Synthesis of N,N,N-tris (diphenylphosphinomethylene)amine, N(CH2PPh2)3(N-triphosPh)
2:44
Synthesis of [Ru(CO)2(N(CH2PPh2)3-κ3P)]
4:25
Synthesis of [Ru(CO3)(CO) (N(CH2PPh2)3-κ3P)]
5:47
Synthesis of [RuH2(CO) (N(CH2PPh2)3-κ3P)]
7:11
Reaction of [RuH2(CO) (N(CH2PPh2)3-κ3P)] with NH4PF5 and Levulinic Acid
8:35
Results: Characterization and Reactivity of Ruthenium N-triphos Complexes
10:17
Conclusion
Ruthenium phosphine complexes are widely used for homogeneous catalytic reactions such as hydrogenations. The synthesis of a series of novel tridentate ruthenium complexes bearing the N-triphos ligand N(CH2PPh2)3 is reported. Additionally, the stoichiometric reaction of a dihydride Ru–N-triphos complex with levulinic acid is described.
