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Chapter 13

Molecular Vibrational Spectroscopy

红外 (IR) 光谱:概述
红外 (IR) 光谱:概述
When electromagnetic radiation passes through a material, atoms or molecules transition from a lower to a higher energy state by absorbing radiation ...
红外光谱:分子振动概述
红外光谱:分子振动概述
When Infrared (IR) radiation passes through a covalently bonded molecule, the bonds transition from lower to higher vibrational levels. The fundamental ...
红外光谱学:分子振动的胡克定律近似
红外光谱学:分子振动的胡克定律近似
A covalently bonded heteronuclear diatomic molecule can be modeled as two vibrating masses connected by a spring. The vibrational frequency of the bond ...
红外光谱仪
红外光谱仪
There are two main infrared (IR) spectrophotometers: dispersive IR spectrometers and Fourier transform infrared (FTIR) spectrometers. In a dispersive IR ...
红外光谱
红外光谱
When infrared (IR) radiation passes through a molecule, the bonds stretch or bend by absorbing the radiation. This absorption creates the molecule's ...
IR 吸收频率:杂交
IR 吸收频率:杂交
Hydrocarbons such as alkanes, alkenes, and alkynes show characteristic C–H stretching absorption bands. These IR stretching frequencies depend on ...
IR 吸收频率:离域
IR 吸收频率:离域
Electron delocalization refers to the distribution of electrons across multiple atoms within a molecule rather than being confined to a single atom or ...
IR 频率区域:X-H 拉伸
IR 频率区域:X-H 拉伸
In IR spectroscopy, signals produced by the X−H bonds (such as C−H, O−H, or N−H) can be observed in the frequency range of  ...
IR 频率区域:炔烃和丁腈拉伸
IR 频率区域:炔烃和丁腈拉伸
Both alkyne (C≡C) and nitrile (C≡N) functional groups contain triple bonds and show stretching absorptions around the wavenumber range of 2100 ...
IR 频率区域:烯烃和羰基拉伸
IR 频率区域:烯烃和羰基拉伸
Double bonds in alkenes and carbonyl compounds exhibit stretching frequencies in the diagnostic region of the IR spectrum. In addition, alkenes exhibit ...
IR 频率区域:指纹区域
IR 频率区域:指纹区域
IR spectra are divided into two main regions: the diagnostic region and the fingerprint region. The diagnostic region of the spectrum lies above 1500 ...
IR 光谱峰值强度:IR 活性键的数量
IR 光谱峰值强度:IR 活性键的数量
When infrared radiation is passed through a molecule, absorption occurs if the molecule's vibration leads to a substantial change in its bond dipole ...
IR 光谱峰值强度:偶极矩
IR 光谱峰值强度:偶极矩
The dipole moment of a bond is the product of the partial charge on either atom and the distance between them. Dipole moments influence the efficiency of ...
IR 光谱峰展宽:氢键
IR 光谱峰展宽:氢键
The vibrational frequency of a bond is directly proportional to its bond strength. As a result, stronger bonds vibrate at higher frequencies, while weaker ...
红外光谱峰值分割:对称与不对称振动
红外光谱峰值分割:对称与不对称振动
Identical bonds within a polyatomic group can stretch symmetrically (in-phase) or asymmetrically (out-of-phase). Similar to hydrogen bonding, these ...
红外光谱的应用:概述
红外光谱的应用:概述
The non-destructive nature and ability to provide valuable chemical information make IR spectroscopy a versatile technique with broad applications in ...
衰减全反射 (ATR) 红外光谱:概述
衰减全反射 (ATR) 红外光谱:概述
Attenuated total reflectance (ATR) infrared spectroscopy is a powerful analytical technique used to study the composition of materials. It is widely ...
拉曼光谱:概述
拉曼光谱:概述
The underlying principle of Raman spectroscopy is based on the interaction between light and matter, specifically molecules' inelastic scattering of ...
拉曼光谱仪器:概述
拉曼光谱仪器:概述
A conventional Raman spectrophotometer includes a laser source, a sample holding system, a wavelength selector, and a detector. The monochromatic laser ...
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