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Capítulo 13

Cinética Química

Velocidade de Reação
Velocidade de Reação
The rate of reaction is the change in the amount of a reactant or product per unit time. Reaction rates are therefore determined by measuring the time ...
Medição das Velociades de Reação
Medição das Velociades de Reação
Polarimetry finds application in chemical kinetics to measure the concentration and reaction kinetics of optically active substances during a chemical ...
Concentração e Lei da Velocidade
Concentração e Lei da Velocidade
The rate of a reaction is affected by the concentrations of reactants. Rate laws (differential rate laws) or rate equations are mathematical expressions ...
Determinação da Ordem de Reação
Determinação da Ordem de Reação
Rate laws describe the relationship between the rate of a chemical reaction and the concentration of its reactants. In a rate law, the rate constant k and ...
A Lei da Velocidade Integrada: A Dependência da Concentração em Relação ao Tempo
A Lei da Velocidade Integrada: A Dependência da Concentração em Relação ao Tempo
While the differential rate law relates the rate and concentrations of reactants, a second form of rate law called the integrated rate law relates ...
Meia-vida de uma Reação
Meia-vida de uma Reação
The half-life of a reaction (t1/2) is the time required for one-half of a given amount of reactant to be consumed. In each succeeding half-life, half of ...
Dependência da Temperatura em Relação à Velocidade de Reação
Dependência da Temperatura em Relação à Velocidade de Reação
The Collision Theory Atoms, molecules, or ions must collide before they can react with each other. Atoms must be close together to form chemical bonds. ...
Equação de Arrhenius
Equação de Arrhenius
The Arrhenius equation relates the activation energy and the rate constant, k, for chemical reactions. In the Arrhenius equation, k = Ae−Ea/RT, R is ...
Mecanismos de Reação
Mecanismos de Reação
Chemical reactions often occur in a stepwise fashion, involving two or more distinct reactions taking place in a sequence. A balanced equation indicates ...
Passos Determinantes da Velocidade
Passos Determinantes da Velocidade
Relating Reaction Mechanisms In a multistep reaction mechanism, one of the elementary steps progresses significantly slower than the others. This slowest ...
Catálise
Catálise
The presence of a catalyst affects the rate of a chemical reaction. A catalyst is a substance that can increase the reaction rate without being consumed ...
Enzimas
Enzimas
Inside living organisms, enzymes act as catalysts for many biochemical reactions involved in cellular metabolism. The role of enzymes is to reduce the ...
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