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Chapter 10

Electrochemical Analyses and Redox Titration

Electroquímica: Visión general
Electroquímica: Visión general
Electrochemistry is the branch of chemistry that studies the relationship between electrical quantities and chemical reactions, particularly oxidation and ...
Electrodos: Descripción general
Electrodos: Descripción general
 Electrochemical measurements are conducted in an electrochemical cell composed of various components that control and measure the current and ...
Métodos electroquímicos interfaciales: descripción general
Métodos electroquímicos interfaciales: descripción general
Interfacial electrochemical methods focus on the phenomena occurring at the boundary between an electrode and a solution, as opposed to bulk methods that ...
Potenciometría: Visión general
Potenciometría: Visión general
Potentiometry is an analytical technique that measures the potential difference between two electrodes in an electrochemical cell without drawing any ...
Potenciometría: Tipos de electrodos
Potenciometría: Tipos de electrodos
Reference electrodes serve as a stable reference point for potentiometric measurements, while indicator and working electrodes react to variations in the ...
Potenciometría: electrodos de membrana
Potenciometría: electrodos de membrana
Membrane electrodes, also known as p-ion electrodes, use membranes that selectively interact with free analyte ions, generating a potential difference ...
Valoración redox: descripción general
Valoración redox: descripción general
Redox titration is a chemical analysis technique used to determine the concentration of an unknown substance by measuring the electron transfer in a redox ...
Valoración redox: yodometría y yodometría
Valoración redox: yodometría y yodometría
Iodometry and iodimetry are analytical methods used to determine the concentration of oxidizing or reducing agents using iodine. In iodometric titrations, ...
Valoración redox: otros agentes oxidantes y reductores
Valoración redox: otros agentes oxidantes y reductores
Besides iodine, other oxidizing or reducing agents can serve as titrants in redox titrations. Common oxidizing titrants include KMnO4, cerium(IV), and ...
Valoración potenciométrica: descripción general
Valoración potenciométrica: descripción general
Potentiometric titration is a quantitative analytical technique that determines the concentration of an analyte by measuring the potential difference ...
Predicción del punto final: Gran Plot
Predicción del punto final: Gran Plot
A Gran plot is used to predict the equivalence volume or endpoint of a potentiometric or acid-base titration without reaching the endpoint. Typically, ...
Análisis electrogravimétrico: descripción general
Análisis electrogravimétrico: descripción general
Electrogravimetric analysis measures the weight of an analyte deposited electrolytically onto a suitable working electrode. This method involves applying ...
Coulometría: Visión general
Coulometría: Visión general
Coulometry is one of the rapid, most accurate, and precise analytical techniques that determine the quantity of an analyte by measuring the electrical ...
Coulometría de Potencial Controlado: Métodos Electrolíticos
Coulometría de Potencial Controlado: Métodos Electrolíticos
Controlled-potential coulometry, also known as potentiostatic coulometry, employs a three-electrode system in which the working electrode's potential ...
Coulometría de corriente controlada: descripción general
Coulometría de corriente controlada: descripción general
Controlled current coulometry, also known as amperostatic coulometry, is a technique used in electrochemical analysis to measure the quantity of a ...
Coulometría de corriente controlada: valoración coulométrica
Coulometría de corriente controlada: valoración coulométrica
Coulometric titrations are a form of titrimetric analysis where the reagent is generated electrically, and its amount is evaluated based on current and ...
Voltamperometría: Descripción general
Voltamperometría: Descripción general
Voltammetry is an electroanalytical technique in which the current flowing through an electrochemical cell is measured as a function of applied potential, ...
Voltamperometría: Factores que afectan a las mediciones
Voltamperometría: Factores que afectan a las mediciones
A current produced due to the redox reactions of the analyte at the working and auxiliary electrodes is called a faradaic current. The reaction can be ...
Voltammogramas: Descripción general
Voltammogramas: Descripción general
Voltammograms are current plots as a function of applied potential, offering insights into electrochemical systems. The shape of a voltammogram depends on ...
Técnicas voltamperométricas: escaneo lineal (E vs tiempo)
Técnicas voltamperométricas: escaneo lineal (E vs tiempo)
Polarography is a classical voltammetric technique used to analyze electrochemical reactions. This method applies a linear potential sweep to a dropping ...
Técnicas de voltamperometría: voltamperometría de pulso
Técnicas de voltamperometría: voltamperometría de pulso
Differential-pulse voltammetry (DPV) is a type of voltammetry that involves applying a series of voltage pulses to an electrochemical cell while measuring ...
Técnicas de voltamperometría: voltamperometría cíclica
Técnicas de voltamperometría: voltamperometría cíclica
Cyclic voltammetry (CV) is an electrochemical technique used to investigate the redox properties of a chemical species. It involves measuring the current ...
Voltammetría: Métodos de pelado
Voltammetría: Métodos de pelado
Anodic Stripping Voltammetry (ASV), Cathodic Stripping Voltammetry (CSV), and Adsorptive Stripping Voltammetry (AdSV) are electrochemical techniques used ...
Amperometría: Descripción general
Amperometría: Descripción general
Amperometry is a technique commonly used to measure the concentration of specific analytes in a solution by monitoring the electric current generated ...
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