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Kapitel 2

Thermodynamik und chemische Kinetik

Chemische Reaktionen
Chemische Reaktionen
A balanced chemical equation provides the information of chemical formulas of the reactants and products involved in the chemical change. A ...
Enthalpie und Reaktionswärme
Enthalpie und Reaktionswärme
Combustion, commonly known as burning, is a reaction in which a substance reacts with an oxidizing agent, which in most cases is molecular oxygen, to ...
Energetik der Lösungsbildung
Energetik der Lösungsbildung
The formation of a solution is an example of a spontaneous process, which is a process that occurs under specified conditions without energy from some ...
Entropie und Solvatation
Entropie und Solvatation
The process of surrounding a solute with solvent is called solvation. It involves evenly distributing the solute within the solvent. The rule of thumb for ...
Gibbs-freie Energie und thermodynamische Begünstigung
Gibbs-freie Energie und thermodynamische Begünstigung
The spontaneity of a process depends upon the temperature of the system. Phase transitions, for example, will proceed spontaneously in one direction or ...
Chemische und Löslichkeitsgleichgewichte
Chemische und Löslichkeitsgleichgewichte
The free energy change associated with dissolving a solute in a liter of solvent is called the free energy of a solution, ΔGsolution. The overall ...
Zinssatzgesetz und Reaktionsordnung
Zinssatzgesetz und Reaktionsordnung
The rate of a reaction is affected by the concentrations of reactants. Rate laws (differential rate laws) or rate equations are mathematical expressions ...
Einfluss der Temperaturänderung auf die Reaktionsgeschwindigkeit
Einfluss der Temperaturänderung auf die Reaktionsgeschwindigkeit
The Arrhenius equation, relates the activation energy and the rate constant, k, for many chemical reactions. In this equation, R is the ideal gas ...
Mehrstufige Reaktionen
Mehrstufige Reaktionen
Chemical reactions often occur in a stepwise fashion involving two or more distinct reactions taking place in a sequence. A balanced equation indicates ...
Bindungsdissoziationsenergie und Aktivierungsenergie
Bindungsdissoziationsenergie und Aktivierungsenergie
Bond energy is the energy required to break a bond homolytically. These values are usually expressed in units of kcal/mol or kJ/mol and are referred to as ...
Energiediagramme, Übergangszustände und Zwischenprodukte
Energiediagramme, Übergangszustände und Zwischenprodukte
Free-energy diagrams, or reaction coordinate diagrams, are graphs showing the energy changes that occur during a chemical reaction. The reaction ...
Vorhersage von Reaktionsergebnissen
Vorhersage von Reaktionsergebnissen
Kinetics describes the rate and path by which a reaction occurs. In contrast, thermodynamics deals with state functions and describes the properties, ...
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