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Chapter 13

Chemical Kinetics

معدّل التفاعل
معدّل التفاعل
The rate of reaction is the change in the amount of a reactant or product per unit time. Reaction rates are therefore determined by measuring the time ...
قياس معدّلات التفاعل
قياس معدّلات التفاعل
Polarimetry finds application in chemical kinetics to measure the concentration and reaction kinetics of optically active substances during a chemical ...
قانون التركيز والمعدّل
قانون التركيز والمعدّل
The rate of a reaction is affected by the concentrations of reactants. Rate laws (differential rate laws) or rate equations are mathematical expressions ...
تحديد ترتيب التفاعل
تحديد ترتيب التفاعل
Rate laws describe the relationship between the rate of a chemical reaction and the concentration of its reactants. In a rate law, the rate constant k and ...
قانون المعدّل المتكامل: اعتماد التركيز على الوقت
قانون المعدّل المتكامل: اعتماد التركيز على الوقت
While the differential rate law relates the rate and concentrations of reactants, a second form of rate law called the integrated rate law relates ...
نصف عمر التفاعل
نصف عمر التفاعل
The half-life of a reaction (t1/2) is the time required for one-half of a given amount of reactant to be consumed. In each succeeding half-life, half of ...
نظية الاصطدام
نظية الاصطدام
The Collision Theory Atoms, molecules, or ions must collide before they can react with each other. Atoms must be close together to form chemical bonds. ...
مخطّطات أرهينيوس
مخطّطات أرهينيوس
The Arrhenius equation relates the activation energy and the rate constant, k, for chemical reactions. In the Arrhenius equation, k = Ae−Ea/RT, R is ...
آليات التفاعل
آليات التفاعل
Chemical reactions often occur in a stepwise fashion, involving two or more distinct reactions taking place in a sequence. A balanced equation indicates ...
خطوات تحديد المعدّل
خطوات تحديد المعدّل
Relating Reaction Mechanisms In a multistep reaction mechanism, one of the elementary steps progresses significantly slower than the others. This slowest ...
التحفيز
التحفيز
The presence of a catalyst affects the rate of a chemical reaction. A catalyst is a substance that can increase the reaction rate without being consumed ...
الانزيمات
الانزيمات
Inside living organisms, enzymes act as catalysts for many biochemical reactions involved in cellular metabolism. The role of enzymes is to reduce the ...
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