Amy A. Sarjeant

A molecular pinwheel multicopper(I) cluster, [(L(S-))6Cu(I)13(S2-)2]3+ with mu4-sulfido, mu3-thiolato and nitrogen ligands.

Geometric preferences in iron(II) and zinc(II) model complexes of peptide deformylase.

Reactivity study of a hydroperoxodicopper(II) complex: hydroxylation, dehydrogenation, and ligand cross-link reactions.

Thioether sulfur oxygenation from O2 or H2O2 reactivity of copper complexes with tridentate N2Sthioether ligands.

Copper(II)-hydroperoxo complex induced oxidative N-dealkylation chemistry.

Aryl hydroxylation from a mononuclear copper-hydroperoxo species.

Copper(I) complex O(2)-reactivity with a N(3)S thioether ligand: a copper-dioxygen adduct including sulfur ligation, ligand oxygenation, and comparisons with all nitrogen ligand analogues.

Copper(I)/S(8) reversible reactions leading to an end-on bound dicopper(II) disulfide complex: nucleophilic reactivity and analogies to copper-dioxygen chemistry.

Thiol-copper(I) and disulfide-dicopper(I) complex O2-reactivity leading to sulfonate-copper(II) complex or the formation of a cross-linked thioether-phenol product with phenol addition.

Reactions of a copper(II) superoxo complex lead to C-H and O-H substrate oxygenation: modeling copper-monooxygenase C-H hydroxylation.

Carbon monoxide coordination and reversible photodissociation in copper(I) pyridylalkylamine compounds.

Rational tuning of the thiolate donor in model complexes of superoxide reductase: direct evidence for a trans influence in Fe(III)-OOR complexes.

Heme-copper assembly mediated reductive coupling of nitrogen monoxide (*NO).

Toluene and ethylbenzene aliphatic C-H bond oxidations initiated by a dicopper(II)-mu-1,2-peroxo complex.

Post-synthesis alkoxide formation within metal-organic framework materials: a strategy for incorporating highly coordinatively unsaturated metal ions.

Heme/O2/*NO nitric oxide dioxygenase (NOD) reactivity: phenolic nitration via a putative heme-peroxynitrite intermediate.

Synthesis and gas sorption properties of a metal-azolium framework (MAF) material.

Influence of the nitrogen donors on nonheme iron models of superoxide reductase: high-spin Fe(III)-OOR complexes.

Reductive coupling of nitrogen monoxide (*NO) facilitated by heme/copper complexes.

Heme-copper-dioxygen complexes: toward understanding ligand-environmental effects on the coordination geometry, electronic structure, and reactivity.

A catenated strut in a catenated metal-organic framework.

Highly stable tetrathiafulvalene radical dimers in [3]catenanes.

NHC-catalyzed/titanium(IV)-mediated highly diastereo- and enantioselective dimerization of enals.

Plasticity of the nickel(II) coordination environment in complexes with hemilabile phosphino thioether ligands.

Mechanically stabilized tetrathiafulvalene radical dimers.

Selective surface and near-surface modification of a noncatenated, catalytically active metal-organic framework material based on Mn(salen) struts.

Kinetic separation of propene and propane in metal-organic frameworks: controlling diffusion rates in plate-shaped crystals via tuning of pore apertures and crystallite aspect ratios.

Active-site-accessible, porphyrinic metal-organic framework materials.

Post-synthesis modification of a metal-organic framework to form metallosalen-containing MOF materials.

A coordination chemistry dichotomy for icosahedral carborane-based ligands.

Enantioselective total synthesis and studies into the configurational stability of bismurrayaquinone A.

Light-harvesting metal-organic frameworks (MOFs): efficient strut-to-strut energy transfer in bodipy and porphyrin-based MOFs.

Donor-acceptor ring-in-ring complexes.

Crystallographic snapshots of the bond-breaking isomerization reactions involving nickel(II) complexes with hemilabile ligands.

Urea metal-organic frameworks as effective and size-selective hydrogen-bond catalysts.

One-pot synthesis of Mo(0) dinitrogen complexes possessing monodentate and multidentate phosphine ligands.

Designing higher surface area metal-organic frameworks: are triple bonds better than phenyls?

Oligomeric pseudorotaxanes adopting infinite-chain lattice superstructures.

Controlling switching in bistable [2]catenanes by combining donor-acceptor and radical-radical interactions.

The effects of conformation on the noncovalent bonding interactions in a bistable donor-acceptor [3]catenane.

Metal-organic framework materials with ultrahigh surface areas: is the sky the limit?

Room-temperature ferroelectricity in supramolecular networks of charge-transfer complexes.

ExBox: a polycyclic aromatic hydrocarbon scavenger.

One-pot synthesis of an Fe(II) bis-terpyridine complex with allosterically regulated electronic properties.

A neutral naphthalene diimide [2]rotaxane.

Opening ZIF-8: a catalytically active zeolitic imidazolate framework of sodalite topology with unsubstituted linkers.

Light-harvesting and ultrafast energy migration in porphyrin-based metal-organic frameworks.

A radically configurable six-state compound.

Redox-controlled selective docking in a [2]catenane host.

Asararenes--a family of large aromatic macrocycles.

Boron-dipyrromethene-functionalized hemilabile ligands as "turn-on" fluorescent probes for coordination changes in weak-link approach complexes.

General strategy for the synthesis of rigid weak-link approach platinum(II) complexes: tweezers, triple-layer complexes, and macrocycles.

Three-dimensional architectures incorporating stereoregular donor-acceptor stacks.

Vapor-phase metalation by atomic layer deposition in a metal-organic framework.

An exceptionally high boron content supramolecular cuboctahedron.

Ex(2)Box: interdependent modes of binding in a two-nanometer-long synthetic receptor.

Aromatizing olefin metathesis by ligand isolation inside a metal-organic framework.

Enzymatic- and iridium-catalyzed asymmetric synthesis of a benzothiazepinylphosphonate bile acid transporter inhibitor.

Structure and electronic spectra of purine-methyl viologen charge transfer complexes.

Syntheses, structures, and electronic properties of Ba3FeUS6 and Ba3AgUS6.

Efficient syntheses of pillar[6]arene-based hetero[4]rotaxanes using a cooperative capture strategy.

Orally active fumagillin analogues: transformations of a reactive warhead in the gastric environment.

ExCage.

A multi-state, allosterically-regulated molecular receptor with switchable selectivity.

Solid-state characterization and photoinduced intramolecular electron transfer in a nanoconfined octacationic homo[2]catenane.

Mechanical bonds and topological effects in radical dimer stabilization.

Formation of a hetero[3]rotaxane by a dynamic component-swapping strategy.

Water-Stable Zirconium-Based Metal-Organic Framework Material with High-Surface Area and Gas-Storage Capacities.