Name: preparation of polyoxometalate-based photo-responsive membranes for the photo-activation of manganese oxide catalysts
Uploaded: 2018-08-07T14:30:00
Description: Watch this Scientific Journal Video about Preparation of Polyoxometalate-based Photo-responsive Membranes for the Photo-activation of Manganese Oxide Catalysts at JoVE.com

a.y. 获得了东京大学机械系统创新项目全球卓越中心的财政支持, 并得到了东京大学博士学位研究的东京都补助金。这项工作部分是由 jsp KAKENHI 资助的青年科学家 (B) (17K17718) 所支持的。

在使用化学品之前, 最好参考所有相关的材料安全数据表 (MSDS), 因为这些合成中的一些使用是高酸性和腐蚀性的。此外, 在这项工作中使用的一种聚合物 (聚丙烯酰胺) 可能含有致癌单体, 丙烯酰胺。使用个人防护设备 (安全眼镜, 手套, 实验室大衣, 全长长裤, 闭合脚趾鞋), 以防止伤害化学品或热。在进行交联过程后, 应将膜样品储存在黑暗条件下的水中, 以避免干燥和任何不必要的光化学反应的发生?...

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J. <a target="_blank" href="http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?db=PubMed&cmd=Search&doptcmdl=Citation&defaultField=Title+Word&term=Density+Functional+Study+of+the+Vibrational+Frequencies+of+&#945;-Keggin+Heteropolyanions.">Density Functional Study of the Vibrational Frequencies of &#945;-Keggin Heteropolyanions.</a> Chemical Physics. 287, 55-69 (2003).</li><li>Meng, Y., Song, W., Huang, H., Ren, Z., Chen, S. -. Y., Suib, S. 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应用海伦等的交联方法是至关重要的。14开发一种独立的膜。本研究以聚醋酸乙烯为基聚合物, 对 H312O40进行聚集体, 防止自立膜的形成。然而, 当利用 Nafion 作为基聚合物制备膜时, 与 Ce3 +和 Co2 +的反应没有进展, 虽然已经实现了自立膜的制备。在本研究中, 为了保证整个膜的电子传递, 加载量被修改为 80 wt% H3密码12O<s...

利用人工光合作用或太阳能电池开发太阳能转换系统是必要的, 以便提供可替代的能源, 以改善全球气候和能源问题1、2、 3,4。光功能材料可以大致分为两组, 基于半导体的系统和基于有机分子的系统。虽然已经开发了许多不同的系统类型, 但仍需改进, 因为半导体系统缺乏精确的电荷转移控制, 而有机分子系统在光辐照。然而, 使用无机分子作为电荷转移单元的组成部分可以改善这些各自的问题。例如, 在介孔二氧化硅表面接枝的氧化桥型金属系统可以通过光辐照诱导金属-金属电荷转移 (MMCT), 并触发光化学氧化还原反应5,6,7,8,9。
我们的小组将单一原子系统扩展到一个多核系统, 利用 polyoxometalate (POM) 作为电子受体10,11,12, 并期望使用多核系统将是有利于诱导和控制多电子转移反应, 是能量转换中的一个重要概念。在本文所描述的协议中, 我们提出了用于准备基于 POM 的 MMCT 系统的详细方法, 它在聚合物矩阵中工作, 正如我们最近报告的13。膜型结构有利于阳极和阴极反应产物的分离。采用交联法, 即使具有高聚甲醛含量, 也能够形成自立膜。光电测量证明, 适当选择供体金属是触发目标的关键。POM/供体金属系统作为一种光敏剂在可见光照射下活化多电子转移催化剂。虽然这项工作利用 MnOx作为一个多电子转移催化剂的水氧化反应, 这一光功能系统也适用于其他类型的反应, 利用不同的, 捐助金属和催化剂。

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	<tbody>
		<tr height="42">
			<td height="42" style="height:42px;width:287px;">Poly(vinyl Alcohol) 1000, Completely Hydrolyzed</td>
			<td style="width:119px;">Wako</td>
			<td style="width:119px;">162-16325</td>
			<td style="width:295px;"></td>
		</tr>
		<tr height="42">
			<td height="42" style="height:42px;width:287px;">Polyacrylamide, Mv 6,000,000</td>
			<td style="width:119px;">Polyaciences, Inc.</td>
			<td style="width:119px;">2806</td>
			<td>May contain carcinogenic monomer, acrylamide.</td>
		</tr>
		<tr height="21">
			<td height="21" style="height:21px;width:287px;">12 Tungsto(VI)phosphoric Acid n-Hydrate</td>
			<td style="width:119px;">Wako</td>
			<td style="width:119px;">164-02431</td>
			<td>Highly acidic</td>
		</tr>
		<tr height="21">
			<td height="21" style="height:21px;width:287px;">Acetone 99.5 + %(GC)</td>
			<td style="width:119px;">Wako</td>
			<td style="width:119px;">012-00343</td>
			<td></td>
		</tr>
		<tr height="21">
			<td height="21" style="height:21px;width:287px;">25% Glutaraldehyde Solution</td>
			<td style="width:119px;">Wako</td>
			<td style="width:119px;">079-00533</td>
			<td></td>
		</tr>
		<tr height="21">
			<td height="21" style="height:21px;width:287px;">Hydrochloric Acid 35-37%</td>
			<td style="width:119px;">Wako</td>
			<td style="width:119px;">080-01066</td>
			<td></td>
		</tr>
		<tr height="21">
			<td height="21" style="height:21px;width:287px;">Cerium(III) Nitrate Hexahydrate 98 + %(Ti)</td>
			<td style="width:119px;">Wako</td>
			<td style="width:119px;">031-09732</td>
			<td></td>
		</tr>
		<tr height="21">
			<td height="21" style="height:21px;width:287px;">Cobalt(II) Chloride Hexahydrate 99 + %(Ti)</td>
			<td style="width:119px;">Wako</td>
			<td style="width:119px;">036-03682</td>
			<td></td>
		</tr>
		<tr height="21">
			<td height="21" style="height:21px;width:287px;">Pottasium Permanganate 99.3 + %(Ti)</td>
			<td style="width:119px;">Wako</td>
			<td style="width:119px;">167-04182</td>
			<td>Highly oxydative</td>
		</tr>
		<tr height="42">
			<td height="42" style="height:42px;width:287px;">Sodium Thiosulfate Pentahydrate 99 + %(Ti)</td>
			<td style="width:119px;">Wako</td>
			<td style="width:119px;">197-03585</td>
			<td></td>
		</tr>
		<tr height="21">
			<td height="21" style="height:21px;width:287px;">Automatic spray gun</td>
			<td style="width:119px;">Lumina</td>
			<td style="width:119px;">ST-6</td>
			<td></td>
		</tr>
	</tbody>
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preparation of polyoxometalate-based photo-responsive membranes for the photo-activation of manganese oxide catalysts

本文提出了一种用 polyoxotungstate (12O403-)、过渡金属离子 (Ce3 +或 Co2 +) 和有机聚合物制备电荷转移染色体的方法, 其目的是实现光激活。氧演化氧化锰催化剂, 是人工光合作用的重要组成部分。采用交联技术获得了高12O403含量的自立膜。采用红外光谱和显微拉曼光谱法, 对12O403-聚合物基体中的密码的加入和结构保留进行了验证, 并通过紫外-可见光谱研究了光学特性, 揭示了金属-金属电荷转移 (MMCT) 单元的成功构造。在 MnOx氧进化催化剂沉积后, 可见光照射下的光电流测量验证了顺序电荷转移、锰→ MMCT 单元→电极, 光电流强度与氧化还原反应一致。供方金属 (Ce 或 Co) 的潜力。该方法为制备具有光功能材料的催化剂和光子吸收部件的集成系统提供了一种新的策略。

通过红外光谱和显微拉曼光谱 (图 1) 证实了聚合物基体中 POM 结构的保留;观察了与 pom Keggin 结构相对应的振动峰, 发现聚合物的峰值由于与 pom 的氢键结合而转移。光谱学分析对于确定电荷转移单元的成功构造非常有用, 而且样品的表面颜色变化也证实了这一点 (图 2)。它也得到了紫外-可见光谱和光电测量 (图 3</s...

Watch this Scientific Journal Video about Preparation of Polyoxometalate-based Photo-responsive Membranes for the Photo-activation of Manganese Oxide Catalysts at JoVE.com

Preparation of Polyoxometalate-based Photo-responsive Membranes for the Photo-activation of Manganese Oxide Catalysts

氧化锰催化剂光活化 Polyoxometalate 基光响应膜的制备

在这里, 我们提出了一个协议, 以准备电荷转移染色体基于 polyoxometalate/聚合物复合膜。

This paper presents a method to prepare charge-transfer chromophores using polyoxotungstate (PW12O403-), transition metal ions (Ce3+ or Co2+), and organic ...

Research

JoVE Journal

Chemistry

Atomically Defined Templates for Epitaxial Growth of Complex Oxide Thin Films

原子定义模板复合氧化物薄膜的外延生长

Atomically defined substrate surfaces are prerequisite for the epitaxial growth of complex oxide thin films. In this protocol, two approaches to obtain ...

科研

化学

Preparation of Highly Porous Coordination Polymer Coatings on Macroporous Polymer Monoliths for Enhanced Enrichment of Phosphopeptides

对磷酸增强富集制备高度多孔配位聚合物涂层的孔聚合物石柱的

We describe a protocol for the preparation of hybrid materials based on highly porous coordination polymer coatings on the internal surface of macroporous ...

Photochemical Oxidative Growth of Iridium Oxide Nanoparticles on CdSe@CdS Nanorods

铱氧化物纳米颗粒对硒化镉硫化镉@纳米棒光化学氧化增长

We demonstrate a procedure for the photochemical oxidative growth of iridium oxide catalysts on the surface of seeded cadmium selenide-cadmium sulfide ...

Temperature-programmed Deoxygenation of Acetic Acid on Molybdenum Carbide Catalysts

对碳化钼催化合成乙酸的程序升温脱氧

Temperature programmed reaction (TPRxn) is a simple yet powerful tool for screening solid catalyst performance at a variety of conditions. A TPRxn system ...

Synthesis and Testing of Supported Pt-Cu Solid Solution Nanoparticle Catalysts for Propane Dehydrogenation

用于丙烷脱氢的负载型Pt-Cu固溶体纳米粒子催化剂的合成与测试

A convenient method for the synthesis of bimetallic Pt-Cu catalysts and performance tests for propane dehydrogenation and characterization are ...

Aerosol-assisted Chemical Vapor Deposition of Metal Oxide Structures: Zinc Oxide Rods

金属氧化物结构的气溶胶辅助化学气相沉积: 氧化锌棒

Whilst columnar zinc oxide (ZnO) structures in the form of rods or wires have been synthesized previously by different liquid- or vapor-phase routes, ...

Chemical Precipitation Method for the Synthesis of Nb2O5 Modified Bulk Nickel Catalysts with High Specific Surface Area

Chemical Precipitation Method for the Synthesis of Nb2O5 Modified Bulk Nickel Catalysts with High Specific Surface Area

化学沉淀法合成铌2O5改性高比表面积镍催化剂

We demonstrate a method for the synthesis of NixNb1-xO catalysts with sponge-like and fold-like nanostructures. By varying the Nb:Ni ratio, a series of ...

Electrophoretic Crystallization of Ultrathin High-performance Metal-organic Framework Membranes

超薄高性能金属-有机骨架膜的电泳结晶

We report the synthesis of thin, highly intergrown, polycrystalline metal-organic framework (MOF) membranes on a wide range of unmodified porous and ...

Imine Metathesis by Silica-Supported Catalysts Using the Methodology of Surface Organometallic Chemistry

利用表面有机金属化学方法，利用硅支持的催化剂进行Imine金属分析

With this protocol, a well-defined singlesite silica-supported heterogeneous catalyst [(&#8801;Si-O-)Hf(=NMe)(&#951;1-NMe2)] is designed and prepared ...

Tuning the Acidity of Pt/ CNTs Catalysts for Hydrodeoxygenation of Diphenyl Ether

调整二苯醚氢氧化的Pt/CNT催化剂的酸度

We herein present a method for the synthesis of HNbWO6, HNbMoO6, HTaWO6 solid acid nanosheet modified Pt/CNTs. By varying the weight of various solid acid ...