Harry B. Gray

High-Valent Manganese Corroles and the First Perhalogenated Metallocorrole Catalyst This research (No. 368/00) was supported by the Israel Science Foundation (Z.G.), the US National Science Foundation (H.B.G.), and the Fund for the Promotion of Research at the Technion (Z.G.).

Electronic Spectroscopy of Gold(I) Pseudomonasaeruginosa Azurin Derivatives.

Resonance Raman Spectra of [M(6)X(8)Y(6)](2)(-) Cluster Complexes (M = Mo, W; X, Y = Cl, Br, I).

Aerobic Epoxidation of Olefins Catalyzed by Electronegative Vanadyl Salen Complexes.

Time-Resolved Resonance Raman Spectroscopy at Low Temperature. The Excited-State Metal-Metal Stretching Frequency of Rh(2)(TMB)(4)(2+) (TMB = 2,5-Dimethyl-2,5-diisocyanohexane).

X-ray Absorption Spectra of the Oxidized and Reduced Forms of C112D Azurin from Pseudomonas aeruginosa.

An outer-sphere hydrogen-bond network constrains copper coordination in blue proteins.

Mapping the cytochrome C folding landscape.

The cytochrome c folding landscape revealed by electron-transfer kinetics.

Using deeply trapped intermediates to map the cytochrome c folding landscape.

Fluorescent probes for cytochrome p450 structural characterization and inhibitor screening.

Structural features of cytochrome c' folding intermediates revealed by fluorescence energy-transfer kinetics.

Sensitizer-linked substrates and ligands: ruthenium probes of cytochrome P450 structure and mechanism.

Structural features of the cytochrome C molten globule revealed by fluorescence energy transfer kinetics.

Cloning, heterologous expression, and characterization of recombinant class II cytochromes c from Rhodopseudomonas palustris.

Trapping of peptide-based surrogates in an artificially created channel of cytochrome c peroxidase.

Aerobic oxidations catalyzed by chromium corroles.

Structural model for an alkaline form of ferricytochrome C.

The protein-folding speed limit: intrachain diffusion times set by electron-transfer rates in denatured Ru(NH3)5(His-33)-Zn-cytochrome c.

Biological inorganic chemistry at the beginning of the 21st century.

15N-1H Residual dipolar coupling analysis of native and alkaline-K79A Saccharomyces cerevisiae cytochrome c.

Gold electrodes wired for coupling with the deeply buried active site of Arthrobacter globiformis amine oxidase.

Nanosecond photoreduction of cytochrome p450cam by channel-specific Ru-diimine electron tunneling wires.

Spectroscopy and reactivity of a photogenerated tryptophan radical in a structurally defined protein environment.

NMR-validated structural model for oxidized Rhodopseudomonas palustris cytochrome c(556).

Photoswitchable luminescence of rhenium(i) tricarbonyl diimines.

Electron tunneling through proteins.

Electron tunneling in rhenium-modified Pseudomonas aeruginosa azurins.

X-ray magnetic circular dichroism of Pseudomonas aeruginosa nickel(II) azurin.

The stability of the cytochrome c scaffold as revealed by NMR spectroscopy.

Electron-transfer chemistry of Ru-linker-(heme)-modified myoglobin: rapid intraprotein reduction of a photogenerated porphyrin cation radical.

Oxoiron(IV) in chloroperoxidase compound II is basic: implications for P450 chemistry.

Amphiphilic corroles bind tightly to human serum albumin.

Excited-state dynamics of fac-[ReI(L)(CO)3(phen)]+ and fac-[ReI(L)(CO)3(5-NO2-phen)]+ (L = imidazole, 4-ethylpyridine; phen = 1,10-phenanthroline) complexes.

Reduction of dioxygen catalyzed by pyrene-wired heme domain cytochrome P450 BM3 electrodes.

Cobaltocene-mediated catalytic monooxygenation using holo and heme domain cytochrome P450 BM3.

Alpha-synuclein: stable compact and extended monomeric structures and pH dependence of dimer formation.

Mimicking protein-protein electron transfer: voltammetry of Pseudomonas aeruginosa azurin and the Thermus thermophilus Cu(A) domain at omega-derivatized self-assembled-monolayer gold electrodes.

Conformational states of cytochrome P450cam revealed by trapping of synthetic molecular wires.

Alpha-synuclein structures from fluorescence energy-transfer kinetics: implications for the role of the protein in Parkinson's disease.

Inner-sphere electron-transfer reorganization energies of zinc porphyrins.

Metalloprotein folding.

Zinc-porphyrin Solvation in folded and unfolded states of Zn-cytochrome c.

Many faces of the unfolded state: conformational heterogeneity in denatured yeast cytochrome C.

Electron tunneling through organic molecules in frozen glasses.

Distant charge transport.

Long-range electron transfer.

Ligand-field excited states of metal hexacarbonyls.

Luminescent ruthenium(II)- and rhenium(I)-diimine wires bind nitric oxide synthase.

Early events in the folding of four-helix-bundle heme proteins.

Protein-surfactant film voltammetry of wild-type and mutant cytochrome P450 BM3.

Redox couples of inducible nitric oxide synthase.

Electrochemistry of heme-thiolate proteins.

Reversible inhibition of copper amine oxidase activity by channel-blocking ruthenium(II) and rhenium(I) molecular wires.

Nature of the cytochrome c molten globule.

Picosecond photoreduction of inducible nitric oxide synthase by rhenium(I)-diimine wires.

Tertiary contact formation in alpha-synuclein probed by electron transfer.

Snapshots of cytochrome c folding.

Electronic structures of trans-dioxometal complexes.

Specific delivery of corroles to cells via noncovalent conjugates with viral proteins.

Electrochemical generation of a high-valent state of cytochrome P450.

Excited-state dynamics of structurally characterized [ReI(CO)3(phen)(HisX)]+ (X = 83, 109) Pseudomonas aeruginosa azurins in aqueous solution.

Alpha-synuclein structures probed by 5-fluorotryptophan fluorescence and 19F NMR spectroscopy.

Spectroscopy and electrochemistry of cytochrome P450 BM3-surfactant film assemblies.

Electronic excited states of tetracyanonickelate(II).

Stability and folding kinetics of structurally characterized cytochrome c-b562.

Probing folded and unfolded states of outer membrane protein a with steady-state and time-resolved tryptophan fluorescence.

Cyclometalated iridium(III)-sensitized titanium dioxide solar cells.

Electrochemistry of cytochrome P450 BM3 in sodium dodecyl sulfate films.

Site-specific collapse dynamics guide the formation of the cytochrome c' four-helix bundle.

Bacterial spore detection by [Tb3+(macrocycle)(dipicolinate)] luminescence.

Alpha-synuclein tertiary contact dynamics.

Probing heme coordination states of inducible nitric oxide synthase with a ReI(imidazole-alkyl-nitroarginine) sensitizer-wire.

Probing the cytochrome c' folding landscape.

Probing inducible nitric oxide synthase with a pterin-ruthenium(II) sensitizer wire.

Probing melittin helix-coil equilibria in solutions and vesicles.

Deeply inverted electron-hole recombination in a luminescent antibody-stilbene complex.

Preface on making oxygen.

Copper(II) binding to alpha-synuclein, the Parkinson's protein.

Enantiomer-specific binding of ruthenium(II) molecular wires by the amine oxidase of Arthrobacter globiformis.

Iridium corroles.

Spectroscopic analysis of ligand binding to lanthanide-macrocycle platforms.

Tryptophan-accelerated electron flow through proteins.

Electron transfer and electronic conduction through an intervening medium.

Spermine binding to Parkinson's protein alpha-synuclein and its disease-related A30P and A53T mutants.

Synchronous vs asynchronous chain motion in alpha-synuclein contact dynamics.

High-potential C112D/M121X (X = M, E, H, L) Pseudomonas aeruginosa azurins.

Electrostatic effects on funneled landscapes and structural diversity in denatured protein ensembles.

Electron Tunneling through Pseudomonas aeruginosa Azurins on SAM Gold Electrodes.

Tumor detection and elimination by a targeted gallium corrole.

Folding energy landscape of cytochrome cb562.

Nanosecond photoreduction of inducible nitric oxide synthase by a Ru-diimine electron tunneling wire bound distant from the active site.

Deamidation of alpha-synuclein.

Detection of bacterial spores with lanthanide-macrocycle binary complexes.

Relaxation dynamics of Pseudomonas aeruginosa Re(I)(CO)3(alpha-diimine)(HisX)+ (X = 83, 107, 109, 124, 126)Cu(II) azurins.

Structures and reactivity patterns of group 9 metallocorroles.

Probing the heme-thiolate oxygenase domain of inducible nitric oxide synthase with Ru(II) and Re(I) electron tunneling wires.

Hydrogen evolution catalyzed by cobaloximes.

Kinetics of electron transfer reactions of H2-evolving cobalt diglyoxime catalysts.

Electronic structures of Pd(II) dimers.

Electron tunneling through sensitizer wires bound to proteins.

Electron Flow through Proteins.

Type-zero copper proteins.

Terbium-macrocycle complexes as chemical sensors: detection of an aspirin metabolite in urine using a salicylurate-specific receptor site.

Electron flow through metalloproteins.

Near-IR phosphorescence of iridium(III) corroles at ambient temperature.

Outer-sphere effects on reduction potentials of copper sites in proteins: the curious case of high potential type 2 C112D/M121E Pseudomonas aeruginosa azurin.

Photooxidation of cytochrome P450-BM3.

Mechanism of H(2) evolution from a photogenerated hydridocobaloxime.

Proton-coupled electron flow in protein redox machines.

Electronic structures of Group 9 metallocorroles with axial ammines.

Spectroscopic and redox properties of amine-functionalized K2[OsII(bpy)(CN)4] complexes.

Multimodal wide-field two-photon excitation imaging: characterization of the technique for in vivo applications.

Powering the planet with solar fuel.

Geometrical Analysis of Cytochrome c Unfolding.

Electron transfer reactivity of type zero Pseudomonas aeruginosa azurin.

Mass spectrometric characterization of oligomers in Pseudomonas aeruginosa azurin solutions.

Phototriggering electron flow through Re(I)-modified Pseudomonas aeruginosa azurins.

Ratiometric spectral imaging for fast tumor detection and chemotherapy monitoring in vivo.

Shedding light on solar fuel efficiencies.

Iodinated aluminum(III) corroles with long-lived triplet excited states.

A Multimode Optical Imaging System for Preclinical Applications In Vivo: Technology Development, Multiscale Imaging, and Chemotherapy Assessment.

Redox reactivity of photogenerated osmium(II) complexes.

Noninnocence in metal complexes: a dithiolene dawn.

Dual coordination modes of ethylene-linked NP2 ligands in cobalt(II) and nickel(II) iodides.

Nitrogen insertion into a corrole ring: iridium monoazaporphyrins.

A mechanistic study of tumor-targeted corrole toxicity.

Rapid water reduction to H2 catalyzed by a cobalt bis(iminopyridine) complex.

Gating NO release from nitric oxide synthase.

Differential cytostatic and cytotoxic action of Metallocorroles against human cancer cells: potential platforms for anticancer drug development.

Redox properties of tyrosine and related molecules.

Fe4 cluster and a buckled macrocycle complex from the reduction of [(dmgBF2)2Fe(L)2] (L = MeCN, (t)Bu(i)NC).

Investigating photoexcitation-induced mitochondrial damage by chemotherapeutic corroles using multimode optical imaging.

Spin delocalization over type zero copper.

Groups 5 and 6 terminal hydrazido(2-) complexes: N(β) substituent effects on ligand-to-metal charge-transfer energies and oxidation states.

Electron transfer triggered by optical excitation of phenothiazine-tris(meta-phenylene-ethynylene)-(tricarbonyl)(bpy)(py)rhenium(I).

Outer-sphere contributions to the electronic structure of type zero copper proteins.

Hydrogen generation catalyzed by fluorinated diglyoxime-iron complexes at low overpotentials.

M-M bond-stretching energy landscapes for M2(dimen)4(2+) (M = Rh, Ir; dimen = 1,8-diisocyanomenthane) complexes.

Inner- and outer-sphere metal coordination in blue copper proteins.

Catalytic hydrogen evolution from a covalently linked dicobaloxime.

Structural control of 1A2u-to-3A2u intersystem crossing in diplatinum(II,II) complexes.

Spectroscopic and magnetic properties of an iodo Co(I) tripodal phosphine complex.

Molecular mechanisms of cobalt-catalyzed hydrogen evolution.

A novel ruthenium(ii)-cobaloxime supramolecular complex for photocatalytic H(2) evolution: synthesis, characterisation and mechanistic studies.

Thermally stable N2-intercalated WO3 photoanodes for water oxidation.

Photoexcitation of tumor-targeted corroles induces singlet oxygen-mediated augmentation of cytotoxicity.

Catalysis of dioxygen reduction by Thermus thermophilus strain HB27 laccase on ketjen black electrodes.

Hydrogen Evolution from Pt/Ru-Coated p-Type WSe(2) Photocathodes.

Hopping Maps for Photosynthetic Reaction Centers().

Snapshots of a protein folding intermediate.

Light-triggered modulation of cellular electrical activity by ruthenium diimine nanoswitches.

Electron hopping through proteins.

Solar fuels editorial.

Long Range Proton-Coupled Electron Transfer Reactions of Bis(imidazole) Iron Tetraphenylporphyrins Linked to Benzoates.

Decorating metal oxide surfaces with fluorescent chlorosulfonated corroles.

A Euclidean Perspective on the Unfolding of Azurin: Spatial Correlations.

Generation of powerful tungsten reductants by visible light excitation.

Electron flow through nitrotyrosinate in Pseudomonas aeruginosa azurin.

Kinetics of CO Recombination to the Heme in Geobacillus Stearothermophilus Nitric Oxide Synthase.

Intrachain contact dynamics in unfolded cytochrome cb562.

Tryptophan-accelerated electron flow across a protein-protein interface.

Enhancement of anion binding in lanthanide optical sensors.

Noncovalent immobilization of electrocatalysts on carbon electrodes for fuel production.

Electron flow through metalloproteins.

A Euclidean perspective on the unfolding of azurin: chain motion.

Long-range electron tunneling.

Assembly, characterization, and electrochemical properties of immobilized metal bipyridyl complexes on silicon(111) surfaces.

Cellular uptake and cytotoxicity of a near-IR fluorescent corrole-TiO2 nanoconjugate.

Fluorescence quenching of (dimethylamino)naphthalene dyes Badan and Prodan by tryptophan in cytochromes P450 and micelles.

Theoretical modeling of low-energy electronic absorption bands in reduced cobaloximes.

Modeling dioxygen reduction at multicopper oxidase cathodes.

Highly active mixed-metal nanosheet water oxidation catalysts made by pulsed-laser ablation in liquids.

A cytotoxic and cytostatic gold(III) corrole.

Symmetry-Breaking Charge Transfer of Visible Light Absorbing Systems: Zinc Dipyrrins.

Catalysis of proton reduction by a [BO4]-bridged dicobalt glyoxime.

Electron Transfer Reactions of Electronically Excited Zinc Tetraphenylporphyrin with Multinuclear Ruthenium Complexes.

Bespoke photoreductants: tungsten arylisocyanides.

Could tyrosine and tryptophan serve multiple roles in biological redox processes?

Spin-Orbit TDDFT Electronic Structure of Diplatinum(II,II) Complexes.