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Chapter 10

Chemical Bonding: Molecular Geometry and Bonding Theories

VSEPR Theory and the Basic Shapes
VSEPR Theory and the Basic Shapes
Overview of VSEPR Theory Valence shell electron-pair repulsion theory (VSEPR theory) enables us to predict the molecular structure, including approximate ...
VSEPR Theory and the Effect of Lone Pairs
VSEPR Theory and the Effect of Lone Pairs
Effect of Lone Pairs of Electrons on Molecule Geometry It is important to note that electron-pair geometry around a central atom is not the same ...
Predicting Molecular Geometry
Predicting Molecular Geometry
VSEPR Theory for Determination of Electron Pair Geometries The following procedure uses VSEPR theory to determine the electron pair geometries and the ...
Molecular Shape and Polarity
Molecular Shape and Polarity
Dipole Moment of a Molecule Polar covalent bonds connect two atoms with differing electronegativities, leaving one atom with a partial positive charge ...
Valence Bond Theory
Valence Bond Theory
Overview of Valence Bond Theory Valence bond theory describes a covalent bond as the overlap of half-filled atomic orbitals (each containing a single ...
Hybridization of Atomic Orbitals I
Hybridization of Atomic Orbitals I
The mathematical expression known as the wave function, ψ, contains information about each orbital and the wavelike properties of electrons in an ...
Hybridization of Atomic Orbitals II
Hybridization of Atomic Orbitals II
sp3d and sp3d 2 Hybridization To describe the five bonding orbitals in a trigonal bipyramidal arrangement, we must use five of the valence shell ...
Molecular Orbital Theory I
Molecular Orbital Theory I
Overview of Molecular Orbital Theory Molecular orbital theory describes the distribution of electrons in molecules in the same way as the distribution of ...
Molecular Orbital Theory II
Molecular Orbital Theory II
Molecular Orbital Energy Diagrams The relative energy levels of atomic and molecular orbitals are typically shown in a molecular orbital diagram. For a ...
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