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Chapter 13

반응 속도론

반응 속도
반응 속도
The rate of reaction is the change in the amount of a reactant or product per unit time. Reaction rates are therefore determined by measuring the time ...
반응 속도 측정
반응 속도 측정
Polarimetry finds application in chemical kinetics to measure the concentration and reaction kinetics of optically active substances during a chemical ...
농도와 속도 법칙
농도와 속도 법칙
The rate of a reaction is affected by the concentrations of reactants. Rate laws (differential rate laws) or rate equations are mathematical expressions ...
반응차수 계산
반응차수 계산
Rate laws describe the relationship between the rate of a chemical reaction and the concentration of its reactants. In a rate law, the rate constant k and ...
적분 속도 법칙: 시간에 의존하는 농도
적분 속도 법칙: 시간에 의존하는 농도
While the differential rate law relates the rate and concentrations of reactants, a second form of rate law called the integrated rate law relates ...
반응의 반감기
반응의 반감기
The half-life of a reaction (t1/2) is the time required for one-half of a given amount of reactant to be consumed. In each succeeding half-life, half of ...
반응 속도의 온도 의존성
반응 속도의 온도 의존성
The Collision Theory Atoms, molecules, or ions must collide before they can react with each other. Atoms must be close together to form chemical bonds. ...
아레니우스 플롯
아레니우스 플롯
The Arrhenius equation relates the activation energy and the rate constant, k, for chemical reactions. In the Arrhenius equation, k = Ae−Ea/RT, R is ...
반응 메커니즘
반응 메커니즘
Chemical reactions often occur in a stepwise fashion, involving two or more distinct reactions taking place in a sequence. A balanced equation indicates ...
속도 결정 단계
속도 결정 단계
Relating Reaction Mechanisms In a multistep reaction mechanism, one of the elementary steps progresses significantly slower than the others. This slowest ...
촉매
촉매
The presence of a catalyst affects the rate of a chemical reaction. A catalyst is a substance that can increase the reaction rate without being consumed ...
효소
효소
Inside living organisms, enzymes act as catalysts for many biochemical reactions involved in cellular metabolism. The role of enzymes is to reduce the ...
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