Preparation of ZnO Nanorod/Graphene/ZnO Nanorod Epitaxial Double Heterostructure for Piezoelectrical Nanogenerator by Using Preheating Hydrothermal

Summary

One-step fabrication method for obtaining freestanding epitaxial double heterostructure is presented. This approach could achieve ZnO coverage with a higher number density than that of the epitaxial single heterostructure, leading to a piezoelectric nanogenerator with an increased output electrical performance.

Abstract

Well-aligned ZnO nanostructures have been intensively studied over the last decade for remarkable physical properties and enormous applications. Here, we describe a one-step fabrication technique to synthesis freestanding ZnO nanorod/graphene/ZnO nanorod double heterostructure. The preparation of the double heterostructure is performed by using thermal chemical vapor deposition (CVD) and preheating hydrothermal technique. In addition, the morphological properties were characterized by using the scanning electron microscopy (SEM). The utility of freestanding double heterostructure is demonstrated by fabricating the piezoelectric nanogenerator. The electrical output is improved up to 200% compared to that of a single heterostructure owing to the coupling effect of the piezoelectricity between the arrays of ZnO nanorods on the top and bottom of graphene. This unique double heterostructure have a tremendous potential for applications of electrical and optoelectrical devices where the high number density and specific surface area of nanorod are needed, such as pressure sensor, immuno-biosensor and dye-sensitized solar cells.

Introduction

Recently, the portable and wearable electronics devices became an essential element for a comfortable life owing to the nanotechnology development, which results in the tremendous demands for a power source in the range of microwatt to milliwatt. Considerable approaches for the power source of portable and wearable devices have been achieved by the renewable energy, including solar energy ^1,2, thermal ^3,4 and mechanical source ^5,6. Piezoelectric nanogenerator have been intensively studied as one of possible candidate for energy harvesting device from environments, such as rustling the leaf ⁷, sound wave ⁸ and movement of human being ⁹. The primary principle underlying the nanogenerator is the coupling between the piezoelectric potential and dielectric material as a barrier. The piezoelectric potential generated in strained material induces the transient current that flows through the external circuit, which balances the potential at the interface between piezoelectric and dielectric material. The performance of nanogenerator would be improved by using nanostructure of piezoelectric material due to robustness under robustness under high stress and responsiveness to tiny deformation ¹⁰.

One-dimensional zinc oxide nanostructure is a promising component for piezoelectric materials in nanogenerator due to its attractive properties, e.g., its high piezoelectricity (26.7 pm/V) ¹¹, optical transparency ¹², and facile synthesis by using chemical process ¹³. Hydrothermal approach for growing the well aligned ZnO nanorod receives a great attention due to low cost, environmental friendly synthesis and potential for easy scaling up. Moreover, the preheating hydrothermal technique is easily controllable in experimental condition, resulting in many kinds of novel nanostructures, such as nanoleaves ¹⁴, nanoflowers ¹⁵ and nanotubes ¹⁶. The novel nanostructures enable a beneficial effect on performance of the electric and optoelectric devices wherever the high specific surface area of material is demanded.

In this protocol, we describe the experimental procedures for synthesis of more novel nanostructure (i.e., freestanding double heterostructure). The growth of ZnO nanorod at interface between graphene and polyethylene terephthalate (PET) substrate leads to the self-elevating the ZnO nanorod/graphene single heterostructure, yielding the freestanding double heterostructure. Furthermore, the feasible application of this unique nanostructure for electronic and optoelectric devices is demonstrated by fabricating a piezoelectric nanogenerator. Freestanding double heterostructure provides not only a high specific surface area but also a high number density of nanorod in a given area. This unique nanostructure has a tremendous potential for applications of electrical and optoelectrical devices, such as pressure sensor, immuno-biosensor and dye-sensitized solar cells.

Protocol

1. Chemical Vapor Deposition (CVD) Growth of Single Layered Graphene

Note: The graphene used in this study was grown on copper (Cu) foil using the thermal chemical vapor deposition (CVD) technique (Figure 1A). Growth is uniform over an area of 2 cm x 10 cm for this system.

1. Wash the Cu foil (2 cm x 10 cm) with mild flow of acetone, isopropyl alcohol (IPA) and distilled water, respectively.
2. Place the cleaned Cu foil in a 2 in. quartz tube (Figure 1B), and then purge the chamber with vacuum (approximately 1 mTorr) for 10 min by using rotary pump.
3. Configure the temperature of digitalized furnace and ramp up the furnace to 995 °C, while maintaining the desired flow rates (100 sccm for Argon and 50 sccm for hydrogen) (Figure 1C).
4. Introduce the 20 sccm of methane (CH₄) for 10 min to grow the single layered graphene. Maintain the 80 sccm of Argon and 20 sccm of hydrogen throughput the process.
5. Allow the furnace to cool down to RT within 5 min with the flow rates specified in the step 1.4. Purge the chamber again with Argon at 100 sccm.

2. Preparation of Graphene/Polyethylene Terephthalate (PET) Substrate

1. Place the graphene grown Cu foil (1.5 cm x 2 cm) on the glass slide, and fix the edges by commercial tape (Figure 2A).
2. Spin coat a layer of poly(methyl methacrylate) (PMMA) at 500 rpm for 5 sec and then 3,000 rpm for 30 sec (Figure2B). Then, bake the PMMA-coated Cu foil substrate at 60 °C for 2 min to remove solvent residue.
3. Dice the PMMA coated Cu foil into smaller piece 1 cm x 1.5 using razor blade.
4. Immerse PMMA coated Cu foil into Ni etchant reservoir (more than 500 ml) by placing the Cu foil face down for 30 min. This leaves the floating PMMA/graphene layer on etchant solution (Figure 2C). A piece of PMMA-coated Cu foil is enough for the experiment forward.
5. Scoop PMMA/graphene layer up on slide glass, and then immerse PMMA/graphene layer into DI water reservoir. Repeat twice. Finally, scoop PMMA/graphene layer up on PET substrate (Figure 2D), and then bake the substrate at 105 °C for 2 min to remove water residue.
6. Remove the PMMA layer by dipping in warm acetone (60 °C) for 10 min.

3. Synthesis of ZnO Nanorod/Graphene/ZnO Nanorod Epitaxial Double Heterostructure

1. Begin with heating the precursor solution with 40 mM zinc nitrate hexahydrate, 40 mM hexamethylenetetramine (HMT) and 9 mM polyethylenimine (PEI) in DI water for 60 min at 95 °C in convection oven (Figure 3A). Namely, preheating process.
2. While preheating process, fully cover the solution with 5 mM zinc acetate in ethanol on the substrate and spin coat a layer of zinc acetate on the graphene/PET substrate at 500 rpm for 5 sec and then 2,000 rpm for 60 sec (Figure 3B and Figure 3C).Then, bake the substrate at 200 °C for 30 min. Repeat twice. The thickness of layer is approximately 30 nm.
3. Immerse the seed-coated graphene/PET substrate into preheated solution by placing the substrate face down at 95 °C (Figure 3D). Determine the heating time for the desired nanostructure; i.e., single heterostructure (t < 12 hr, Figure 3E) and double heterostructure (t > 12 hr, Figure 3F).
4. Carefully spray ethanol on the substrate and dry it at RT for 1 hr.
   Note : For scanning electron microscopy (SEM), dice the sample into smaller piece 5 mm x 5 mm using razor blade and mount the sample on SEM stage.

4. Fabrication of Piezoelectric Nanogenerator

Note: Piezoelectric nanogenerator in this study has the three electrodes (top, middle, bottom). Use the indium tin oxide (ITO) coated PET as the bottom electrode (Figure 4A).

1. Spin coat a layer of polydimethylsiloxane (PDMS) at 500 rpm for 5 sec and then 6,000 rpm for 60 sec to form the insulating layer between ITO and ZnO nanorod (Figure 4B). The thickness of layer is approximately 3 µm.
2. Fully cure the substrate at 80 °C for 2 hr in convection oven.
3. Transfer the graphene to PDMS coated ITO/PET substrate by using the method in Section 2 (Figure 4C).
4. Synthesize the double heterostructure on the substrate by using the method in Section 3 (Figure 4D).
5. Spin coat a layer of PDMS at 500 rpm for 5 sec and then 5,000 rpm for 60 sec to improve the robustness and durability of the ZnO nanorod, and then fully cure it at 80 °C for 2 hr (Figure 4E). The thickness of layer is approximately 8 µm.
6. Cover the substrate with ITO-coated PET as the top electrode (Figure 4F).

5. Electrical Performance Measurement Setup

Note: We set up custom-made equipment for electrical performance characterization using linear motor, commercial scale and oscilloscope. Build the frame for vertically supporting the linear motor and place the commercial scale under the linear motor as shown in Figure 5A. The scale should be sensitive to small weight (0.02 kg - 20 kg).

1. Place the nanogenerator on a scale, and then connect the electrodes of nanogenerator to sensing probes of oscilloscope (Figure 5A and 5B).
2. Set up the initial and final positions and speed of linear motor while carefully monitoring the weight in the scale.
   Tip : Configure the initial position where nanogenerator is slightly contacted with measurement setup. Speed of linear motor determines the strain rate.
3. Start the linear motor and monitor the voltage signal with time. Save the time-dependent voltage signal in flash memory. Strain rate: 100 mm/sec and applied load: 50 N.

Results

The scanning electron microscopy (SEM) images shown in Figure 6 present the morphologies of hydrothermally grown ZnO nanorods. The preheating hydrothermal technique can result in two different nanostructures depending on the growth time. Figure 6A shows a typical image of ZnO nanorod on graphene/PET substrate at the growth time of 5 hr. In contrast, the image shown in Figure 6B indicates that the growth of ZnO nanorod at the growth time o...

Discussion

Please note that the high quality (>99.8%, annealed) of Cu foil should be considered as a substrate for successful growth of single layer graphene. Otherwise, the single layer graphene is not uniformly grown over the Cu foil, leading to dramatically decrease in conductivity of graphene. A 1 hr annealing at high temperature would help the improvement of the Cu foil crystallinity as well as removal of any contaminants from the Cu foil.

The growth of ZnO nanorod depends on the conditions for ...

Materials

Name	Company	Catalog Number	Comments
Cu foil	Alfa Aesar	13382
poly(methyl methacrylate) (PMMA)	Aldrich	182230
zinc nitrate hexahydrate	Sigma-Aldrich	228732
hexamethylenetetramine (HMT)	Sigma-Aldrich	398160
polyethylenimine (PEI)	Sigma-Aldrich	408719
indium tin oxide (ITO) coated PET	Aldrich	639303
Silicone Elastomer Kit	Dow Corning	Sylgard 184 a, b
Nickel Etchant Type1	Transene Company	41212