparticle to the rate of monomer addition and crosslinking density. The synthesis method produces 5-20 nm radii polystyrene nanoparticles with tunable morphologies. We report small angle neutron scattering (SANS) results that correlate synthetic conditions to the structural characteristics of soft polystyrene nanoparticles. These results show that the measured molecular weight of the nanoparticles is controlled by the monomer addition rate, the total nanoparticle radius is controlled by the excess surfactant concentration, and the crosslinking density has a direct effect on the topology of each nanoparticle. These studies thus provide pathways to control these 3 structural characteristics of the nanoparticle. This research, therefore provides a conduit to thoroughly investigate the effect of structural features of soft nanoparticles on their individual properties and those of their polymer nanocomposites.

Mark D. Dadmun

Department of Chemistry

University of Tennessee, Knoxville

Monitoring the Effects of Illumination on the Structure of Conjugated Polymer Gels Using Neutron Scattering

Mark D. Dadmun

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University of Tennessee, Knoxville

Monitoring the Effects of Illumination on the Structure of Conjugated Polymer Gels Using Neutron Scattering

Department of Chemistry