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The Synthesis, Characterization and Reactivity of a Series of Ruthenium N-triphosPh Complexes

DOI :

10.3791/52689-v

April 10th, 2015

April 10th, 2015

11,852 Views

1Department of Chemistry, Imperial College London

Ruthenium phosphine complexes are widely used for homogeneous catalytic reactions such as hydrogenations. The synthesis of a series of novel tridentate ruthenium complexes bearing the N-triphos ligand N(CH2PPh2)3 is reported. Additionally, the stoichiometric reaction of a dihydride Ru–N-triphos complex with levulinic acid is described.

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Synthesis

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