Ulf-Peter Apfel

Synthesis and characterization of hydroxy-functionalized models for the active site in Fe-only-hydrogenases.

Oxidation of diiron and triiron sulfurdithiolato complexes: mimics for the active site of [FeFe]-hydrogenase.

Investigation of amino acid containing [FeFe] hydrogenase models concerning pendant base effects.

Reaction of Fe3(CO)12 with octreotide--chemical, electrochemical and biological investigations.

Reactions of 7,8-dithiabicyclo[4.2.1]nona-2,4-diene 7-exo-oxide with dodecacarbonyl triiron Fe3(CO)12: a novel type of sulfenato thiolato diiron hexacarbonyl complexes.

Models for the active site in [FeFe] hydrogenase with iron-bound ligands derived from bis-, tris-, and tetrakis(mercaptomethyl)silanes.

Efficient activation of the greenhouse gas CO2.

A C2-symmetric, basic Fe(III) carboxylate complex derived from a novel triptycene-based chelating carboxylate ligand.

Aging-associated enzyme human clock-1: substrate-mediated reduction of the diiron center for 5-demethoxyubiquinone hydroxylation.

Detection of nitric oxide and nitroxyl with benzoresorufin-based fluorescent sensors.

Triptycene-based Bis(benzimidazole) Carboxylate-Bridged Biomimetic Diiron(II) Complexes.

[FeFe]-hydrogenase models assembled into vesicular structures.

Biomimetic assembly of the [FeFe] hydrogenase: synthetic mimics in a biological shell.

Versatile reactivity of a solvent-coordinated diiron(II) compound: synthesis and dioxygen reactivity of a mixed-valent Fe(II)Fe(III) species.

A sterically stabilized FeI-FeI semi-rotated conformation of [FeFe] hydrogenase subsite model.

Modulation of extrasynaptic NMDA receptors by synaptic and tonic zinc.

Controlled Flexible Coordination in Tripodal Iron(II) Phosphane Complexes: Effects on Reactivity.

[FeFe]-Hydrogenase with Chalcogenide Substitutions at the H-Cluster Maintains Full H2 Evolution Activity.

Stepwise isotope editing of [FeFe]-hydrogenases exposes cofactor dynamics.

Pentlandite rocks as sustainable and stable efficient electrocatalysts for hydrogen generation.

Electrochemical Investigations of the Mechanism of Assembly of the Active-Site H-Cluster of [FeFe]-Hydrogenases.

Organometallic Fe-Fe Interactions: Beyond Common Metal-Metal Bonds and Inverse Mixed-Valent Charge Transfer.

Sunlight-Dependent Hydrogen Production by Photosensitizer/Hydrogenase Systems.

Spontaneous Si-C bond cleavage in (Triphos(Si))-nickel complexes.

Mobile zinc increases rapidly in the retina after optic nerve injury and regulates ganglion cell survival and optic nerve regeneration.

Redox Induced Configurational Isomerization of Bisphosphine-Tricarbonyliron(I) Complexes and the Difference a Ferrocene Makes.