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Chapter 14

Chemical Equilibrium

Równowaga dynamiczna
Równowaga dynamiczna
A reversible chemical reaction represents a chemical process that proceeds in both forward (left to right) and reverse (right to left) directions. When ...
Stała równowagi
Stała równowagi
Consider the oxidation of sulfur dioxide: For a reaction that begins with a mixture of reactants only, the product concentration is initially equal to ...
Równowagi jednorodne dla reakcji gazowych
Równowagi jednorodne dla reakcji gazowych
Homogeneous Equilibria for Gaseous Reactions For gas-phase reactions, the equilibrium constant may be expressed in terms of either the molar ...
Obliczanie stałej równowagi
Obliczanie stałej równowagi
The equilibrium constant for a reaction is calculated from the equilibrium concentrations (or pressures) of its reactants and products. If these ...
Iloraz reakcji
Iloraz reakcji
The status of a reversible reaction is conveniently assessed by evaluating its reaction quotient (Q). For a reversible reaction described by m A + n B ...
Obliczanie stężeń równowagowych
Obliczanie stężeń równowagowych
Being able to calculate equilibrium concentrations is essential to many areas of science and technology—for example, in the formulation and dosing ...
Zasada Le Chateliera: zmiana koncentracji
Zasada Le Chateliera: zmiana koncentracji
A system at equilibrium is in a state of dynamic balance, with forward and reverse reactions taking place at equal rates. If an equilibrium system is ...
Zasada Le Chateliera: zmiana objętości (ciśnienia)
Zasada Le Chateliera: zmiana objętości (ciśnienia)
For gas-phase equilibria, changes in the concentrations of reactants and products can occur with altered volume and pressure. The partial pressure, P, of ...
Zasada Le Chateliera: Zmiana temperatury
Zasada Le Chateliera: Zmiana temperatury
Consistent with the law of mass action, an equilibrium stressed by a change in concentration will shift to re-establish equilibrium without any change in ...
Założenie Małe x
Założenie Małe x
If a reaction has a small equilibrium constant, the equilibrium position favors the reactants. In such reactions, a negligible change in concentration may ...
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