July 27th, 2022
•Line shape analysis of NMR spectra collected over a range of temperatures serves as a guide for the rearrangement of inner coordination-sphere atoms at a chiral, eight-coordinate, rhenium(V) polyhydride complex, ReH5(PPh3)2(sec-butyl amine). Line shape analysis is also used to determine the activation parameters ΔH‡, ΔS‡, and ΔG‡ for those atom rearrangements.
Tags
Related Videos
Structure and Coordination Determination of Peptide-metal Complexes Using 1D and 2D 1H NMR
Atomically Defined Templates for Epitaxial Growth of Complex Oxide Thin Films
Dissolution Dynamic Nuclear Polarization Instrumentation for Real-time Enzymatic Reaction Rate Measurements by NMR
Rapid High-throughput Species Identification of Botanical Material Using Direct Analysis in Real Time High Resolution Mass Spectrometry
On-line Analysis of Nitrogen Containing Compounds in Complex Hydrocarbon Matrixes
Synthesis of a Water-soluble Metal–Organic Complex Array
Real-time Breath Analysis by Using Secondary Nanoelectrospray Ionization Coupled to High Resolution Mass Spectrometry
Synthesis of Terpolymers at Mild Temperatures Using Dynamic Sulfur Bonds in Poly(S-Divinylbenzene)
Application of Voltage in Dynamic Light Scattering Particle Size Analysis
Excitonic Hamiltonians for Calculating Optical Absorption Spectra and Optoelectronic Properties of Molecular Aggregates and Solids
ABOUT JoVE
Copyright © 2024 MyJoVE Corporation. All rights reserved