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Chapter 14

화학 평형

동적평형
동적평형
A reversible chemical reaction represents a chemical process that proceeds in both forward (left to right) and reverse (right to left) directions. When ...
평형상수
평형상수
Consider the oxidation of sulfur dioxide: For a reaction that begins with a mixture of reactants only, the product concentration is initially equal to ...
기체 반응과 불균일계 반응의 평형
기체 반응과 불균일계 반응의 평형
Homogeneous Equilibria for Gaseous Reactions For gas-phase reactions, the equilibrium constant may be expressed in terms of either the molar ...
평형상수 계산
평형상수 계산
The equilibrium constant for a reaction is calculated from the equilibrium concentrations (or pressures) of its reactants and products. If these ...
반응지수
반응지수
The status of a reversible reaction is conveniently assessed by evaluating its reaction quotient (Q). For a reversible reaction described by m A + n B ...
평형 농도 계산
평형 농도 계산
Being able to calculate equilibrium concentrations is essential to many areas of science and technology—for example, in the formulation and dosing ...
르샤틀리에의 원리: 농도 변화
르샤틀리에의 원리: 농도 변화
A system at equilibrium is in a state of dynamic balance, with forward and reverse reactions taking place at equal rates. If an equilibrium system is ...
르샤틀리에의 원리: 부피 변화 (압력 변화)
르샤틀리에의 원리: 부피 변화 (압력 변화)
For gas-phase equilibria, changes in the concentrations of reactants and products can occur with altered volume and pressure. The partial pressure, P, of ...
르샤틀리에의 원리: 온도 변화
르샤틀리에의 원리: 온도 변화
Consistent with the law of mass action, an equilibrium stressed by a change in concentration will shift to re-establish equilibrium without any change in ...
작은 x 가정
작은 x 가정
If a reaction has a small equilibrium constant, the equilibrium position favors the reactants. In such reactions, a negligible change in concentration may ...
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