Name: a protocol for electrochemical evaluations and state of charge diagnostics of a symmetric organic redox flow battery
Uploaded: 2017-02-13T12:30:00
Description: Watch this Scientific Journal Video about A Protocol for Electrochemical Evaluations and State of Charge Diagnostics of a Symmetric Organic Redox Flow Battery at JoVE.com

这项工作在财政联合中心储能研究（JCESR），由能源，科学办公室，基础能源科学，美国能源部资助的能源创新中心的支持。作者也承认期刊材料化学A（化学杂志的英国皇家学会）为最初发布此研究（ <a href="http://pubs.rsc.org/en/content/articlehtml/2016/ta/c6ta01177b">http://pubs.rsc.org/en/content/articlehtml/2016/ta/c6ta01177b</a> ）。 PNNL根据合同DE-AC05-76RL01830能源部巴特尔操作多项目国家实验室。

注意：所有的溶液制剂，循环伏安（CV）测试，和流动池的组装和测试在充满氩气的手套箱中进行的与低于1ppm水和O 2的水平。 1. PTIO流动池的电化学评估<ol><li> CV测试 <ol><li>抛光用0.05微米的γ-氧化铝粉末的玻璃碳电极，用去离子水冲洗它，把它放在真空下，在室温下搅拌过夜，并将其转移到手套箱中。 </li><li>溶解硝酸银（8.5毫克）用MeCN（5mL）中在手套?...

<ol>
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Y., et al. <a target="_blank" href="http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?db=PubMed&cmd=Search&doptcmdl=Citation&defaultField=Title+Word&term=Polysulfide+Flow+Batteries+Enabled+by+Percolating+Nanoscale+Conductor+Networks.">Polysulfide Flow Batteries Enabled by Percolating Nanoscale Conductor Networks.</a> Nano Lett. 14 (4), 2210-2218 (2014).</li><li>Pan, H., et al. <a target="_blank" href="http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?db=PubMed&cmd=Search&doptcmdl=Citation&defaultField=Title+Word&term=On+the+Way+Toward+Understanding+Solution+Chemistry+of+Lithium+Polysulfides+for+High+Energy+Li-S+Redox+Flow+Batteries.">On the Way Toward Understanding Solution Chemistry of Lithium Polysulfides for High Energy Li-S Redox Flow Batteries.</a> Adv. Energy Mater. 5 (16), 1500113 (2015).</li><li>Escalante-Garcia, I. L., Wainright, J. S., Thompson, L. T., Savinell, R. 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D. <a target="_blank" href="http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?db=PubMed&cmd=Search&doptcmdl=Citation&defaultField=Title+Word&term=On+the+Benefits+of+a+Symmetric+Redox+Flow+Battery.">On the Benefits of a Symmetric Redox Flow Battery.</a> J. Electrochem. Soc. 163 (3), 338-344 (2016).</li><li>Kim, H. S., et al. <a target="_blank" href="http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?db=PubMed&cmd=Search&doptcmdl=Citation&defaultField=Title+Word&term=A+Tetradentate+Ni(II)+Complex+Cation+as+a+Single+Redox+Couple+for+Non-aqueous+Flow+Batteries.">A Tetradentate Ni(II) Complex Cation as a Single Redox Couple for Non-aqueous Flow Batteries.</a> J. Power Sources. 283, 300-304 (2015).</li><li>Shinkle, A. A., Sleightholme, A. E. S., Griffith, L. D., Thompson, L. T., Monroe, C. 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如我们之前显示出，25 FTIR能够非侵入性地检测PTIO液流电池的SOC。作为一种诊断工具，FTIR是因为它拆装方便，响应速度快，成本低，占地面积小，对网上注册成立，没有检测器的饱和，以及相关的结构信息，调查液流电池操作过程中的分子进化的能力，设施的特别有利。 图3E说明了提出的液流电池设备集成在线红外传感器，使得安全运行实时监控SOC。 <p class="jove_...

氧化还原液流电池存储的能量在包含在外部水库和被泵送到内部电极以完成电化学反应液体电解质。储存的能量和动力因此可以分离导致了出色的设计灵活性，可扩展性和模块化。这些优点使液流电池非常适合于集成清洁还间歇性可再生能源的固定能量存储应用，增加格资产利用和效率，和提高能源弹性和安全性。 1，2，3传统的水液流电池从有限的能量密度的困扰，主要是由于狭窄的电压窗口，以避免电解水。 4，5，6，7，8与此相反，非aque基于液流电池的OU电解质因为用于实现高电池电压，高能量密度的潜力被广泛开展。 9，10在这些努力中，各种流量电池化学组成进行了研究，其中包括金属配合物，11，12全有机，13，14的氧化还原活性聚合物，15和锂的混合流动系统。 16，17，18，19 然而，非水液流电池的潜力尚未得到充分展现，由于液流电池相关的条件下，有限的示范的主要技术瓶颈。这个瓶颈是密切多项性能限制性因素有关。第一，大多数电活性材料的小的溶解度的非水流动细胞导致低的能量密度输送。第二，非水液流电池的速率能力主要是由高电解质的粘度和电阻率在相关的氧化还原的浓度限制。第三个因素是缺乏高性能膜。的Nafion和陶瓷膜表现出与非水电解质的低离子传导性。多孔分离器已经证实体面流动池的性能，但是遭受相当大的自放电，因为相对大的孔径。 14，20通常情况下，同时含有阳极电解液和阴极电解液的氧化还原物质的混合反应物电解质（1：1的比例）用于减少氧化还原材料交叉，然而这牺牲了有效的氧化还原浓度，典型地通过一半。 14，21克服上述瓶颈，需要改进母校IALS发现，电池化学设计和流动池结构实现电池相关的循环。 电池状态监测是可靠的操作基本上是很重要的。非正常状态，包括过充电，气体逸出，以及材料的降解可能导致损害电池性能和甚至电池故障。尤其是对于涉及大量电池材料大规模液流电池，这些因素可能会导致严重的安全问题和投资损失。充电状态（SOC），说明电荷或液流电池的放电深度的状态是最重要的电池状态参数中的一个。他们到达危险的水平之前及时SOC的监测可以检测到潜在的风险。然而，该区域似乎是迄今为止下寻址，特别是在非水液流电池。 Spectrophotoscopic方法如紫外可见（UV-VIS）光谱和电解质电导率测量已经在水性流蓄电池装填评价<html> RY的SOC判定。 22，23，24 我们最近引进了基于新的双极的氧化还原物质的新的对称的非水液流电池设计，2-苯基-4,4,5,5- tetramethylimidazoline -1-氧基-3-氧化物（PTIO）。 25此液流电池保持承诺解决非水液流电池前述的挑战。首先，PTIO在乙腈中的电池溶剂（乙腈），该被看好，以使高能量密度的高溶解度（2.6 M）。第二，PTIO呈现被适度分离并因此可以通过本身构成了一个对称电池化学两可逆等的氧化还原对。我们还证明了在FTIR光谱的可分辨的PTIO峰可与未反应的PTIO的流动池中，这导致分光SOC的测定，用ESR结果交叉验证的浓度相关联。姑娘=“外部参照”&gt; 26在这里，我们提出了一个协议，以拟定电化学评估和PTIO对称液流电池的基于FTIR的SOC诊断过程。这项工作预计在长期液流电池业务保持了安全性和可靠性，尤其是在现实世界电网应用触发更多的见解。

<table border="1" fo:keep-together.within-page="1" fo:keep-with-next.within-page="always">
	<tbody>
		<tr>
			<td>PTIO</td>
			<td>TCI America</td>
			<td>A5440</td>
			<td>&#62;98.0%</td>
		</tr>
		<tr>
			<td>Tetrabutylammonium hexafluorophosphate</td>
			<td>Sigma-Aldrich</td>
			<td>86879</td>
			<td>electrochemical grade, &#8805;99.0%</td>
		</tr>
		<tr>
			<td>MeCN</td>
			<td>BASF</td>
			<td>50325685</td>
			<td>Battery grade</td>
		</tr>
		<tr>
			<td>Silver nitrate</td>
			<td>Sigma-Aldrich</td>
			<td>204390</td>
			<td>99.9999% trace metals basis</td>
		</tr>
		<tr>
			<td>Gamma alumina powder</td>
			<td>CH Instruments</td>
			<td>CHI120</td>
			<td></td>
		</tr>
		<tr>
			<td>Graphite felt</td>
			<td>SGL</td>
			<td>GFD3</td>
			<td>Vacuum-dry at 70&#176;C for 24 h</td>
		</tr>
		<tr>
			<td>Porous separator</td>
			<td>Daramic</td>
			<td>AA800</td>
			<td>Vacuum-dry at 70&#176;C for 24 h</td>
		</tr>
		<tr>
			<td>Battery Tester</td>
			<td>Wuhan LAND electronics Co., Ltd.</td>
			<td>Lanhe</td>
			<td>1A current range</td>
		</tr>
		<tr>
			<td>Electrochemical Workstation</td>
			<td>Solartron Analytical</td>
			<td>ModuLab</td>
			<td></td>
		</tr>
		<tr>
			<td>glove box</td>
			<td>MBRAUN</td>
			<td>Labmaster SP</td>
			<td>oxygen and water levels &#60;1 ppm</td>
		</tr>
		<tr>
			<td>ESR spectrometer</td>
			<td>Bruker&#160;</td>
			<td>Elexsys 580&#160;</td>
			<td>Equipped with an SHQE resonator with microwave frequency ~9.85 GHz (X band) at 2 mW power, with 100 kHz field modulation</td>
		</tr>
	</tbody>
</table>

a protocol for electrochemical evaluations and state of charge diagnostics of a symmetric organic redox flow battery

氧化还原液流电池已被认为是用于改善的可再生能源技术的电网和部署的可靠性的最有希望的静止能量存储解决方案之一。在众多的流动化学电池，非水液流电池具有实现的，因为非水电解质的宽电压窗口的高能量密度的潜力。然而，显著技术障碍存在目前限制非水液流电池以证明其全部潜力，如低氧化还原浓度，低工作电流，欠探索电池状态监视等在试图解决这些限制，我们最近报道了基于高度可溶的，氧化还原活性有机氮氧自由基化合物的非水液流电池，2-苯基-4,4,5,5- tetramethylimidazoline -1-氧基-3-氧化物（PTIO）。这种氧化还原材料表现出双极电化学特性，因此可以作为既anolyte和阴极电解液的氧化还原物质，以形成对称的液流电池化学。此外，我们证明了傅里叶变换红外光谱（FTIR）可以测量PTIO浓度PTIO液流电池循环过程中，并提供充电量（SOC）的电池状态的相当准确的检测，如通过电子自旋共振（ESR）的测量交叉验证。在此，我们提出了PTIO对称液流电池的电化学评估和诊断SOC的视频协议。用的详细描述，我们实验证明的路线来实现这样的目的。该协议的目的是引发关于在非水氧化还原液流电池领域的安全性和可靠性更加的兴趣和见解。

对称PTIO液流电池系统的独特的优点是高度归因于PTIO，有机氮氧自由基化合物的电化学性能。 PTIO可以经历电化学歧化反应以形成PTIO +和PTIO - （ 图2a）。这两个氧化还原对是由〜电压间隙适度分开1.7 V（ 图2b），并且可以同时用作阳极电解液和阴极电解液的氧化还原物质中的对称电池化学。使用PTIO作为氧化还原物质可以消除混合反...

Watch this Scientific Journal Video about A Protocol for Electrochemical Evaluations and State of Charge Diagnostics of a Symmetric Organic Redox Flow Battery at JoVE.com

A Protocol for Electrochemical Evaluations and State of Charge Diagnostics of a Symmetric Organic Redox Flow Battery

我们提出的协议电化学评估对称非水有机氧化还原液流电池和用于诊断其用FTIR充电状态。

- 电化学评估和对称有机氧化还原液流电池的充电诊断状态协议

Redox flow batteries have been considered as one of the most promising stationary energy storage solutions for improving the reliability of the power grid ...

Research

JoVE Journal

Chemistry

Steady-state, Pre-steady-state, and Single-turnover Kinetic Measurement for DNA Glycosylase Activity

稳态，稳定前的状态，单营业额动力学测量DNA糖基化酶活性

Human 8-oxoguanine DNA glycosylase (OGG1) excises the mutagenic oxidative DNA lesion 8-oxo-7,8-dihydroguanine (8-oxoG) from DNA. Kinetic characterization ...

科研

化学

Analysis of Volatile and Oxidation Sensitive Compounds Using a Cold Inlet System and Electron Impact Mass Spectrometry

挥发和氧化敏感的化合物使用冷进气系统和电子轰击质谱分析

This video presents a protocol for the mass spectrometrical analysis of volatile and oxidation sensitive compounds using electron impact ionization. The ...

Dynamic Electrochemical Measurement of Chloride Ions

氯离子的动态电化学测试

This protocol describes the dynamic measurement of chloride ions using the transition time of a silver silver chloride (Ag/AgCl) electrode. Silver silver ...

Glycan Node Analysis: A Bottom-up Approach to Glycomics

聚糖节点分析：自下而上的方法，以糖原组学

Synthesized in a non-template-driven process by enzymes called glycosyltransferases, glycans are key players in various significant intra- and ...

Synthesis of Cyclic Polymers and Characterization of Their Diffusive Motion in the Melt State at the Single Molecule Level

环状聚合物的合成及其在熔融状态扩散运动的表征在单分子水平

We demonstrate a method for the synthesis of cyclic polymers and a protocol for characterizing their diffusive motion in a melt state at the single ...

Using Capillary Electrophoresis to Quantify Organic Acids from Plant Tissue: A Test Case Examining Coffea arabica Seeds

Using Capillary Electrophoresis to Quantify Organic Acids from Plant Tissue: A Test Case Examining Coffea arabica Seeds

利用毛细管电泳从植物组织量化有机酸：一个测试用例检查<em&gt;小粒种咖啡</em&gt;种子

Carboxylic acids are organic acids containing one or more terminal carboxyl (COOH) functional groups. Short chain carboxylic acids (SCCAs; carboxylic ...

Electrochemical Impedance Spectroscopy as a Tool for Electrochemical Rate Constant Estimation

电化学阻抗谱作为电化学速率常数估计的一种工具

Electrochemical impedance spectroscopy (EIS) was used for advanced characterization of organic electroactive compounds along with cyclic voltammetry (CV). ...

Controlled Photoredox Ring-Opening Polymerization of O-Carboxyanhydrides Mediated by Ni/Zn Complexes

Controlled Photoredox Ring-Opening Polymerization of O-Carboxyanhydrides Mediated by Ni/Zn Complexes

镍/锌配合物介导的O-Carboxyanhydrides 的控制 Photoredox 环开聚合

Here, we describe an effective protocol that combines photoredox Ni/Ir catalysis with the use of a Zn-alkoxide for efficient ring-opening polymerization, ...

Ion Mobility-Mass Spectrometry Techniques for Determining the Structure and Mechanisms of Metal Ion Recognition and Redox Activity of Metal Binding Oligopeptides

用于测定金属结合寡聚肽的金属电子识别和机制的Ion流动性-质谱技术

Electrospray ionization (ESI) can transfer an aqueous-phase peptide or peptide complex to the gas-phase while conserving its mass, overall charge, ...

Evaluation of Oxidative Stress in Biological Samples Using the Thiobarbituric Acid Reactive Substances Assay

使用硫代巴比妥酸反应物质测定法评估生物样品中的氧化应激

Despite its limited analytical specificity and ruggedness, the thiobarbituric acid reactive substances (TBARS) assay has been widely used as a generic ...