Name: deposition of porous sorbents on fabric supports
Uploaded: 2018-06-12T14:45:00.000+00:00
Duration: 5 min 58 s
Description: Watch this Scientific Journal Video about Deposition of Porous Sorbents on Fabric Supports at JoVE.com

This research was sponsored by the Defense Threat Reduction Agency (DTRA BA08PRO015) and the U.S. Office of Naval Research through Naval Research Laboratory base funds. The views expressed here are those of the authors and do not represent those of the U.S. Navy, the U.S. Department of Defense, or the U.S. Government.

1. Microwave Initiation
<ol>
	<li>Prepare the initiation solution by mixing 10 mL of ammonium hydroxide (28 - 30%) with 184 mL of isopropanol in a glass beaker using a magnetic stir bar at 150 rpm. Add 6 mL of tetraethyl orthosilicate (TEOS) to the ammonium hydroxide solution5. 
	Caution: Ammonium Hydroxide is an alkali solution that poses irritation and burn hazards on contact with eyes and skin as well as toxicity upon inhalation or ingestion. 
	Caution: Tetraethyl orthosilicate is flammable and toxic.</li>
	<li>To initiate the sample, submerge fabric substrate fully in the TEOS mixture and remove to a glass, microwave safe dish. 
	NOTE: The fabric used here was a light weight, unbleached cotton obtained from a specialty crafts and fabrics retailer. The described process is suitable to a wide range of fabrics with the limitation that they must have available hydroxyl or amine groups5. The size of the dish is not important provided the cloth can lie flat within it.
	<ol>
		<li>Microwave the saturated fabric sample using 1,200 W for 30 s. 
		Caution: Fabric sample and dish will be hot following treatment. Microwave samples with sufficient ventilation and avoid inhalation of resulting vapors.</li>
		<li>Repeat soaking and microwave treatment for a total of three cycles. 
		NOTE: TEOS mixture becomes cloudy quickly as precipitation occurs. Use immediately.</li>
		<li>Dry treated fabric at 100 &#176;C for 30 min in a drying oven. Once dry, the fabric can be stored under ambient conditions. 
		NOTE: The oven used here was a gravity oven, but any oven of sufficient size is suitable for drying the materials.</li>
	</ol>
	</li>
</ol>
2. Preparation of Sol for Dip Coating
<ol>
	<li>To prepare the sol, mix 1.9 g of Pluronic P123, 0.5 g of mesitylene, and 2.12 g of 1,2-bis(trimethyoxysilyl)ethane (BTE) in a plastic vial at room temperature15,16,17,18,20,21. 
	Caution: 1,2-Bis(trimethyoxysilyl)ethane is flammable and toxic. Avoid skin contact and inhalation. Mesitylene is flammable and toxic. Avoid skin contact and inhalation.
	<ol>
		<li>Add 2.0 g of methanol and a magnetic stir bar. Seal the container and stir at 150 rpm. 
		Caution: Methanol is flammable and toxic and may present other health hazards. Avoid skin contact and inhalation. 
		NOTE: In variations of this deposition, ethanol may be used in place of the methanol of this protocol. Additional information is provided in the Discussion.</li>
		<li>When the stirred solution appears homogeneous, add 6.07 g of 0.1 M HNO3 dropwise. 
		Caution: Nitric acid is corrosive and can cause skin, eye, and respiratory system irritation. Avoid skin contact and inhalation.</li>
		<li>Continuing stirring the mixture for 6 h. 
		NOTE: The mixture is stable overnight at this point, but only in the absence of evaporation. If methanol evaporates during storage, changes to the sol-gel will occur.</li>
	</ol>
	</li>
</ol>
3. Dip Coating Fabric
<ol>
	<li>Dip the TEOS treated fabric into the prepared sol at a rate of 150 mm/min. 
	NOTE: Faster rates of up to 270 mm/min can be used with no negative impact on the resulting materials. Here, any equipment achieving dip and draw rates between 150 and 270 mm/min is suitable.
	<ol>
		<li>Transfer the sample to hang dry in a 60 &#176;C oven for 24 h.</li>
		<li>Continue curing at 80 &#176;C for an additional 24 h. 
		NOTE: Higher curing temperatures of up to 120 &#176;C are acceptable at this point. After curing, the fabric can be stored at ambient temperature, allowing for later extraction.</li>
	</ol>
	</li>
	<li>Immerse the fabric sample in excess ethanol at 65 &#176;C for 48 h to extract surfactant. 
	Caution: Ethanol is flammable. 
	NOTE: Ensure the container will tolerate necessary temperatures.
	<ol>
		<li>Rinse the fabric with additional ethanol.</li>
	</ol>
	</li>
	<li>Dry the fabric overnight at 60 - 65 &#176;C. Once dry, the fabric can be stored under ambient conditions.</li>
</ol>
4. Porphyrin Functionalization of Coated Fabrics
<ol>
	<li>To functionalize the sorbent material with primary amine groups, prepare a solution of 3-aminopropyltriethoxy silane (APS) in toluene at 0.5% volume/volume15,16. 
	Caution: 3-Aminopropyltriethoxy silane is corrosive and toxic. Avoid skin contact and inhalation. Toluene is flammable, toxic, and a known carcinogen. Avoid skin contact and inhalation.
	<ol>
		<li>Submerge fabric in the solution and incubate for 1 h, covered.</li>
		<li>Rinse the samples thoroughly with toluene.</li>
		<li>Dry the fabric samples overnight at 100 &#176;C.</li>
	</ol>
	</li>
	<li>To prepare the copper complex of Deuteroporphyrin IX 2,4 bis ethylene glycol (DIX), dissolve 20 mg of the porphyrin in 2 mL dimethyl sulfoxide22. 
	Caution: Porphyrins may present health hazards; follow recommended precautionary procedures.
	<ol>
		<li>Add the porphyrin solution to 100 mL of water with 12.8 mg of copper (II) chloride in a round bottom flask. 
		Caution: Copper chloride is corrosive, toxic, and presents hazards to the aquatic environment. Avoid skin contact and inhalation.</li>
		<li>Reflux the solution overnight.</li>
		<li>Use rotary evaporation to reduce total sample volume to 5 mL. 
		NOTE: The porphyrin can be prepared in larger quantities for later use. Prepared porphyrin should be stored in the dark at room temperature.</li>
	</ol>
	</li>
	<li>Add the prepared porphyrin solution to 15 mL of 0.1 M 2-(N-morpholino)ethansulfonic acid (MES) buffer pH 5.5.
	<ol>
		<li>Add 5 mg of 1-ethyl-3-(3-dimethylaminopropyl)carbodiimide (EDC) to the solution and immediately submerge the fabric samples.</li>
		<li>Cover the samples and incubate overnight.</li>
		<li>Rinse the samples thoroughly using water.</li>
		<li>Dry the fabric samples overnight at 100 &#176;C.</li>
	</ol>
	</li>
</ol>
5. Characterization of Fabrics
<ol>
	<li>Use any commercially available nitrogen adsorption characterization system according to manufacturer protocols to characterize the porosity of the fabric samples. 
	NOTE: Here, nitrogen adsorption analysis was completed 77 K. Depending on the system used, it may be necessary to weigh samples or degas at &#8805;65 &#176;C prior to analysis.
	<ol>
		<li>Use the Brunauer-Emmett-Teller (BET) method for determination of surface area.</li>
		<li>Use the Barrett-Joyner-Halenda (BJH) method for determination of the pore size from the adsorption branch of the isotherm.</li>
		<li>Use the single point method to determine the pore volume at relative pressure (P/P0) 0.97.</li>
	</ol>
	</li>
	<li>Characterize the permeation of 2-chloroethyl ethyl sulfide (CEES) through fabric samples by following the guidance provided by Test Operations Procedure (TOP) 8-2-501, Permeation Testing of Materials with Chemical Agents or Simulants (Swatch Testing)23,24. 
	Caution: 2-Chloroethyl ethyl sulfide is flammable, corrosive, toxic, and presents a health hazard. Avoid skin contact and inhalation. 
	NOTE: Under this study, an internal, probe driven heater was used to control the temperature within a custom environmental. The ratio of humid to dry air entering this chamber is addressed using probe driven mass flow controllers. The stainless-steel aerosol-vapor-liquid-assessment group (AVLAG) cell holds the sample horizontally with O-ring seals. Diffusive permeation testing uses a nitrogen stream. The headspace above the swatch, in which the target is placed, is stagnant with no pressure difference above and below the swatch. The sample is supported between two solid support discs with aligned 0.64 cm2 circular openings. This assembly is placed in the AVLAG cell, and humidity is equilibrated for 2 h. Target is introduced as liquid droplets using a repeating dispenser. A dedicated FID allows for continuous monitoring of target concentrations.</li>
	<li>Follow the guidance provided by ASTM E96, Water Vapor Transport: Upright Open Cup Method to characterize water vapor transport through the fabric samples4,24,25.
	<ol>
		<li>Modify an incubator to provide an enclosure for this analysis at 25 &#176;C.</li>
		<li>Fill a scintillation vial (20 mL) with 16.9 mL deionized water. Seal the sample material over this vial, and weigh the vial. Use desiccant to drive a humidity differential in the incubator, and align a dry nitrogen stream so that it flowed across the surface of the sample (0.25 L/min).</li>
		<li>Measure the weight of the sample covered vial at 30 to 45 min intervals using an analytical balance.</li>
	</ol>
	</li>
</ol>

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The authors declare that they have no competing financial interests.

Here, we have shown that the microwave-initiated deposition of TEOS can be used to prepare fabric for subsequent deposition of a porous organosilicate sorbent. The approach leads to loading of the fabric with 1.12 g sorbent per m2 of fabric surface. Analysis of the coated fabric by nitrogen adsorption indicated deposition of a porous coating with significant differences between the full treated material and that of the initiated fabric. The surface area was, however, less than that observed for a similarly composed material synthesized as a monolith. The sorbent alone reduced the rate of CEES transport across the fabric by 85%. Addition of the porphyrin functionalization to the supported sorbent further decreased transport (93% total reduction). Initial breakthrough for the porphyrin functionalized treated fabric occurred at 2 min; initial breakthrough the cotton fabric was at 0.6 min. This reduction in chemical permeation was achieved with little impact on the water vapor transport of the fabric.
The deposited sorbent is not a continuous thin film. The approach produces a coating that is more closely conformal to the yarn of the fabric. As a result, reduction to permeation is limited by the weave of the fabric. Here, a light-weight cotton fabric is used as the support material. The microwave initiation is suitable for use on other fabrics that provide amine or hydroxyl groups for modification. A more densely woven fabric, such as the nylon and cotton blend used in the US Army Combat Uniform (ACU), would produce greater reduction to target transport simply on the basis of reduction in void spaces within the weave. A densely woven fabric used as a shelter material would provide similar advantages. Recalling that the sorbent treatment is not limited to the surface of the fabric, a material providing some depth in the manner of a fleece or heavy knit fabric would also be expected to produce additional reductions in permeation. This concept would also apply to the three-dimensional pleated materials used in air filtration.
The treatment outlined here is not limited to use on traditional fabrics. It provides the potential for modification of the paper, layered, and pleated materials more typically applied in filtration approaches as well as nonwoven textiles. In some cases, the conditions described here may need to be gentled to maintain the integrity of the supporting material. Reducing the concentration of the base (ammonium hydroxide) may be necessary, as in the case of polyethylene fabrics. Shortening the duration of the microwave period may be necessary to avoid scorching (paper materials). Some synthetic fabrics, polypropylene for example, require reduction in the drying temperatures used. Changes to sol aging temperatures and durations should be avoided as these conditions have significant impact on the morphology of the resulting sorbent.
Ethanol may be substituted for methanol in the dip coating sol. This is encouraged when scaling up a synthesis and using a larger volume of sol, because ethanol presents a lesser health hazard. The sol can be diluted considerably with alcohol, e.g., 4 to 12 g ethanol instead of 2 g methanol) to prepare a greater volume of the mixture without a proportional increase in the masses of BTE, Pluronic P123, mesitylene, and acid. Relative amounts of reactants and solvent can also be multiplied to prepare a sol for generation of larger samples of coated materials. The degree of dilution or concentration of a sol may impact the resulting mass loading of sorbent material on a particular fabric. Multiple cycles of dipping into a sol mixture should also lead to changes in total loading.
Optimization of the deposition approach for other support materials is ongoing. Modification of the ACU nylon and cotton blend fabric is of particular interest for a daily wear solution providing baseline chemical protection as are jersey knit based materials. The deposition of other sorbent materials is also being explored. The diethylbenzene bridged sorbents developed for capture of pesticide targets, for example, use a sol preparation that differs from the one described here17,20,27 and catalysis is based on a different porphyrin. Finally, evaluation of the fabric supported materials against aerosol, liquid, and vapor targets is ongoing.

Currently available chemical protective garments used by the US Department of Defense (DoD) either provide a full barrier, the Level A chemical protective suit, for example, or use multiple layers of fabric for protection, as in the Joint Service Lightweight Integrated Suit Technology (JSLIST). Full barrier garments impose a significant burden on the user. With no water vapor transport through the material, thermal regulation is hindered. As a result, the duration of use (mission length) is restricted; the garment is appropriate to a limited range of scenarios. The JSLIST, on the other hand, uses a layer of carbon adsorbent between a shell fabric and a comfort layer. The resulting burden on the user is reduced but not eliminated, and protective capabilities are reduced in comparison to the barrier suits. Beyond the thermal burden, the JSLIST suit is suitable for only 24 hours of continuous use. Neither of these types of technology are suitable for providing a baseline protective capability in a long term, daily wear garment. Baseline protection would be of use for low hazard environments, conditions suitable to MOPP 0 through 2 (MOPP - Mission Oriented Protective Posture), and other low risk conditions. Beyond DoD concerns, baseline protection would be of utility to first responders who may enter contaminated environments with no prior warning.
Research seeking improvements to DoD protective garments is ongoing and continuous1,2,3,4. A previous effort identified the potential of a microwave initiated process for deposition of heptadecafluoro-1,1,2,2-tetrahydrodecyl)trimethoxysilane on fabrics to produce oleophobic behavior5. The intention was to produce a fabric that may enhance the shell layer of the JSLIST garment. While this oleophobicity may improve the chemical resistance of the layered garment, it will not address the thermal burden imposed by the suit. There is additional ongoing work focused on sorbents and catalysts for capture and/or decomposition of chemical threats6,7,8,9,10,11,12,13,14. A recently described approach used porous organosilicate sorbents combined with porphyrins to capture and degrade phosgene and used similar materials for capture of toxic industrial compounds (TICS) as well as pesticide simulants and nitroenergetics15,16,17,18,19,20. While promising, these powdered materials are not directly applicable to garment technologies.
Organosilicate systems have been widely applied in dip and spin coating approaches, typically, on glass and silicon wafers. The microwave deposition technique described above provides a mechanism for application of these materials to fabrics. Here, we use the described process in combination with tetraethylorthosilicate to prepare fabrics. They are then treated with the porous sorbents through a dip coating approach. Morphological characterization demonstrates the presence of the porous sorbent on the fabric. Evaluation of 2-chloroethyl ethyl sulfide (CEES) permeation through the fabric with and without this treatment shows a significant impact on transport of the target across the material.

<table><tbody><tr><td>unbleached 100% cotton fabric</td><td>JOANN Stores</td><td>N/A</td><td>Protocol is suitable for use on a variety of fabrics</td></tr><tr><td>ammonium hydroxide</td><td>Aldrich</td><td>32,014-5</td><td></td></tr><tr><td>tetraethyl orthosilicate</td><td>Aldrich</td><td>13,190-3</td><td></td></tr><tr><td>Pluronic P123</td><td>Aldrich</td><td>435465</td><td></td></tr><tr><td>mesitylene</td><td>Sigma-Aldrich</td><td>M7200</td><td></td></tr><tr><td>1,2-bis(trimethoxysilyl)ethane</td><td>Aldrich</td><td>447242</td><td></td></tr><tr><td>methanol</td><td>Fisher Chemical</td><td>A454SK-4</td><td></td></tr><tr><td>nitric acid</td><td>Sigma-Aldrich</td><td>438073</td><td>Prepare 0.1 M aqueous solution</td></tr><tr><td>3-aminopropyltriethoxysilane</td><td>Gelest</td><td>SIA0603.4</td><td></td></tr><tr><td>toluene</td><td>Sigma-Aldrich</td><td>650579</td><td></td></tr><tr><td>Deuteroporphyrin IX bis ethylene glycol</td><td>Frontier Scientific</td><td>D630-9</td><td></td></tr><tr><td>dimethyl sulfoxide</td><td>Sigma-Aldrich</td><td>276855</td><td></td></tr><tr><td>copper chloride</td><td>Sigma-Aldrich</td><td>256528</td><td></td></tr><tr><td>2-(N-morpholino)ethansulfonic acid</td><td>Sigma-Aldrich</td><td>M3671</td><td>Prepare 0.1M buffer at pH 5.5</td></tr><tr><td>1-ethyl-3-(3-dimethylaminopropyl)carbodiimide</td><td>Sigma-Aldrich</td><td>E6383</td><td></td></tr><tr><td>ethyl alcohol</td><td>Warner-Graham</td><td>64-17-5</td><td></td></tr><tr><td>Drierite</td><td>Sigma-Aldrich</td><td>737828</td><td></td></tr><tr><td>Microwave</td><td>Daewoo</td><td>KOR-630A</td><td></td></tr><tr><td>Nitrogen adsorption instrument</td><td>Micromeritics</td><td>&amp;nbsp;TriStar II Plus&amp;nbsp;</td><td></td></tr><tr><td>Environmental chamber</td><td>custom part</td><td>N/A</td><td>Here, a modified Thermolyne incubator, Compact Series 5000 was used</td></tr><tr><td>Flame ionization detector (FID)</td><td>SRI Instruments</td><td>8690-0010</td><td>Model 110</td></tr><tr><td>Humidity probe</td><td>Vaisala</td><td>HMT3303E0A193BCAC100A0CCABEA1</td><td></td></tr><tr><td>AVLAG Cell</td><td>custom part</td><td>N/A</td><td>AERO-Space Tooling and Machining, P/N RS0010 Permeation cell</td></tr><tr><td>Computer controlled heater</td><td>World Precision Instruments</td><td>AIRTHERMY-ATX</td><td></td></tr><tr><td>Mass flow controller</td><td>MKS Instruments</td><td>1179A01312CS</td><td></td></tr><tr><td>Dipper mechanism Type D1L</td><td>NIMA Technology Ltd</td><td>D1L</td><td></td></tr><tr><td>Gravity oven</td><td>Fisher Scientific</td><td>15-103-0520</td><td></td></tr><tr><td>Stirring hotplate</td><td>Fisherbrand</td><td>S28482</td><td></td></tr><tr><td>Octagon spinbar, magnetic stirring bar</td><td>Fisherbrand</td><td>14-513-82</td><td></td></tr><tr><td>PSI-Plot version 9.5</td><td>Poly Software International, Inc</td><td>N/A</td><td></td></tr><tr><td>Microsoft Office Professional Plus - Excel 2013 32-bit</td><td>Microsoft</td><td>N/A</td><td></td></tr><tr><td>MicroActive TriStar II Plus Software</td><td>Micromeritics</td><td>packaged with the TriStar II nitrogen adsorption instrument</td><td></td></tr></tbody></table>

deposition of porous sorbents on fabric supports

A microwave deposition technique for silanes, previously described for production of oleophobic fabrics, is adapted to provide a fabric support material that can be subsequently treated by dip coating. Dip coating with a sol preparation provides a supported porous layer on the fabric. In this case, the porous layer is a porphyrin functionalized sorbent system based on a powdered material that has been demonstrated previously for the capture and conversion of phosgene. A representative coating is applied to cotton fabric at a loading level of 10 mg/g. This coating has minimal impact on water vapor transport through the fabric (93% of the support fabric rate) while significantly reducing transport of 2-chloroethyl ethyl sulfide (CEES) through the material (7% of support fabric rate). The described approaches are suitable for use with other fabrics providing amine and hydroxyl groups for modification and can be used in combination with other sol preparations to produce varying functionality.

Nitrogen adsorption was used to evaluate the treated fabric following the dip coating procedure. As shown in Figure 1, the expected isotherm was obtained for the porous coating. This contrasts with the behaviors noted for the untreated fabric and for the microwave-initiated fabric. Negligible nitrogen adsorption was noted for the fabric alone and the fabric following microwave treatment. No pore sizes were determined. The porous coating produced a surface area of 3.39 m2/g with pore volume 0.013 cm3/g. While the instrument reported a BJH adsorption pore size of 76 &#197;, no significant features are observed in the pore size distribution. Images of the fabric at each stage in the coating process are provided in Figure 2. The average mass of sorbent deposited on the cotton support was determined to be 0.01 g/g based on the differential weight of samples before deposition and after the final drying process, an increase in weight of ~1% from the original fabric. If the measured surface area and pore volume are corrected to account for only the sorbent mass component of the material, the surface area for the sorbent is 339 m2/g with pore volume 1.3 cm3/g. For comparison, when this sorbent was synthesized as a monolith in a closed reactor, nitrogen porosimetry indicated a BET surface area of 1143 m2/g with pore volume 1.01 m2/g and pore diameter 76 &#197;26. A type IV-like isotherm was observed for this material with significant hysteresis (Figure 3). A thick film sample was prepared by curing the dip-coating sol in a Petri dish and processing based on the protocol used for coated fabric samples. Nitrogen porosimetry indicated a BET surface area of 968 m2/g with pore volume 0.78 cm3/g and pore diameter 39 &#197; for this material (Figure 3).
The water vapor transport (WVT) rate for the treated fabrics was evaluated using a two chambered cell4,24,25. This evaluation used a circular fabric sample with a total exposed area of 1.65 cm2. As shown in Figure 4, microwave initiation of the fabric caused a slight reduction in water vapor transport as compared to the untreated cotton. No additional changes in water vapor transport were noted following sorbent deposition or functionalization with porphyrin. The WVT rate for the cotton fabric was determined to be 121 g/h/m2. The WVT rate was reduced to 112 g/h/m2 upon microwave initiation. A WVT rate of 113 g/h/m2 was determined for the full porphyrin-functionalized treatment.
2-Chloroethyl ethyl sulfide (CEES) was used as a simulant to determine whether deposition of the porous treatment resulted in changes to chemical transport properties for the fabric. CEES is commonly used as a simulant for sulfur mustard, a chemical warfare agent. The sorbent material used here consists of ethane-bridging groups and has been functionalized with a copper Deuteroporphyrin IX 2,4 bis ethylene glycol (CuDIX) metalloporphyrin. This reflects the characteristics of the sorbent system demonstrated previously for use in capture of phosgene15,16. Chemical vapor transport was determined using aerosol-vapor-liquid-assessment group (AVLAG) cells23,24. The method uses continuous flow with flame ionization detection (FID) under controlled temperature (40 &#176;C) and relative humidity (50%) for total exposed area of 0.64 cm2. Figure 5 provides time-dependent FID responses. When the cotton fabric alone was evaluated, a peak rate of 67 g/h/m2 was noted with no retention of the target (214 &#181;g total). The porous treatment resulted in significant reduction to both the peak rate of transport (9.6 g/h/m2) and the total transport of target through the fabric. Only 78 &#181;g of the 214 &#181;g CEES originally applied was recovered over an 83 h period. The porphyrin functionalized porous treatment further reduced the peak rate of transport to 4.5 g/h/m2 with a total transport of 39 &#181;g CEES over the 83 h experiment.
<img alt="Figure 1" class="xfigimg" src="/files/ftp_upload/57331/57331fig1.jpg" /> 
Figure 1: Morphological characterization of fabrics. Shown here are representative nitrogen sorption isotherms (A) and pore size distributions (B) for a typical fabric swatch (red), a similar swatch following the microwave initiation process (blue), the fabric following application of the sorbent (green), and the fabric following application of the full sorbent system (black). <a href="/files/ftp_upload/57331/57331fig1large.jpg" target="_blank">Please click here to view a larger version of this figure.</a>
<img alt="Figure 2" class="xfigimg" src="/files/ftp_upload/57331/57331fig2.jpg" /> 
Figure 2: Photographs of fabric. The photograph here shows the microwave initiated, sorbent coated material (A), the CuDIX porphyrin alone on cotton (B), and a full porphyrin functionalized coating on the cotton (C). The treated swatches are overlaid on the untreated cotton fabric. <a href="/files/ftp_upload/57331/57331fig2large.jpg" target="_blank">Please click here to view a larger version of this figure.</a>
<img alt="Figure 3" class="xfigimg" src="/files/ftp_upload/57331/57331fig3.jpg" /> 
Figure 3: Morphological characterization of unsupported sorbent. Shown here are representative nitrogen sorption isotherms (A) and pore size distributions (B) for the sorbent when synthesized as a monolith (black) and when synthesized as a thick film (red)26. <a href="/files/ftp_upload/57331/57331fig3large.jpg" target="_blank">Please click here to view a larger version of this figure.</a>
<img alt="Figure 4" class="xfigimg" src="/files/ftp_upload/57331/57331fig4.jpg" /> 
Figure 4: Water vapor permeation. Results from water vapor permeation analysis are presented for the complete CuDIX porphyrin functionalized sorbent on cotton fabric (black). Cotton fabric only (red) and cotton fabric with only the sorbent component (blue) are presented for comparison. <a href="/files/ftp_upload/57331/57331fig4large.jpg" target="_blank">Please click here to view a larger version of this figure.</a>
<img alt="Figure 5" class="xfigimg" src="/files/ftp_upload/57331/57331fig5.jpg" /> 
Figure 5: Permeation of CEES. Permeation of CEES through a complete porphyrin functionalized sorbent coating on cotton fabric is presented (black). Fabric only (red) and fabric with only the sorbent component (blue) are presented for comparison. The inset provides a zoomed view of the initial breakthrough period for the three materials. <a href="/files/ftp_upload/57331/57331fig5large.jpg" target="_blank">Please click here to view a larger version of this figure.</a>

Watch this Scientific Journal Video about Deposition of Porous Sorbents on Fabric Supports at JoVE.com

Deposition of Porous Sorbents on Fabric Supports

This report details a microwave-initiated approach for deposition of porphyrin functionalized porous organosilicate sorbents on a cotton fabric and demonstrates reduction in 2-chloroethyl ethyl sulfide (CEES) transport through the fabric resulting from this treatment.

A microwave deposition technique for silanes, previously described for production of oleophobic fabrics, is adapted to provide a fabric support material ...

deposition-of-porous-sorbents-on-fabric-supports

Research

JoVE Journal

Chemistry

6.5K Views.  Naval Research Laboratory. This report details a microwave-initiated approach for deposition of porphyrin functionalized porous organosilicate sorbents on a cotton fabric and demonstrates reduction in 2-chloroethyl ethyl sulfide (CEES) transport through the fabric resulting from this treatment.

Video: Deposition of Porous Sorbents on Fabric Supports

Preparation of Hydrophobic Metal-Organic Frameworks via Plasma Enhanced Chemical Vapor Deposition of Perfluoroalkanes for the Removal of Ammonia

Plasma enhanced chemical vapor deposition (PECVD) of perfluoroalkanes has long been studied for tuning the wetting properties of surfaces. For high surface area microporous materials, such as metal-organic frameworks (MOFs), unique challenges present themselves for PECVD treatments. Herein the protocol for development of a MOF that was previously unstable to humid conditions is presented. The protocol describes the synthesis of Cu-BTC (also known as HKUST-1), the treatment of Cu-BTC with PECVD of perfluoroalkanes, the aging of materials under humid conditions, and the subsequent ammonia microbreakthrough experiments on milligram quantities of microporous materials. Cu-BTC has an extremely high surface area (~1,800 m2/g) when compared to most materials or surfaces that have been previously treated by PECVD methods. Parameters such as chamber pressure and treatment time are extremely important to ensure the perfluoroalkane plasma penetrates to and reacts with the inner MOF surfaces. Furthermore, the protocol for ammonia microbreakthrough experiments set forth here can be utilized for a variety of test gases and microporous materials.

Herein the procedures for plasma enhanced chemical vapor deposition of perfluoroalkanes on microporous materials such as metal-organic frameworks to enhance their stability and hydrophobicity are described. Furthermore, breakthrough testing of milligram quantities of samples is described in detail.

Plasma enhanced chemical vapor deposition (PECVD) of perfluoroalkanes has long been studied for tuning the wetting properties of surfaces. For high ...

Characterization and Application of Passive Samplers for Monitoring of Pesticides in Water

Five different water passive samplers were calibrated under laboratory conditions for measurement of 124 legacy and current used pesticides. This study provides a protocol for the passive sampler preparation, calibration, extraction method and instrumental analysis. Sampling rates (RS) and passive sampler-water partition coefficients (KPW) were calculated for silicone rubber, polar organic chemical integrative sampler POCIS-A, POCIS-B, SDB-RPS and C18 disk. The uptake of the selected compounds depended on their physicochemical properties, i.e., silicone rubber showed a better uptake for more hydrophobic compounds (log octanol-water partition coefficient (KOW) &#62; 5.3), whereas POCIS-A, POCIS-B and SDB-RPS disk were more suitable for hydrophilic compounds (log KOW &#60; 0.70).

A protocol about the characterization and application of five different passive sampling devices is presented.

Five different water passive samplers were calibrated under laboratory conditions for measurement of 124 legacy and current used pesticides. This study ...

Environment

Air Filter Devices Including Nonwoven Meshes of Electrospun Recombinant Spider Silk Proteins

Based on the natural sequence of Araneus diadematus Fibroin 4 (ADF4), the recombinant spider silk protein eADF4(C16) has been engineered. This highly repetitive protein has a molecular weight of 48kDa and is soluble in different solvents (hexafluoroisopropanol (HFIP), formic acid and aqueous buffers). eADF4(C16) provides a high potential for various technical applications when processed into morphologies such as films, capsules, particles, hydrogels, coatings, fibers and nonwoven meshes. Due to their chemical stability and controlled morphology, the latter can be used to improve filter materials. In this protocol, we present a procedure to enhance the efficiency of different air filter devices, by deposition of nonwoven meshes of electrospun recombinant spider silk proteins. Electrospinning of eADF4(C16) dissolved in HFIP results in smooth fibers. Variation of the protein concentration (5-25% w/v) results in different fiber diameters (80-1,100 nm) and thus pore sizes of the nonwoven mesh.
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Spider silk fibers display extraordinary mechanical properties. Engineered Araneus diadematus Fibroin 4 (eADF4) can be processed into nonwoven meshes using electrospinning. Here, the eADF4 nonwoven meshes are used to improve the performance of air filtering devices.

Based on the natural sequence of Araneus diadematus Fibroin 4 (ADF4), the recombinant spider silk protein eADF4(C16) has been engineered. This highly ...

Bioengineering

Manufacturing Of Robust Natural Fiber Preforms Utilizing Bacterial Cellulose as Binder

A novel method of manufacturing rigid and robust natural fiber preforms is presented here. This method is based on a papermaking process, whereby loose and short sisal fibers are dispersed into a water suspension containing bacterial cellulose. The fiber and nanocellulose suspension is then filtered (using vacuum or gravity) and the wet filter cake pressed to squeeze out any excess water, followed by a drying step. This will result in the hornification of the bacterial cellulose network, holding the loose natural fibers together.
Our method is specially suited for the manufacturing of rigid and robust preforms of hydrophilic fibers. The porous and hydrophilic nature of such fibers results in significant water uptake, drawing in the bacterial cellulose dispersed in the suspension. The bacterial cellulose will then be filtered against the surface of these fibers, forming a bacterial cellulose coating. When the loose fiber-bacterial cellulose suspension is filtered and dried, the adjacent bacterial cellulose forms a network and hornified to hold the otherwise loose fibers together.
The introduction of bacterial cellulose into the preform resulted in a significant increase of the mechanical properties of the fiber preforms. This can be attributed to the high stiffness and strength of the bacterial cellulose network. With this preform, renewable high performance hierarchical composites can also be manufactured by using conventional composite production methods, such as resin film infusion (RFI) or resin transfer molding (RTM). Here, we also describe the manufacturing of renewable hierarchical composites using double bag vacuum assisted resin infusion.

We present a novel method of manufacturing rigid and robust short natural fiber preforms using a papermaking process. Bacterial cellulose acts simultaneously as the binder for the loose fibers and provides rigidity to the fiber preforms. These preforms can be infused with a resin to produce truly green hierarchical composites.

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Solvothermal Synthesis of MIL-96 and UiO-66-NH2 on Atomic Layer Deposited Metal Oxide Coatings on Fiber Mats

Metal-organic frameworks (MOFs), which contain reactive metal clusters and organic ligands allowing for large porosities and surface areas, have proven effective in gas adsorption, separations, and catalysis. MOFs are most commonly synthesized as bulk powder, requiring additional processes to adhere them to functional devices and fabrics that risk decreasing the powder porosity and adsorption capacity. Here, we demonstrate a method of first coating fabrics with metal oxide films using atomic layer deposition (ALD). This process creates conformal films of controllable thickness on each fiber, while providing a more reactive surface for MOF nucleation. By submerging the ALD coated fabric in solution during solvothermal MOF synthesis, the MOFs create a conformal, well-adhered coating on the fibers, resulting in a MOF-functionalized fabric, without additional adhesion materials that may block MOF pores and functional sites. Here we demonstrate two solvothermal synthesis methods. First, we form a MIL-96(Al) layer on polypropylene fibers using synthetic conditions that convert the metal oxide to MOF. Using initial inorganic films of varying thicknesses, diffusion of the organic linker into the inorganic allows us to control the extent of MOF loading on the fabric. Second, we perform a solvothermal synthesis of UiO-66-NH2 in which the MOF nucleates on the conformal metal oxide coating on polyamide-6 (PA-6) fibers, thereby producing a uniform and conformal thin film of MOF on the fabric. The resulting materials can be directly incorporated into filter devices or protective clothing and eliminate the maladroit qualities of loose powder.

Solvothermal Synthesis of MIL-96 and UiO-66-NH2 on Atomic Layer Deposited Metal Oxide Coatings on Fiber Mats

Metal-organic frameworks are effective in gas storage and heterogeneous catalysis, but typical synthesis methods result in loose powders that are difficult to incorporate into smart materials. We demonstrate a method of first coating fabrics with ALD metal oxides, resulting in conformal films of MOF on the fabrics during solvothermal synthesis.

Metal-organic frameworks (MOFs), which contain reactive metal clusters and organic ligands allowing for large porosities and surface areas, have proven ...

Surface Properties of Synthesized Nanoporous Carbon and Silica Matrices

In this work, we report the synthesis and characterization of ordered nanoporous carbon material (also called ordered mesoporous carbon material [OMC]) with a 4.6 nm pore size, and ordered silica porous matrix, SBA-15, with a 5.3 nm pore size. This work describes the surface properties of nanoporous molecular sieves, their wettability, and the melting behavior of D2O confined in the differently ordered porous materials with similar pore sizes. For this purpose, OMC and SBA-15 with highly ordered nanoporous structures are synthesized via impregnation of the silica matrix by applying a carbon precursor and by the sol-gel method, respectively. The porous structure of investigated systems is characterized by an N2 adsorption-desorption analysis at 77 K. To determine the electrochemical character of the surface of synthesized materials, potentiometric titration measurements are conducted; the obtained results for OMC shows a significant pHpzc shift toward the higher values of pH, relative to SBA-15. This suggests that investigated OMC has surface properties related to oxygen-based functional groups. To describe the surface properties of the materials, the contact angles of liquids penetrating the studied porous beds are also determined. The capillary rise method has confirmed the increased wettability of the silica walls relative to the carbon walls and an influence of the pore roughness on the fluid/wall interactions, which is much more pronounced for silica than for carbon mesopores. We have also studied the melting behavior of D2O confined in OMC and SBA-15 by applying the dielectric method. The results show that the depression of the melting temperature of D2O in the pores of OMC is about 15 K higher relative to the depression of the melting temperature in SBA-15 pores with a comparable 5 nm size. This is caused by the influence of adsorbate/adsorbent interactions of the studied matrices.

Here we report the synthesis and characterization of ordered nanoporous carbon (with a 4.6 nm pore size) and SBA-15 (with a 5.3 nm pore size). The work describes the surface and textural properties of nanoporous molecular sieves, their wettability, and the melting behavior of D2O confined in the materials.

In this work, we report the synthesis and characterization of ordered nanoporous carbon material (also called ordered mesoporous carbon material [OMC]) ...

Synthesis of Hydrogels with Antifouling Properties As Membranes for Water Purification

Hydrogels have been widely utilized to enhance the surface hydrophilicity of membranes for water purification, increasing the antifouling properties and thus achieving stable water permeability through membranes over time. Here, we report a facile method to prepare hydrogels based on zwitterions for membrane applications. Freestanding films can be prepared from sulfobetaine methacrylate (SBMA) with a crosslinker of poly(ethylene glycol) diacrylate (PEGDA) via photopolymerization. The hydrogels can also be prepared by impregnation into hydrophobic porous supports to enhance the mechanical strength. These films can be characterized by attenuated total reflection Fourier transform infrared spectroscopy (ATR-FTIR) to determine the degree of conversion of the (meth)acrylate groups, using goniometers for hydrophilicity and differential scanning calorimetry (DSC) for polymer chain dynamics. We also report protocols to determine the water permeability in dead-end filtration systems and the effect of foulants (bovine serum albumin, BSA) on membrane performance.

This paper reports practical methods to prepare hydrogels in freestanding films and impregnated membranes and to characterize their physical properties, including water transport properties.

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A Simple and Scalable Fabrication Method for Organic Electronic Devices on Textiles

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In this paper, we present a protocol to selectively deposit organic materials on textiles, which allows for the direct integration of organic electronic devices with wearables. The fabricated devices can be fully integrated in textiles, respecting their mechanical appearance and enabling sensing capabilities.

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Impregnation and Grafting of Aminated Compounds onto Silica Substrates

A Synthetic Methodology for Preparing Impregnated and Grafted Amine-Based Silica Composites for Carbon Capture

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Author Spotlight: Standardizing the Development of Amine-Based Silica Composites as CO2 Adsorbents for Direct Air Capture 

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Vapor Phase Deposition of Electroactive Poly(3,4-ethylenedioxythiophene) onto Electrospun Commodity Polymer Nanofibers

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This paper describes a simple technique for coating electrospun PAN nanofibers with electroactive polymers using vapor deposition. The effects of the oxidant FeCl&#8323; on the deposition of poly(3,4-ethylenedioxythiophene) coatings on PAN were investigated to understand and optimize polymer growth, fiber diameter, and overall mechanical strength of the nanofiber mats.

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