Chungbuk National University

2 ARTICLES PUBLISHED IN JoVE

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Chemistry

Development of Heterogeneous Enantioselective Catalysts using Chiral Metal-Organic Frameworks (MOFs)
Jeehwan Han *1, Seongwoo Kim *2, Mi Sun Lee 1, Min Kim 2, Nakcheol Jeong 1
1Department of Chemistry, Korea University, 2Department of Chemistry and BK21Plus Research Team, Chungbuk National University

Here, we present a protocol for active site validation of metal-organic framework catalysts by comparing stoichiometric and catalytic carbonyl-ene reactions to find out whether a reaction takes place on the inner or outer surface of metal-organic frameworks.

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Chemistry

Synthesis of Triazole and Tetrazole-Functionalized Zr-Based Metal-Organic Frameworks Through Post-Synthetic Ligand Exchange
Sangho Lee *1, Daeyeon Lee *1, Jin Yeong Kim 2, Min Kim 1
1Department of Chemistry, Chungbuk National University, 2Department of Chemistry Education, Seoul National University

Post-synthetic ligand exchange (PSE) is a versatile and powerful tool for installing functional groups into metal-organic frameworks (MOFs). Exposing MOFs to solutions containing triazole- and tetrazole-functionalized ligands can incorporate these heterocyclic moieties into Zr-MOFs through PSE processes.

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