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Chapter 15

Acids and Bases

Bronsted-Lowry Acids and Bases
Bronsted-Lowry Acids and Bases
The acid-base reaction class has been studied for quite some time. In 1680, Robert Boyle reported traits of acid solutions that included their ability to ...
Acid/Base Strengths and Dissociation Constants
Acid/Base Strengths and Dissociation Constants
The relative strength of an acid or base is the extent to which it ionizes when dissolved in water. If the ionization reaction is essentially complete, ...
Water: A Bronsted-Lowry Acid and Base
Water: A Bronsted-Lowry Acid and Base
The reaction between a Brønsted-Lowry acid and water is called acid ionization. For example, when hydrogen fluoride dissolves in water and ionizes, ...
pH Scale
pH Scale
Hydronium and hydroxide ions are present both in pure water and in all aqueous solutions, and their concentrations are inversely proportional as ...
Relative Strengths of Conjugate Acid-Base Pairs
Relative Strengths of Conjugate Acid-Base Pairs
Brønsted-Lowry acid-base chemistry is the transfer of protons; thus, logic suggests a relation between the relative strengths of conjugate acid-base ...
Strong Acid and Base Solutions
Strong Acid and Base Solutions
A strong acid is a compound that dissociates completely in an aqueous solution and produces a concentration of hydronium ions equal to the initial ...
Weak Acid Solutions
Weak Acid Solutions
Few compounds act as strong acids. A far greater number of compounds behave as weak acids and only partially react with water, leaving a large majority of ...
Weak Base Solutions
Weak Base Solutions
Some compounds produce hydroxide ions when dissolved by chemically reacting with water molecules. In all cases, these compounds react only partially and ...
Mixtures of Acids
Mixtures of Acids
The pH of a solution containing an acid can be determined using its acid dissociation constant and its initial concentration. If a solution contains two ...
Ions as Acids and Bases
Ions as Acids and Bases
Salts with Acidic Ions Salts are ionic compounds composed of cations and anions, either of which may be capable of undergoing an acid or base ionization ...
Determining the pH of Salt Solutions
Determining the pH of Salt Solutions
The pH of a salt solution is determined by its component anions and cations. Salts that contain pH-neutral anions and the hydronium ion-producing cations ...
Polyprotic Acids
Polyprotic Acids
Acids are classified by the number of protons per molecule that they can give up in a reaction. Acids such as HCl, HNO3, and HCN that contain one ...
Acid Strength and Molecular Structure
Acid Strength and Molecular Structure
Binary Acids and Bases In the absence of any leveling effect, the acid strength of binary compounds of hydrogen with nonmetals (A) increases as the H-A ...
Lewis Acids and Bases
Lewis Acids and Bases
In 1923, G. N. Lewis proposed a generalized definition of acid-base behavior in which acids and bases are identified by their ability to accept or to ...
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