Andreas Schnepf

Chemistry Department, University of Tübingen

Research Area

Chemistry

Biography

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JoVE Journal Publications

Article Total : 1	Year
Publication title	2016

Other Publications

Article	Year
Ge4Br4[Mn(CO)5]4 and Ge6Br2[Mn(CO)5]6: first germanium cluster compounds containing Mn(CO)5 ligands. Dalton transactions (Cambridge, England : 2003)\| PubMed ID: 18026588	2007
Synthesis and Structure of a Ga(84)R(20)(4-) Cluster-A Link between Metalloid Clusters and Fullerenes? This work, which had originally been submitted to Nature in September 1999 and has been... Angewandte Chemie (International ed. in English)\| PubMed ID: 11241599	2001
A Ga(8)R(6) Cluster as an Ideal Model for a Metal-Metal Bond? This work was supported by the Deutsche Forschungsgemeinschaft and by the Fonds der Chemischen Industrie. Angewandte Chemie (International ed. in English)\| PubMed ID: 11301437	2001
Metalloid aluminum and gallium clusters: element modifications on the molecular scale? Angewandte Chemie (International ed. in English)\| PubMed ID: 12370894	2002
[Ge8[N(SiMe3)2]6]: a ligand-stabilized Ge cluster compound with formally zero-valent Ge atoms. Angewandte Chemie (International ed. in English)\| PubMed ID: 12596175	2003
[Ge9[Si(SiMe3)3]3]-: a soluble polyhedral Ge9 cluster stabilized by only three silyl ligands. Angewandte Chemie (International ed. in English)\| PubMed ID: 12813736	2003
Preparation and precise structural determination of a second Ga84 cluster compound. A first hint for cluster doping and its fundamental consequences in the field of chemistry and physics of ... Inorganic chemistry\| PubMed ID: 14632487	2003
Novel compounds of elements of group 14: ligand-stabilized clusters with "naked" atoms. Angewandte Chemie (International ed. in English)\| PubMed ID: 14755694	2004
Two metalloid Ga22 clusters containing a novel Ga22 core with an icosahedral Ga12 center. Chemistry (Weinheim an der Bergstrasse, Germany)\| PubMed ID: 15079837	2004
Subvalent compounds featuring direct metal-metal bonds: the Zn-Zn bond in [Cp*2Zn2]. Angewandte Chemie (International ed. in English)\| PubMed ID: 15844126	2005
Ge8R6: the ligands define the bonding situation within the cluster core. Dalton transactions (Cambridge, England : 2003)\| PubMed ID: 16193145	2005
Na6[Ge10{Fe(CO)4}8]18 THF: a centaur polyhedron of germanium atoms. Angewandte Chemie (International ed. in English)\| PubMed ID: 16847861	2006
{Ge10Si[Si(SiMe3)3]4(SiMe32)Me}-: a Ge10Si framework reveals a structural transition onto elemental germanium. Chemical communications (Cambridge, England)\| PubMed ID: 17180243	2007
Metalloid group 14 cluster compounds: an introduction and perspectives to this novel group of cluster compounds. Chemical Society reviews\| PubMed ID: 17471399	2007
[AuGe18{Si(SiMe3)3}6]-: a soluble Au-Ge cluster on the way to a molecular cable? Angewandte Chemie (International ed. in English)\| PubMed ID: 17579905	2007
[Si(SiMe(3))(3)](6)Ge(18)M (M = Cu, Ag, Au): metalloid cluster compounds as unusual building blocks for a supramolecular chemistry. Dalton transactions (Cambridge, England : 2003)\| PubMed ID: 18698446	2008
Si@Al56[N(2,6-iPr2C6H3)SiMe3]12: the largest neutral metalloid aluminum cluster, a molecular model for a silicon-poor aluminum-silicon alloy? Angewandte Chemie (International ed. in English)\| PubMed ID: 18814152	2008
Ge(14)[Ge(SiMe(3))(3)](5)Li(3)(THF)(6): the largest metalloid cluster compound of germanium: on the way to fullerene-like compounds? Chemical communications (Cambridge, England)\| PubMed ID: 18815711	2008
[(OtBu)(2)C(6)H(3)](3)Ge(+) a free germyl cation with aryl ligands. Dalton transactions (Cambridge, England : 2003)\| PubMed ID: 19156269	2009
{Ge9R3Cr(CO)5}- and {Ge9R3Cr(CO)3}-: a metalloid cluster (Ge9R3-) as a flexible ligand in coordination chemistry [R=Si(SiMe3)3]. Chemical communications (Cambridge, England)\| PubMed ID: 19587915	2009
[Ga22{N(SiMe3)2}10]2-: a metalloid cluster compound with a variation of the Ga22 framework. Angewandte Chemie (International ed. in English)\| PubMed ID: 19750621	2002
[Si(SiMe3)3]6Ge18M (M = Zn, Cd, Hg): neutral metalloid cluster compounds of germanium as highly soluble building blocks for supramolecular chemistry. Dalton transactions (Cambridge, England : 2003)\| PubMed ID: 20449189	2009
The formation of a metalloid Sn(10)[Si(SiMe(3))(3)](6) cluster compound and its relation to the alpha<-->beta tin phase transition. Dalton transactions (Cambridge, England : 2003)\| PubMed ID: 20449434	2010
Sn[Si(SiMe3)3]3- and Sn3[Si(SiMe3)3]4: first insight into the mechanism of the disproportionation of a tin monohalide gives access to the shortest double bond of tin. Chemical communications (Cambridge, England)\| PubMed ID: 20717582	2010
The formal combination of three singlet biradicaloid entities to a singlet hexaradicaloid metalloid Ge14[Si(SiMe3)3]5[Li(THF)2]3 cluster. Journal of the American Chemical Society\| PubMed ID: 21302926	2011
[Si(SiMe3)3]3Ge9M(CO)3(-) (M=Cr, Mo, W): coordination chemistry with metalloid clusters. Dalton transactions (Cambridge, England : 2003)\| PubMed ID: 21614350	2011
[Sn4Si{Si(SiMe3)3}4{SiMe3}2]: a model compound for the unexpected first-order transition from a singlet biradicaloid to a classical bonded molecule. Angewandte Chemie (International ed. in English)\| PubMed ID: 21698735	2011
{Sn9[Si(SiMe3)3]3}− and {Sn8Si[Si(SiMe3)3]3}−: variations of the E9 cage of metalloid group 14 clusters. Inorganic chemistry\| PubMed ID: 22436071	2012
{Sn9[Si(SiMe3)3]2}2-: a metalloid tin cluster compound with a Sn9 core of oxidation state zero. Inorganic chemistry\| PubMed ID: 22804582	2012
[Ge12{FeCp(CO)2}8{FeCp(CO)}2]: a Ge12 core resembles the arrangement of the high-pressure modification germanium (II). Angewandte Chemie (International ed. in English)\| PubMed ID: 23288682	2013
Dative bonds in main-group compounds: a case for fewer arrows! Angewandte Chemie (International ed. in English)\| PubMed ID: 24243854	2014
Nanoscale molecular silver cluster compounds in gram quantities. Angewandte Chemie (International ed. in English)\| PubMed ID: 24519816	2014
Dative or not dative? Angewandte Chemie (International ed. in English)\| PubMed ID: 24889370	2014
{Sn10 [Si(SiMe3 )3 ]4 }(2-) : A highly reactive metalloid tin cluster with an open ligand shell. Chemistry (Weinheim an der Bergstrasse, Germany)\| PubMed ID: 25430476	2015
Reactions with a Metalloid Tin Cluster {Sn10[Si(SiMe3)3]4}(2-): Ligand Elimination versus Coordination Chemistry. Chemistry (Weinheim an der Bergstrasse, Germany)\| PubMed ID: 25892180	2015
Reactions with a Metalloid Tin Cluster {Sn10[Si(SiMe3)3]4}(2-): Ligand Elimination versus Coordination Chemistry. Chemistry (Weinheim an der Bergstrasse, Germany)\| PubMed ID: 26095993	2015
{Ge9[Si(SiMe3)2(SiPh3)]3}(-): Ligand Modification in Metalloid Germanium Cluster Chemistry. Inorganic chemistry\| PubMed ID: 26154728	2015
The Largest Metalloid Group 14 Cluster, Ge18[Si(SiMe3)3]6 : An Intermediate on the Way to Elemental Germanium. Angewandte Chemie (International ed. in English)\| PubMed ID: 26822765	2016
IPr3 Si3 Cl5 (+) : A Highly Reactive Cation with Silanide Character. Chemistry (Weinheim an der Bergstrasse, Germany)\| PubMed ID: 27258331	2016
Reactivity of [Ge9{Si(SiMe3)3}3]- towards transition metal M2+ cations : coordination and redox chemistry. Chemistry (Weinheim an der Bergstrasse, Germany)\| PubMed ID: 27796057	2016