Chryssostomos Chatgilialoglu

Addition Reactions of Tris(trimethylsilyl)germyl Radicals to Unsaturated Compounds. An EPR and Product Study.

Chemistry of Acyl Radicals.

5-Endo-trig radical cyclizations: disfavored or favored processes?

The kinetics of thiyl radical-induced reactions of monounsaturated fatty acid esters.

Arachidonate geometrical isomers generated by thiyl radicals: the relationship with trans lipids detected in biological samples.

Geometrical isomerism of monounsaturated fatty acids: thiyl radical catalysis and influence of antioxidant vitamins.

Model studies of DNA C5' radicals. Selective generation and reactivity of 2'-deoxyadenosin-5'-yl radical.

Rate constants for the beta-elimination of tosyl radical from a variety of substituted carbon-centered radicals.

Regioselective cis-trans isomerization of arachidonic double bonds by thiyl radicals: the influence of phospholipid supramolecular organization.

Selective generation and reactivity of 5'-adenosinyl and 2'-adenosinyl radicals.

Excess electron transfer in G-quadruplex.

A biomimetic model of tandem radical damage involving sulfur-containing proteins and unsaturated lipids.

The photochemistry of 8-bromo-2'-deoxyadenosine. A direct entry to cyclopurine lesions.

Synthesis and biological evaluation of novel 1'-branched and spironucleoside analogues.

The kinetics of Z/E isomerization of methyl oleate catalyzed by photogenerated thiyl radicals.

Trans lipid formation induced by thiols in human monocytic leukemia cells.

Synthesis of all-trans arachidonic acid and its effect on rabbit platelet aggregation.

The influence of solid-state molecular organization on the reaction paths of thiyl radicals.

Trans lipids: the free radical path.

Tautomers of one-electron-oxidized guanosine.

Comparison of phosphatidylcholine vesicle properties related to geometrical isomerism.

Geometrical trans lipid isomers: a new target for lipidomics.

Trans fatty acids and atopic eczema/dermatitis syndrome: the relationship with a free radical cis-trans isomerization of membrane lipids.

Complex sequence dependence by excess-electron transfer through DNA with different strength electron acceptors.

Probing the influence of cis-trans isomers on model lipid membrane fluidity using cis-parinaric acid and a stop-flow technique.

Reductive modification of a methionine residue in the amyloid-beta peptide.

Occurrence of trans fatty acids in rats fed a trans-free diet: a free radical-mediated formation?

C5'-adenosinyl radical cyclization. A stereochemical investigation.

Trans-fatty acids and radical stress: what are the real culprits?

Chemical radiation studies of 8-bromo-2'-deoxyinosine and 8-bromoinosine in aqueous solutions.

The reaction of hydrogen atoms with methionine residues: A model of reductive radical stress causing tandem protein-lipid damage.

Tautomerism in the guanyl radical.

Reactions of hydrogen atoms with met-enkephalin and related peptides.

Independent generation of C5'-nucleosidyl radicals in thymidine and 2'-deoxyguanosine.

The sulfhydryl radical (HS(.)/S(.-)): a contender for the isomerization of double bonds in membrane lipids.

Lipid metabolism and diet: possible mechanisms of slow aging.

One-electron reduction of methanesulfonyl chloride. The fate of MeSO2Cl(.)(-) and MeSO2(.) intermediates in oxygenated solutions and their role in the cis-trans isomerization of mono-unsaturated fatty acids.

Radical carbonylation with [11C]carbon monoxide promoted by oxygen-centered radicals: experimental and DFT studies of the mechanism.

Ring opening of the cyclobutane in a thymine dimer radical anion.

Trans fatty acids in membranes: the free radical path.

(5'S)- and (5'R)-5',8-cyclo-2'-deoxyguanosine: mechanistic insights on the 2'-deoxyguanosin-5'-yl radical cyclization.

Radical reactions in aqueous medium using (Me3Si)3SiH.

Fatty acid profile of erythrocyte membranes as possible biomarker of longevity.

(Me3Si)3SiH: twenty years after its discovery as a radical-based reducing agent.

Solar one-way photoisomerisation of 5',8-cyclo-2'-deoxyadenosine.

One-electron reduction of 8-bromo-2-aminoadenosine in the aqueous phase: radiation chemical and DFT studies of the mechanism.

The reductive desulfurization of Met and Cys residues in bovine RNase A is associated with trans lipids formation in a mimetic model of biological membranes.

The fate of C5' radicals of purine nucleosides under oxidative conditions.

Synthesis of all-trans anandamide: a substrate for fatty acid amide hydrolase with dual effects on rabbit platelet activation.

Reaction of hydrated electrons with guanine derivatives: tautomerism of intermediate species.

A reevaluation of the ambident reactivity of the guanine moiety towards hydroxyl radicals.

Zinc and cadmium complexes of a plant metallothionein under radical stress: desulfurisation reactions associated with the formation of trans-lipids in model membranes.

Membrane lipidomics and the geometry of unsaturated fatty acids from biomimetic models to biological consequences.

Comparison of isoelectronic 8-HO-G and 8-NH2-G derivatives in redox processes.

Radiation chemical studies of methionine in aqueous solution: understanding the role of molecular oxygen.

Radiation-induced formation of purine 5',8-cyclonucleosides in isolated and cellular DNA: high stereospecificity and modulating effect of oxygen.

Base-promoted reaction of 5-hydroxyuracil derivatives with peroxyl radicals.

Human serum albumin modifications associated with reductive radical stress.

Investigation of excess-electron transfer in DNA double-duplex systems allows estimation of absolute excess-electron transfer and CPD cleavage rates.

Purine 5',8-cyclonucleoside lesions: chemistry and biology.

Radical-based alkylation of guanine derivatives in aqueous medium.

Linoleic acid peroxidation vs. isomerization: a biomimetic model of free radical reactivity in the presence of thiols.

Radiation-induced reductive modifications of sulfur-containing amino acids within peptides and proteins.

Rat liver mitochondrial membrane characteristics and mitochondrial functions are more profoundly altered by dietary lipid quantity than by dietary lipid quality: effect of different nutritional lipid patterns.

Lipid markers of "geometrical" radical stress: synthesis of monotrans cholesteryl ester isomers and detection in human plasma.

Role of lipid peroxidation and PPAR-δ in amplifying glucose-stimulated insulin secretion.

New insights into the reaction paths of hydroxyl radicals with 2'-deoxyguanosine.

Revisiting the reaction of hydroxyl radicals with vicinal diols in water.

Recent applications of the (TMS)3SiH radical-based reagent.

Trans fatty acids: chemical synthesis of eicosapentaenoic acid isomers and detection in rats fed a deodorized fish oil diet.

Investigation of reactions postulated to occur during inhibition of ribonucleotide reductases by 2'-azido-2'-deoxynucleotides.

Kinetic studies on the formation of sulfonyl radicals and their addition to carbon-carbon multiple bonds.

Biomimetic models of radical stress and related biomarkers.

Role of fatty acid-based functional lipidomics in the development of molecular diagnostic tools.

Non-enzymatic modifications in metallothioneins connected to lipid membrane damages: Structural and biomimetic studies under reductive radical stress.