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Epitaxial Nanostructured &alpha;-Quartz Films on Silicon: From the Material to New Devices

In this work, we show a detailed engineering route of the first piezoelectric nanostructured epitaxial quartz-based microcantilever. We will explain all ...

Université de Montpellier

The monolithic integration of sub-micron quartz structures on silicon substrates is a key issue for the future development of piezoelectric devices as prospective sensors with applications based on the operation in the high-frequency range. However, to date, it has not been possible to make existing quartz manufacturing methods compatible with integration on silicon and structuration by top-down lithographic techniques. Here, we report an unprecedented large-scale fabrication of ordered arrays of piezoelectric epitaxial quartz nanostructures on silicon substrates by the combination of soft-chemistry and three lithographic techniques: (i) laser interference lithography, (ii) soft nanoimprint lithography on Sr-doped SiO sol-gel thin films, and (iii) self-assembled SrCO nanoparticle reactive nanomasks. Epitaxial α-quartz nanopillars with different diameters (from 1 μm down to 50 nm) and heights (up to 2 μm) were obtained. This work demonstrates the complementarity of soft-chemistry and top-down lithographic techniques for the patterning of epitaxial quartz thin films on silicon while preserving its epitaxial crystallinity and piezoelectric properties. These results open up the opportunity to develop a cost-effective on-chip integration of nanostructured piezoelectric α-quartz MEMS with enhanced sensing properties of relevance in different fields of application.

David Sanchez-Fuentes

Institut d'Electronique et des Systemes (IES),
CNRS,
Institut d'Electronique et des Systemes (IES), CNRS

Université de Montpellier

Epitaxial Nanostructured α-Quartz Films on Silicon: From the Material to New Devices

David Sanchez-Fuentes

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Université de Montpellier

Epitaxial Nanostructured α-Quartz Films on Silicon: From the Material to New Devices

Institut d'Electronique et des Systemes (IES),
CNRS,
Institut d'Electronique et des Systemes (IES), CNRS