Jevgenij A. Raskatov

DFT calculations on [6.8]cyclacenes and CpCo-capped [4.8]cyclacenes.

Ir-Catalyzed asymmetric allylic substitutions with (phosphoramidite)Ir complexes-resting states, synthesis, and characterization of catalytically active (pi-allyl)Ir complexes.

Determination of the conformation of the key intermediate in an enantioselective palladium-catalyzed allylic substitution from residual dipolar couplings.

Ir-catalysed asymmetric allylic substitutions with cyclometalated (phosphoramidite)Ir complexes--resting states, catalytically active (pi-allyl)Ir complexes and computational exploration.

Exploring the reactions of CO2 with PCP supported nickel complexes.

Expanding the repertoire of natural product-inspired ring pairs for molecular recognition of DNA.

The origins of enantioselectivity in Rh-diene complex catalysed arylation of cyclohex-2-enones.

Modulation of NF-κB-dependent gene transcription using programmable DNA minor groove binders.

Pharmacokinetics of Py-Im polyamides depend on architecture: cyclic versus linear.

Characterization and solubilization of pyrrole-imidazole polyamide aggregates.

Gene expression changes in a tumor xenograft by a pyrrole-imidazole polyamide.

Iridium-catalyzed allylic substitutions with cyclometalated phosphoramidite complexes bearing a dibenzocyclooctatetraene ligand: preparation of (π-allyl)Ir complexes and computational and NMR spectroscopic studies.

Activity of a Py-Im polyamide targeted to the estrogen response element.

A C-14 labeled Py-Im polyamide localizes to a subcutaneous prostate cancer tumor.

Tumor xenograft uptake of a pyrrole-imidazole (Py-Im) polyamide varies as a function of cell line grafted.

Genome-Directed Lead Discovery: Biosynthesis, Structure Elucidation, and Biological Evaluation of Two Families of Polyene Macrolactams against Trypanosoma brucei.

An HRE-Binding Py-Im Polyamide Impairs Hypoxic Signaling in Tumors.

4-Azidobenzyl ferrocenylcarbamate as an anticancer prodrug activated under reductive conditions.

Strict Regiospecificity of Human Epithelial 15-Lipoxygenase-2 Delineates Its Transcellular Synthesis Potential.

Introduction of d-Glutamate at a Critical Residue of Aβ42 Stabilizes a Prefibrillary Aggregate with Enhanced Toxicity.

Using chiral peptide substitutions to probe the structure function relationship of a key residue of Aβ42.