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第6章

熱化学

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エネルギーの基礎
エネルギーの基礎
Chemical reactions, such as those that occur when you light a match, involve changes in energy as well as matter. Chemical changes and their accompanying ...

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熱力学の第一法則
熱力学の第一法則
Energy Conservation Energy can be converted from one form into another, but all of the energy present before a change occurs always exists in some form ...

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内部エネルギー
内部エネルギー
The total of all possible kinds of energy present in a substance is called the internal energy (U), sometimes symbolized as E. Suppose a system with ...

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熱の定量化
熱の定量化
Thermal Energy  Microscopically, thermal energy is the kinetic energy associated with the random motion of atoms and molecules. Temperature is a ...

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運動の定量化
運動の定量化
As a system undergoes a change, its internal energy can change, and energy can be transferred from the system to the surroundings, or from the ...

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エンタルピー
エンタルピー
Chemists ordinarily use a property known as enthalpy (H) to describe the thermodynamics of chemical and physical processes. Enthalpy is defined as the sum ...

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熱化学方程式
熱化学方程式
For a chemical reaction (the system) carried out at constant pressure – with the only work done caused by expansion or contraction – the ...

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一定圧力の熱量測定
一定圧力の熱量測定
Calorimetry is a technique used to measure the amount of heat involved in a chemical or physical process or to measure the heat transferred to or from a ...

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一定体積の熱量測定
一定体積の熱量測定
Calorimeters are useful to determine the heat released or absorbed by a chemical reaction. Coffee cup calorimeters are designed to operate at constant ...

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ヘスの法則
ヘスの法則
There are two ways to determine the amount of heat involved in a chemical change: measure it experimentally, or calculate it from other experimentally ...

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標準生成エンタルピー
標準生成エンタルピー
Enthalpy changes are typically tabulated for reactions in which both the reactants and products are at the same conditions. A standard state is a commonly ...

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反応エンタルピー
反応エンタルピー
Hess’s law can be used to determine the enthalpy change of any reaction if the corresponding enthalpies of formation of the reactants and products ...
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