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Chapter 9

化学键合:分子几何学和成键理论

化学键的类型
化学键的类型
Chemical bonding theories were pioneered by American chemist Gilbert N. Lewis. He developed a model called the Lewis model to explain the type and ...
路易斯符号和八偶体规则
路易斯符号和八偶体规则
Chemical bonds are complex interactions between two or more atoms or ions, which reduce the potential energy of the molecule. Gilbert N. Lewis developed a ...
离子键和电子转移
离子键和电子转移
Ions are atoms or molecules bearing an electrical charge. A cation (a positive ion) forms when a neutral atom loses one or more electrons from its valence ...
玻恩-哈伯循环
玻恩-哈伯循环
Lattice Energy  An ionic compound is stable because of the electrostatic attraction between its positive and negative ions. The lattice energy of a ...
晶格能量的趋势:离子大小和电荷
晶格能量的趋势:离子大小和电荷
An ionic compound is stable because of the electrostatic attraction between its positive and negative ions. The lattice energy of a compound is a measure ...
共价键和路易斯结构
共价键和路易斯结构
Compared to ionic bonds, which results from the transfer of electrons between metallic and nonmetallic atoms, covalent bonds result from the mutual ...
电负性
电负性
Whether a bond is nonpolar or polar covalent is determined by a property of the bonding atoms called electronegativity.  Electronegativity values of ...
键极性、偶极矩和离子性百分比
键极性、偶极矩和离子性百分比
Bond Polarity The absolute value of the difference in electronegativity (ΔEN) of two bonded atoms provides a rough measure of the polarity to be ...
分子化合物和多原子离子的路易斯结构
分子化合物和多原子离子的路易斯结构
To draw Lewis structures for complicated molecules and molecular ions, it is helpful to follow a step-by-step procedure as outlined: Determine the ...
共振
共振
The Lewis structure of a nitrite anion (NO2−) may actually be drawn in two different ways, distinguished by the locations of the N-O and N=O ...
形式电荷
形式电荷
In some cases, there are seemingly more than one valid Lewis structures for molecules and polyatomic ions. The concept of formal charges can be used to ...
八偶体规则的例外情况
八偶体规则的例外情况
Many covalent molecules have central atoms that do not have eight electrons in their Lewis structures. These molecules fall into three categories: ...
键能和键长
键能和键长
Stable molecules exist because covalent bonds hold the atoms together. The strength of a covalent bond is measured by the energy required to break it, ...
金属中的键
金属中的键
Metallic bonds are formed between two metal atoms. A simplified model to describe metallic bonding has been developed by Paul Drüde called the ...
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