atom-probe-tomography-analysis-of-exsolved-mineral-phases

Atom Probe Tomography Analysis of Exsolved Mineral Phases

Element diffusion rates and temperature/pressure control a range of fundamental volcanic and metamorphic processes. Such processes are often recorded in ...

University of Alabama

Lightning strikes are known to morphologically alter and chemically reduce geologic formations and deposits, forming fulgurites. A similar process occurs as the result of volcanic lightning discharge, when airborne volcanic ash is transformed into lightning-induced volcanic spherules (LIVS). Here, we adapt the calculations used in previous studies of lightning-induced damage to infrastructure materials to determine the effects on pseudo-ash samples of simplified composition. Using laboratory high-current impulse experiments, this research shows that within the lightning discharge channel there is an ideal melting zone that represents roughly 10% or less of the total channel radius at which temperatures are sufficient to melt the ash, regardless of peak current. The melted ash is simultaneously expelled from the channel by the heated, expanding air, permitting particles to cool during atmospheric transport before coming to rest in ash fall deposits. The limited size of this ideal melting zone explains the low number of LIVS typically observed in volcanic ash despite the frequent occurrence of lightning during explosive eruptions.

The Elusive Evidence of Volcanic Lightning.

High-current impulse experiments were performed on volcanic ash samples to determine the magnetic effects that may result from the occurrence of volcanic lightning during explosive eruptions. Pseudo-ash was manufactured through milling and sieving of eruptive deposits with different bulk compositions and mineral contents. By comparing pre- and post-experimental samples, it was found that the saturation (i.e., maximum possible) magnetization increased, and coercivity (i.e., ability to withstand demagnetization) decreased. The increase in saturation magnetization was greater for compositionally evolved samples compared to more primitive samples subjected to equivalent currents. Changes in remanent (i.e., residual) magnetization do not correlate with composition, and show wide variability. Variations in magnetic properties were generally more significant when samples were subjected to higher peak currents as higher currents affect a greater proportion of the subjected sample. The electrons introduced by the current impulse cause reduction and devolatilization of the ash grains, changing their structural, mineralogical, and magnetic properties.

Kimberly Genareau

Department of Geological Sciences

University of Alabama

Atom Probe Tomography Analysis of Exsolved Mineral Phases

Kimberly Genareau

.css-o250i3{font-size:18px;font-family:Open Sans,sans-serif;line-height:21.6px;}Department of Geological Sciences

University of Alabama

Atom Probe Tomography Analysis of Exsolved Mineral Phases

Department of Geological Sciences