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Capítulo 13

Cinética química

Velocidad de Reacción
Velocidad de Reacción
The rate of reaction is the change in the amount of a reactant or product per unit time. Reaction rates are therefore determined by measuring the time ...
Midiendo las Velocidades de Reacción
Midiendo las Velocidades de Reacción
Polarimetry finds application in chemical kinetics to measure the concentration and reaction kinetics of optically active substances during a chemical ...
Concentración y Ley de Velocidad
Concentración y Ley de Velocidad
The rate of a reaction is affected by the concentrations of reactants. Rate laws (differential rate laws) or rate equations are mathematical expressions ...
Determinando el Orden de Reacción
Determinando el Orden de Reacción
Rate laws describe the relationship between the rate of a chemical reaction and the concentration of its reactants. In a rate law, the rate constant k and ...
Las Leyes de Velocidad Integrada: Dependencia entre la Concentración y el Tiempo
Las Leyes de Velocidad Integrada: Dependencia entre la Concentración y el Tiempo
While the differential rate law relates the rate and concentrations of reactants, a second form of rate law called the integrated rate law relates ...
Vida Media de una Reacción
Vida Media de una Reacción
The half-life of a reaction (t1/2) is the time required for one-half of a given amount of reactant to be consumed. In each succeeding half-life, half of ...
Dependencia de la Temperatura en la Velocidad de Reacción
Dependencia de la Temperatura en la Velocidad de Reacción
The Collision Theory Atoms, molecules, or ions must collide before they can react with each other. Atoms must be close together to form chemical bonds. ...
Los Gráficos de Arrhenius
Los Gráficos de Arrhenius
The Arrhenius equation relates the activation energy and the rate constant, k, for chemical reactions. In the Arrhenius equation, k = Ae−Ea/RT, R is ...
Mecanismos de Reacción
Mecanismos de Reacción
Chemical reactions often occur in a stepwise fashion, involving two or more distinct reactions taking place in a sequence. A balanced equation indicates ...
Pasos Determinantes de la Velocidad
Pasos Determinantes de la Velocidad
Relating Reaction Mechanisms In a multistep reaction mechanism, one of the elementary steps progresses significantly slower than the others. This slowest ...
Catálisis
Catálisis
The presence of a catalyst affects the rate of a chemical reaction. A catalyst is a substance that can increase the reaction rate without being consumed ...
Enzimas
Enzimas
Inside living organisms, enzymes act as catalysts for many biochemical reactions involved in cellular metabolism. The role of enzymes is to reduce the ...
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