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Chapter 14

Chemical Equilibrium

Dynamic Equilibrium
Dynamic Equilibrium
A reversible chemical reaction represents a chemical process that proceeds in both forward (left to right) and reverse (right to left) directions. When ...
The Equilibrium Constant
The Equilibrium Constant
Consider the oxidation of sulfur dioxide: For a reaction that begins with a mixture of reactants only, the product concentration is initially equal to ...
Homogeneous Equilibria for Gaseous Reactions
Homogeneous Equilibria for Gaseous Reactions
Homogeneous Equilibria for Gaseous Reactions For gas-phase reactions, the equilibrium constant may be expressed in terms of either the molar ...
Calculating the Equilibrium Constant
Calculating the Equilibrium Constant
The equilibrium constant for a reaction is calculated from the equilibrium concentrations (or pressures) of its reactants and products. If these ...
Reaction Quotient
Reaction Quotient
The status of a reversible reaction is conveniently assessed by evaluating its reaction quotient (Q). For a reversible reaction described by m A + n B ...
Calculating Equilibrium Concentrations
Calculating Equilibrium Concentrations
Being able to calculate equilibrium concentrations is essential to many areas of science and technology—for example, in the formulation and dosing ...
Le Chatelier's Principle: Changing Concentration
Le Chatelier's Principle: Changing Concentration
A system at equilibrium is in a state of dynamic balance, with forward and reverse reactions taking place at equal rates. If an equilibrium system is ...
Le Chatelier's Principle: Changing Volume (Pressure)
Le Chatelier's Principle: Changing Volume (Pressure)
For gas-phase equilibria, changes in the concentrations of reactants and products can occur with altered volume and pressure. The partial pressure, P, of ...
Le Chatelier's Principle: Changing Temperature
Le Chatelier's Principle: Changing Temperature
Consistent with the law of mass action, an equilibrium stressed by a change in concentration will shift to re-establish equilibrium without any change in ...
The Small x Assumption
The Small x Assumption
If a reaction has a small equilibrium constant, the equilibrium position favors the reactants. In such reactions, a negligible change in concentration may ...
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