Flame Experiments at the Advanced Light Source: New Insights into Soot Formation ProcessesNils Hansen 1, Scott A. Skeen 1, Hope A. Michelsen 1, Kevin R. Wilson 2, Katharina Kohse-Höinghaus 3
1Combustion Research Facility, Sandia National Laboratories, 2Chemical Sciences Division, Advanced Light Source, Lawrence Berkeley National Laboratory, 3Physikalische Chemie I, Universität Bielefeld
Gas sampling from laboratory-scale flames with online analysis of all species by mass spectrometry is a powerful method to investigate the complex mixture of chemical compounds occurring during combustion processes. Coupled with tunable soft ionization via synchrotron-generated vacuum-ultraviolet radiation, this technique provides isomer-resolved information and potentially fragment-free mass spectra.