in-situ-neutron-powder-diffraction-using-custom-made-lithium-ion

<em>In Situ</em> Neutron Powder Diffraction Using Custom-made Lithium-ion Batteries

Li-ion batteries are widely used in portable electronic devices and are considered as promising candidates for higher-energy applications such as electric ...

University of Sydney

Members of the AMOB2O5 (A = K, Rb, Cs, Tl; M = Nb, Ta) family of compounds can be described as modulated structures with a single superspace group and very similar modulation functions. Single-crystal X-ray diffraction data (Mo Kalpha radiation) are used to solve and refine the structure of KNbOB2O5 in these terms for the first time. The average structure is solved and refined in the space group Pmn2(1). Subsequently, the atomic modulation functions are determined using JANA2000 and superspace-group symmetry Pmn2(1)(0,0.375,0)s. The commensurately modulated structure is finally refined as a superstructure in the space group Pbn2(1) using SHELXS97 converging to R(1) = 0.024.

Structure of KNbOB2O5--a commensurately modulated structure.

Rapid lithium insertion and location of mobile lithium in the defect perovskite Li(0.18)Sr(0.66)Ti(0.5)Nb(0.5)O3.

The high-temperature cubic form of bismuth oxide, δ-Bi2O3, is the best intermediate-temperature oxide-ionic conductor known. The most elegant way of stabilizing δ-Bi2O3 to room temperature, while preserving a large part of its conductivity, is by doping with higher valent transition metals to create wide solid-solutions fields with exceedingly rare and complex (3 + 3)-dimensional incommensurately modulated "hypercubic" structures. These materials remain poorly understood because no such structure has ever been quantitatively solved and refined, due to both the complexity of the problem and a lack of adequate experimental data. We have addressed this by growing a large (centimeter scale) crystal using a novel refluxing floating-zone method, collecting high-quality single-crystal neutron diffraction data, and treating its structure together with X-ray diffraction data within the superspace symmetry formalism. The structure can be understood as an "inflated" pyrochlore, in which corner-connected NbO6 octahedral chains move smoothly apart to accommodate the solid solution. While some oxide vacancies are ordered into these chains, the rest are distributed throughout a continuous three-dimensional network of wide δ-Bi2O3-like channels, explaining the high oxide-ionic conductivity compared to commensurately modulated phases in the same pseudobinary system.

A (3 + 3)-dimensional "hypercubic" oxide-ionic conductor: type II Bi2O3-Nb2O5.

The development of electrodes for ambient temperature sodium-ion batteries requires the study of new materials and the understanding of how crystal structure influences properties. In this study, we investigate where sodium locates in two Prussian blue analogues, Fe[Fe(CN)6]1-x·yH2O and FeCo(CN)6. The evolution of the sodium site occupancies, lattice and volume is shown during charge-discharge using in situ synchrotron X-ray powder diffraction data. Sodium insertion is found to occur in these electrodes during cell construction and therefore Fe[Fe(CN)6]1-x·yH2O and FeCo(CN)6 can be used as positive electrodes. NazFeFe(CN)6 electrodes feature higher reversible capacities relative to NazFeCo(CN)6 electrodes which can be associated with a combination of structural factors, for example, a major sodium-containing phase, ∼Na0.5FeFe(CN)6 with sodium locating either at the x = y = z = 0.25 or x = y = 0.25 and z = 0.227(11) sites and an electrochemically inactive sodium-free Fe[Fe(CN)6]1-x·yH2O phase. This study demonstrates that key questions about electrode performance and attributes in sodium-ion batteries can be addressed using time-resolved in situ synchrotron X-ray diffraction studies.

Siegbert Schmid

School of Chemistry

University of Sydney

In Situ Neutron Powder Diffraction Using Custom-made Lithium-ion Batteries

Siegbert Schmid

.css-o250i3{font-size:18px;font-family:Open Sans,sans-serif;line-height:21.6px;}School of Chemistry

University of Sydney

In Situ Neutron Powder Diffraction Using Custom-made Lithium-ion Batteries

School of Chemistry