Preparation of Butadienes by the Olefination of Acrylamides with Allyl Acetate
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Results: Preparation of 1,3-Butadiene via Ruthenium-catalyzed Olefination of Acrylamides with Allyl Acetate
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Conclusion
Transkript
The overall goal of this ruthenium catalyzed and oxidant free protocol is to synthesize Z, E-butadienes by olefination of electron-deficient alkenes using aminocarbonyl as a directing group. This method that can help answer key questions in a C-H
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The ruthenium-catalyzed olefination of electron-deficient alkenes with allyl acetate is described here. By using aminocarbonyl as a directing group, this external oxidant-free protocol has high efficiency and good stereo- and regioselectivity, opening a novel synthetic route to (Z,E)-butadiene skeletons.