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Palladium N-Heterocyclic Carbene Complexes: Synthesis from Benzimidazolium Salts and Catalytic Activity in Carbon-carbon Bond-forming Reactions

DOI :

10.3791/54932-v

July 30th, 2017

July 30th, 2017

9,423 Views

1Faculty of Pharmacy, The University of Sydney, 2Department of Chemistry, Faculty of Sciences, Erciyes University

Detailed and generalized protocols are presented for the synthesis and subsequent purification of four palladium N-heterocyclic carbene complexes from benzimidazolium salts. The complexes were tested for catalytic activity in arylation and Suzuki-Miyaura reactions. For each reaction investigated, at least one of the four complexes successfully catalyzed the reaction.

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