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Chapter 10

醇类和酚类

醇类和酚类的结构和命名法
醇类和酚类的结构和命名法
Overview Alcohols are one of the most important functional groups in organic chemistry. The name of alcohol comes from the hydrocarbon from which it is ...
醇类和酚类的物理性质
醇类和酚类的物理性质
Alcohols are organic compounds in which a hydroxy group is attached to a saturated carbon. Phenols are a class of alcohols containing a hydroxy group ...
醇类和酚类的酸度和碱度
醇类和酚类的酸度和碱度
Like water, alcohols are weak acids and bases. This is attributed to the polarization of the O–H bond making the hydrogen partially positive. ...
通过加成反应制备醇类
通过加成反应制备醇类
Overview The acid-catalyzed addition of water to the double bond of alkenes is a large-scale industrial method used to synthesize low-molecular-weight ...
醇类酸催化脱水制烯烃
醇类酸催化脱水制烯烃
In a dehydration reaction, a hydroxyl group in an alcohol is eliminated along with the hydrogen from an adjacent carbon. Here, the products are an alkene ...
羰基化合物中的醇类:还原
羰基化合物中的醇类:还原
Reduction is a simple strategy to convert a carbonyl group to a hydroxyl group. The three major pathways to reduce carbonyls to alcohols are catalytic ...
羰基化合物中的醇类:格氏反应
羰基化合物中的醇类:格氏反应
Grignard reagents are one of the most commonly used reagents used to synthesize alcohols from carbonyl compounds. Grignard reagents are organomagnesium ...
醇类保护
醇类保护
This lesson delves into the concept of protection and deprotection of a functional group fundamental to synthetic organic chemistry. These phenomena are ...
二醇和频那醇重排的制备
二醇和频那醇重排的制备
Compounds bearing two hydroxyl groups are known as diols. When the hydroxyl groups are located on adjacent carbon atoms, the diols are called vicinal ...
醇类转化为烷基卤化物
醇类转化为烷基卤化物
This lesson delves into the conversion of alcohols to corresponding alkyl halides and the mechanism of action for different reagents. Typically, the ...
醇类的氧化
醇类的氧化
In this lesson, the oxidation of alcohols is discussed in depth. The various reagents used for oxidation of primary and secondary alcohols are detailed, ...
通过取代反应制备醇
通过取代反应制备醇
Overview Alcohols can be synthesized from alkyl halides via nucleophilic substitution reactions. The highly polar carbon-halogen bond in the substrate ...
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