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Chapter 13

Chemical Kinetics

קצב תגובה
קצב תגובה
The rate of reaction is the change in the amount of a reactant or product per unit time. Reaction rates are therefore determined by measuring the time ...
מדידת קצבי תגובה
מדידת קצבי תגובה
Polarimetry finds application in chemical kinetics to measure the concentration and reaction kinetics of optically active substances during a chemical ...
חוק הריכוז והקצב
חוק הריכוז והקצב
The rate of a reaction is affected by the concentrations of reactants. Rate laws (differential rate laws) or rate equations are mathematical expressions ...
קביעת סדר התגובה
קביעת סדר התגובה
Rate laws describe the relationship between the rate of a chemical reaction and the concentration of its reactants. In a rate law, the rate constant k and ...
חוק הקצב המשולב: תלות הריכוז בזמן
חוק הקצב המשולב: תלות הריכוז בזמן
While the differential rate law relates the rate and concentrations of reactants, a second form of rate law called the integrated rate law relates ...
זמן מחצית חיים של תגובה
זמן מחצית חיים של תגובה
The half-life of a reaction (t1/2) is the time required for one-half of a given amount of reactant to be consumed. In each succeeding half-life, half of ...
תלות בטמפרטורה של קצב התגוובה
תלות בטמפרטורה של קצב התגוובה
The Collision Theory Atoms, molecules, or ions must collide before they can react with each other. Atoms must be close together to form chemical bonds. ...
עקומות אהרניוס
עקומות אהרניוס
The Arrhenius equation relates the activation energy and the rate constant, k, for chemical reactions. In the Arrhenius equation, k = Ae−Ea/RT, R is ...
מנגנוני תגובה
מנגנוני תגובה
Chemical reactions often occur in a stepwise fashion, involving two or more distinct reactions taking place in a sequence. A balanced equation indicates ...
שלבים קובעי-קצב
שלבים קובעי-קצב
Relating Reaction Mechanisms In a multistep reaction mechanism, one of the elementary steps progresses significantly slower than the others. This slowest ...
קטליזה
קטליזה
The presence of a catalyst affects the rate of a chemical reaction. A catalyst is a substance that can increase the reaction rate without being consumed ...
אנזימים
אנזימים
Inside living organisms, enzymes act as catalysts for many biochemical reactions involved in cellular metabolism. The role of enzymes is to reduce the ...
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