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Chapter 2

열역학과 화학반응속도론

화학 반응
화학 반응
A balanced chemical equation provides the information of chemical formulas of the reactants and products involved in the chemical change. A ...
엔탈피와 반응의 열
엔탈피와 반응의 열
Combustion, commonly known as burning, is a reaction in which a substance reacts with an oxidizing agent, which in most cases is molecular oxygen, to ...
솔루션 형성의 에너지
솔루션 형성의 에너지
The formation of a solution is an example of a spontaneous process, which is a process that occurs under specified conditions without energy from some ...
엔트로피와 솔비
엔트로피와 솔비
The process of surrounding a solute with solvent is called solvation. It involves evenly distributing the solute within the solvent. The rule of thumb for ...
깁스 무료 에너지 및 열역학적 호의
깁스 무료 에너지 및 열역학적 호의
The spontaneity of a process depends upon the temperature of the system. Phase transitions, for example, will proceed spontaneously in one direction or ...
화학 및 용해도 평형
화학 및 용해도 평형
The free energy change associated with dissolving a solute in a liter of solvent is called the free energy of a solution, ΔGsolution. The overall ...
속도 법 및 반응 순서
속도 법 및 반응 순서
The rate of a reaction is affected by the concentrations of reactants. Rate laws (differential rate laws) or rate equations are mathematical expressions ...
반응 속도에 대한 온도 변화의 영향
반응 속도에 대한 온도 변화의 영향
The Arrhenius equation, relates the activation energy and the rate constant, k, for many chemical reactions. In this equation, R is the ideal gas ...
다단계 반응
다단계 반응
Chemical reactions often occur in a stepwise fashion involving two or more distinct reactions taking place in a sequence. A balanced equation indicates ...
채권 해리 에너지 및 활성화 에너지
채권 해리 에너지 및 활성화 에너지
Bond energy is the energy required to break a bond homolytically. These values are usually expressed in units of kcal/mol or kJ/mol and are referred to as ...
에너지 다이어그램, 전환 상태 및 중간
에너지 다이어그램, 전환 상태 및 중간
Free-energy diagrams, or reaction coordinate diagrams, are graphs showing the energy changes that occur during a chemical reaction. The reaction ...
반응 결과 예측
반응 결과 예측
Kinetics describes the rate and path by which a reaction occurs. In contrast, thermodynamics deals with state functions and describes the properties, ...
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