Chapter 8
Reactions of Alkenes
Free Sample
Free access at this time
الانتقائية للضافات المحبة للكهرباء - تأثير بيروكسيد
In the presence of organic peroxides, the addition of hydrogen bromide to an alkene yields the isomer that is not predicted by Markovnikov’s rule. ...
Free Sample
Free access at this time
التفاعل المتسلسل للجذور الحرة وبلمرة الألكينات
The conversion of alkenes to macromolecules called polymers is a reaction of high commercial importance. The structure of the polymer is defined by a ...
Free Sample
Free access at this time
هالوجين الألكينات
Halogenation is the addition of chlorine or bromine across the double bond in an alkene to yield a vicinal dihalide. The reaction occurs in the presence ...
Free Sample
Free access at this time
تشكيل الهالوهيدرن من الألكينات
An alkene, such as propene, reacts with bromine in the presence of water to yield a halohydrin. Halohydrins contain a halogen and a hydroxyl group ...
Free Sample
Free access at this time
ترطيب الألكينات المحفز بالحمض
Alkenes react with water in the presence of an acid to form an alcohol. In the absence of acid, hydration of alkenes does not occur at a significant rate, ...
Free Sample
Free access at this time
الانتقائية والكيمياء الفراغية للترطيب المحفز بالأحماض
The rate of acid-catalyzed hydration of alkenes depends on the alkene's structure, as the presence of alkyl substituents at the double bond can ...
Free Sample
Free access at this time
Oxymercuration-الحد من الألكينات
Oxymercuration–reduction of alkenes is one of the major reactions converting alkenes to alcohols. It involves the hydration of alkenes with mercuric ...
Free Sample
Free access at this time
الأكسدة المائية للألكينات
In addition to the oxymercuration–demercuration method, which converts the alkenes to alcohols with Markovnikov orientation, a complementary ...
Free Sample
Free access at this time
الانتقائية والكيمياء الفراغية للثقب المائي
A significant aspect of hydroboration–oxidation is the regio- and stereochemical outcome of the reaction.
Hydroboration proceeds in a concerted ...
Free Sample
Free access at this time
أكسدة الألكينات: ثنائي هيدروكسيل المزامنة مع رابع أكسيد الأوزميوم
Alkenes are converted to 1,2-diols or glycols through a process called dihydroxylation. It involves the addition of two hydroxyl groups across the double ...
Free Sample
Free access at this time
أكسدة الألكينات: ثنائي هيدروكسيل متزامن مع برمنجنات البوتاسيوم
Alkenes can be dihydroxylated using potassium permanganate. The method encompasses the reaction of an alkene with a cold, dilute solution of ...
Free Sample
Free access at this time
أكسدة الألكينات: مضاد ثنائي هيدروكسيل مع أحماض البيروكسي
Diols are compounds with two hydroxyl groups. In addition to syn dihydroxylation, diols can also be synthesized through the process of anti ...
Free Sample
Free access at this time
الانقسام التأكسدي للألكينات: تحلل الأزونويل
In ozonolysis, ozone is used to cleave a carbon–carbon double bond to form aldehydes and ketones, or carboxylic acids, depending on the work-up.
...
Free Sample
Free access at this time
الحد من الألكينات: الهدرجة الحفازة
Alkenes undergo reduction by the addition of molecular hydrogen to give alkanes. Because the process generally occurs in the presence of a ...
Free Sample
Free access at this time
تقليل الألكينات: الهدرجة الحفازة غير المتماثلة
Catalytic hydrogenation of alkenes is a transition-metal catalyzed reduction of the double bond using molecular hydrogen to give alkanes. The mode of ...
Copyright © 2025 MyJoVE Corporation. All rights reserved