Iniciar sesión

The earth's gravitational field produces a 'twisting force' perpendicular to the angular momentum of a spinning mass (such as a spinning top) that causes the mass to 'wobble' around the gravitational field axis in a phenomenon called precession. Similarly, the magnetic moment (μ) of a spinning nucleus precesses due to an external magnetic field directed along the z-axis. The precession of the magnetic moment vector about the magnetic field is called Larmor precession, and the angular frequency of precession (ω) is called the precessional or Larmor frequency, which is directly proportional to the applied magnetic field (B0). The proportionality constant is the gyromagnetic ratio (γ), which is fixed for each nucleus. This is because each nucleus has a unique ratio of magnetic moment to angular momentum on account of its charge and mass. For a hydrogen nucleus (a proton), the value of γ is 2.675 × 108 T−1 s−1. Expressing ω in terms of the operating frequency (ν) of the NMR instrument, rearranging the terms, and multiplying both sides of the equation by Planck's constant yields the relationship between the Larmor frequency and the energy difference between the spin states (ΔE).

Tags
Atomic NucleiLarmor PrecessionGravitational FieldAngular MomentumMagnetic MomentPrecession PhenomenonAngular FrequencyLarmor FrequencyApplied Magnetic FieldGyromagnetic RatioHydrogen NucleusNMR InstrumentPlanck s ConstantEnergy DifferenceSpin States

Del capítulo 7:

article

Now Playing

7.6 : Atomic Nuclei: Larmor Precession Frequency

Principles of Nuclear Magnetic Resonance

936 Vistas

article

7.1 : Nuclear Magnetic Resonance (NMR): Overview

Principles of Nuclear Magnetic Resonance

1.7K Vistas

article

7.2 : Atomic Nuclei: Nuclear Spin

Principles of Nuclear Magnetic Resonance

1.4K Vistas

article

7.3 : Atomic Nuclei: Nuclear Magnetic Moment

Principles of Nuclear Magnetic Resonance

957 Vistas

article

7.4 : Atomic Nuclei: Nuclear Spin State Overview

Principles of Nuclear Magnetic Resonance

775 Vistas

article

7.5 : Atomic Nuclei: Nuclear Spin State Population Distribution

Principles of Nuclear Magnetic Resonance

872 Vistas

article

7.7 : Atomic Nuclei: Magnetic Resonance

Principles of Nuclear Magnetic Resonance

577 Vistas

article

7.8 : Atomic Nuclei: Nuclear Relaxation Processes

Principles of Nuclear Magnetic Resonance

567 Vistas

article

7.9 : Atomic Nuclei: Types of Nuclear Relaxation

Principles of Nuclear Magnetic Resonance

205 Vistas

article

7.10 : NMR Spectrometers: Overview

Principles of Nuclear Magnetic Resonance

915 Vistas

article

7.11 : NMR Spectrometers: Radiofrequency Pulses and Pulse Sequences

Principles of Nuclear Magnetic Resonance

659 Vistas

article

7.12 : NMR Spectrometers: Resolution and Error Correction

Principles of Nuclear Magnetic Resonance

575 Vistas

article

7.13 : Diamagnetic Shielding of Nuclei: Local Diamagnetic Current

Principles of Nuclear Magnetic Resonance

766 Vistas

JoVE Logo

Privacidad

Condiciones de uso

Políticas

Investigación

Educación

ACERCA DE JoVE

Copyright © 2025 MyJoVE Corporation. Todos los derechos reservados